公开(公告)号：US5955206A

公开(公告)日：1999-09-21

申请号：US640442

申请日：1996-04-30

申请人： Koju Okazaki ,  Chitoshi Shimakawa ,  Mamoru Tanaka ,  Yoshinobu Kanemura ,  Teruyuki Nagata ,  Yoshihiro Irizato ,  Shinichi Umeda

发明人： Koju Okazaki ,  Chitoshi Shimakawa ,  Mamoru Tanaka ,  Yoshinobu Kanemura ,  Teruyuki Nagata ,  Yoshihiro Irizato ,  Shinichi Umeda

IPC分类号： C08G18/38 ,  C08G59/66 ,  G02B1/04 ,  B29B1/02

CPC分类号： C08G59/66 ,  C08G18/3876 ,  G02B1/041

摘要： A composition for polysulfide-based resin comprising a polythiol having 4 or more functional groups and a compound having a reactive unsaturated bond(s) and/or b epoxy group(s) and/or c iso(thio)cyanato group(s) in one molecule (however, a+b+c.gtoreq.2, and a and b are not simultaneously 0). A polysulfide-based resin obtained by curing the composition, an optical material comprising the resin, a lens consisting of the optical material and a method for producing the polysulfide-based resin are also set forth.

摘要翻译： 一种用于多硫化物基树脂的组合物，其包含具有4个或更多个官能团的多硫醇和具有一个或多个反应性不饱和键和/或b个环氧基和/或c（硫代）氰基的化合物， 一个分子（然而，a + b + c> / = 2，a和b不同时为0）。 还提出了通过固化组合物获得的聚硫化物基树脂，包含树脂的光学材料，由光学材料组成的透镜和用于制备多硫化物基树脂的方法。

公开(公告)号：US5736609A

公开(公告)日：1998-04-07

申请号：US663734

申请日：1996-06-14

申请人： Yoshihiro Irizato ,  Shinichi Umeda ,  Yoshinobu Kanemura ,  Teruyuki Nagata

发明人： Yoshihiro Irizato ,  Shinichi Umeda ,  Yoshinobu Kanemura ,  Teruyuki Nagata

IPC分类号： C08G18/38 ,  C08G18/67 ,  G02B1/04 ,  C08G18/62

CPC分类号： C08G18/677 ,  C08G18/3876 ,  G02B1/041

摘要： The present invention discloses a sulfur-containing urethane-based resin composition of the present invention is directed to a sulfur-containing urethane-based resin composition which comprises a polythiol compound represented by formula (1): ##STR1## wherein X.sub.1, X.sub.2 and X.sub.3 each is a hydrogen atom or a mercapto group; x, y and z each is an integer of 0 to 8; and in their combinations, formula (1) has at least two mercapto groups, a polyiso(thio)cyanate compound, and a compound having two or more reactive unsaturated groups in an amount of 30 to 70% by weight based on the total weight of the composition, or a sulfur-containing urethane-based resin composition which comprises the polythiol compound represented by formula (1), the polyiso(thio)cyanate compound, the compound having two or more reactive unsaturated groups in an amount of 10 to 70% by weight based on the total weight, and a photopolymerization catalyst.

摘要翻译： 本发明公开了本发明的含硫氨基甲酸酯类树脂组合物，其特征在于，含有由式（1）表示的多硫醇化合物的含硫氨基甲酸酯类树脂组合物：其中X1， X2和X3各自为氢原子或巯基; x，y和z各自为0〜8的整数; 并且在它们的组合中，式（1）具有至少两个巯基，多异（硫代）氰酸酯化合物和具有两个或更多个反应性不饱和基团的化合物，其量为30至70重量％，基于 所述组合物，或含有式（1）表示的多硫醇化合物，多异（硫代）氰酸酯化合物，具有10〜70重量％以上的反应性不饱和基团的化合物的含硫氨基甲酸酯类树脂组合物， 和基于总重量的光聚合催化剂。

公开(公告)号：US5545751A

公开(公告)日：1996-08-13

申请号：US358566

申请日：1994-12-14

申请人： Chiyuki Kusuda ,  Masayuki Furuya ,  Masaru Wada ,  Yoshihiro Irizato ,  Hiroshi Naruse ,  Teruyuki Nagata

发明人： Chiyuki Kusuda ,  Masayuki Furuya ,  Masaru Wada ,  Yoshihiro Irizato ,  Hiroshi Naruse ,  Teruyuki Nagata

IPC分类号： C07C213/00 ,  C07C217/92 ,  C07C209/22

CPC分类号： C07C213/00 ,  C07C217/92

摘要： A process for the preparation of 4-methoxy-2,2',6-trimethyldiphenylamine, which comprises heating and reacting 2,6-dimethylcyclohexanone and 2-methyl-4-methoxyaniline in the presence of a dehydrogenation catalyst while removing the resultant hydrogen and water from the reaction system.

摘要翻译： 一种制备4-甲氧基-2,2'，6-三甲基二苯胺的方法，该方法包括在脱氢催化剂的存在下加热和反应2,6-二甲基环己酮和2-甲基-4-甲氧基苯胺，同时除去所得氢气， 来自反应体系的水。

公开(公告)号：US5608115A

公开(公告)日：1997-03-04

申请号：US373083

申请日：1995-01-17

申请人： Koju Okazaki ,  Yoshinobu Kanemura ,  Teruyuki Nagata

发明人： Koju Okazaki ,  Yoshinobu Kanemura ,  Teruyuki Nagata

IPC分类号： G02B1/04 ,  C07C319/20 ,  C07C321/14 ,  C08G18/30 ,  C08G18/38 ,  C08G18/52 ,  C08G18/77

CPC分类号： C08G18/775 ,  C07C321/14 ,  C08G18/3876 ,  C08G18/52 ,  G02B1/041

摘要： A novel polythiol having four or more functional groups, a process for producing the polythiol comprising reacting thiourea with a specific compound, a sulfur-containing urethane-based resin prepared from the polythiol and a lens made of the resin. The resin has a high refractive index, and low dispersion of refractive index, is lightweight, colorless and transparent, has no optical distortion, and has excellent characteristics in weatherability, dye-affinity, heat resistance, impact resistance and machinability.

摘要翻译： 一种具有四个或更多个官能团的新型多硫醇，一种制备多硫醇的方法，包括使硫脲与特定化合物反应，由多硫醇制备的含硫氨基甲酸酯基树脂和由该树脂制成的透镜。 该树脂折射率高，折射率分散性低，重量轻，无色透明，无变形，耐候性，染料亲合性，耐热性，耐冲击性和切削性优异。

公开(公告)号：US5693738A

公开(公告)日：1997-12-02

申请号：US413113

申请日：1995-03-29

申请人： Koju Okazaki ,  Chitoshi Shimakawa ,  Mamoru Tanaka ,  Yoshinobu Kanemura ,  Teruyuki Nagata ,  Seiichi Kobayashi ,  Yoko Tajiri ,  Nobuya Kawauchi ,  Katsuyoshi Sasagawa

发明人： Koju Okazaki ,  Chitoshi Shimakawa ,  Mamoru Tanaka ,  Yoshinobu Kanemura ,  Teruyuki Nagata ,  Seiichi Kobayashi ,  Yoko Tajiri ,  Nobuya Kawauchi ,  Katsuyoshi Sasagawa

IPC分类号： C08G18/18 ,  C08G18/32 ,  C08G18/38 ,  G02B1/04

CPC分类号： C08G18/3876 ,  C08G18/1875 ,  C08G18/3203 ,  C08G18/3868 ,  G02B1/041

摘要： A composition for a urethane-base plastic lens, comprising: (a) at least one ester compound selected from the group consisting of isocyanate compounds, isothiocyanate compounds and isocyanato-containing isothiocyanate compounds, (b) at least one active hydrogen compound selected from the group consisting of hydroxyl compounds, mercapto compounds and mercapto-containing hydroxyl compounds, (c) a tertiary amine, and (d) a Lewis acid; a plastic lens obtained by heating and curing the composition, and a process for the production of the plastic lens. The composition has a long pot life and can produce an optically uniform plastic lens in a short time.

摘要翻译： 一种聚氨酯类塑料透镜用组合物，其含有：（a）至少一种选自异氰酸酯化合物，异硫氰酸酯化合物和含异氰酸酯基的异硫氰酸酯化合物的酯化合物，（b）至少一种选自 由羟基化合物，巯基化合物和含巯基的羟基化合物组成的组，（c）叔胺和（d）路易斯酸; 通过加热和固化组合物获得的塑料透镜，以及用于生产塑料透镜的方法。 该组合物具有长的适用期，并可在短时间内产生光学均匀的塑料透镜。

公开(公告)号：US5021503A

公开(公告)日：1991-06-04

申请号：US311352

申请日：1989-02-15

申请人： Teruyuki Nagata ,  Koju Okazaki ,  Nobuyuki Kajimoto ,  Tohru Miura ,  Yoshinobu Kanemura ,  Katsuyoshi Sasagawa

发明人： Teruyuki Nagata ,  Koju Okazaki ,  Nobuyuki Kajimoto ,  Tohru Miura ,  Yoshinobu Kanemura ,  Katsuyoshi Sasagawa

IPC分类号： C08G18/34 ,  C08G18/38 ,  C08G18/77

CPC分类号： C08G18/3876 ,  C08G18/34 ,  C08G18/775

摘要： The present invention relates to resin useful in preparing plastic lenses having a high refractive index comprising reacting an aliphatic polyisocyanate compounds having at least one sulfur atom with one or more of active hydrogen compounds selected from the group consisting of a polyol, a polythiol having sulfur atoms only in a mercapto groups, and a polythiol having at least one sulfur atom other than in the mercapto groups; lenses containing the above-mentioned resin; and a method for the preparation thereof characterized by adding an internal release agent to the mixture of the above-mentioned raw materials in casting lenses from the resin; and lenses obtained by this method.

公开(公告)号：US5013496A

公开(公告)日：1991-05-07

申请号：US310388

申请日：1989-02-15

申请人： Teruyuki Nagata ,  Koju Okazaki ,  Nobuyuki Kajimoto ,  Tohru Miura ,  Yoshinobu Kanemura ,  Katsuyoshi Sasagawa

发明人： Teruyuki Nagata ,  Koju Okazaki ,  Nobuyuki Kajimoto ,  Tohru Miura ,  Yoshinobu Kanemura ,  Katsuyoshi Sasagawa

IPC分类号： G02B1/04 ,  B29C39/02 ,  B29K75/00 ,  B29K105/32 ,  B29L11/00 ,  C08G18/00 ,  C08G18/34 ,  C08G18/38 ,  C08G18/77 ,  C08L75/00

CPC分类号： C08G18/3876 ,  C08G18/34 ,  C08G18/775

摘要： A process for producing a plastic lens having a high refractive index and profile regularity which includes forming a mixture of one or more of sulfur-containing aromatic polyisocyanate compounds, one or more of active hydrogen compounds selected from the group consisting of polyol compounds and polythiol compounds, and at least one internal mold releasing agent. Then subjecting the resulting mixture to casting polymerization, to form the plastic lens.

公开(公告)号：US4929707A

公开(公告)日：1990-05-29

申请号：US305905

申请日：1989-02-03

申请人： Teruyuki Nagata ,  Koju Okazaki ,  Nobuyuki Kajimoto ,  Tohru Miura ,  Yoshinobu Kanemura ,  Katsuyoshi Sasagawa

发明人： Teruyuki Nagata ,  Koju Okazaki ,  Nobuyuki Kajimoto ,  Tohru Miura ,  Yoshinobu Kanemura ,  Katsuyoshi Sasagawa

IPC分类号： B29C33/60 ,  B29C39/02 ,  B29K75/00 ,  B29K105/32 ,  B29L11/00 ,  C08G18/30 ,  C08G18/32 ,  C08G18/38 ,  C08G18/77 ,  G02B1/04

CPC分类号： C08G18/775 ,  B29C33/60 ,  C08G18/3863 ,  G02B1/041 ,  B29K2075/00 ,  B29L2011/0016

摘要： Polyurethane base lens resins obtained by reacting one or more of sulfur-containing polyisocyanates compound with one or more of sulfur-containing polyols, and polyurethane base lenses comprising these resins are disclosed.A method for preparing polyurethane base lenses which comprises adding internal mold releasing agents to the mixture of the above polyisocyanates and polyols prior to casting polymerization is also disclosed.

公开(公告)号：US5837797A

公开(公告)日：1998-11-17

申请号：US753436

申请日：1996-11-25

申请人： Koju Okazaki ,  Yoshinobu Kanemura ,  Teruyuki Nagata

发明人： Koju Okazaki ,  Yoshinobu Kanemura ,  Teruyuki Nagata

IPC分类号： G02B1/04 ,  C07C319/20 ,  C07C321/14 ,  C08G18/30 ,  C08G18/38 ,  C08G18/52 ,  C08G18/77

CPC分类号： C08G18/775 ,  C07C321/14 ,  C08G18/3876 ,  C08G18/52 ,  G02B1/041

摘要： A novel polythiol having four or more functional groups, a process for producing the polythiol comprising reacting thiourea with a specific compound, a sulfur-containing urethane-based resin prepared from the polythiol and a lens made of the resin. The resin has a high refractive index, and low dispersion of refractive index, is lightweight, colorless and transparent, has no optical distortion, and has excellent characteristics in weatherability, dye-affinity, heat resistance, impact resistance and machinability.

摘要翻译： 一种具有四个或更多个官能团的新型多硫醇，一种制备多硫醇的方法，包括使硫脲与特定化合物反应，由多硫醇制备的含硫氨基甲酸酯基树脂和由该树脂制成的透镜。 树脂折射率高，折射率分散性低，重量轻，无色透明，无变形，耐候性，染料亲合性，耐热性，耐冲击性，切削性等优异的特性。

公开(公告)号：US5753730A

公开(公告)日：1998-05-19

申请号：US700508

申请日：1991-05-15

申请人： Teruyuki Nagata ,  Koju Okazaki ,  Tohru Miura ,  Nobuyuki Kajimoto ,  Yoshinobu Kanemura ,  Katsuyoshi Sasagawa ,  Masao Imai

发明人： Teruyuki Nagata ,  Koju Okazaki ,  Tohru Miura ,  Nobuyuki Kajimoto ,  Yoshinobu Kanemura ,  Katsuyoshi Sasagawa ,  Masao Imai

IPC分类号： B29C33/60 ,  C08G18/38 ,  C08G18/73 ,  C08G18/75 ,  C08G18/76 ,  C08K5/02 ,  C08K5/098 ,  C08K5/19 ,  C08K5/521 ,  C08K5/54 ,  C08L75/04 ,  G02B1/04 ,  C08K5/51

CPC分类号： B29C33/60 ,  C08G18/3863 ,  C08G18/3876 ,  C08G18/73 ,  C08G18/75 ,  C08G18/7628 ,  C08K5/02 ,  C08K5/098 ,  C08K5/19 ,  C08K5/521 ,  C08K5/54 ,  C08L75/04 ,  G02B1/041

摘要： One aspect of the present invention relates to a process for preparing plastic lenses having a high-refractive index comprising forming a mixture containing one or more polyisocyanate compounds; one or more active hydrogen compounds selected from the group consisting of a polyol compound having no sulfur atom, a polyol compound having at least one sulfur atom, and a polythiol compound having at least one sulfur atom in addition to the sulfur atom contained in mercapto group and at least one internal releasing agent and then casting and polymerizing the mixture. A second aspect of the present invention relates to a process for preparing a sulfur-containing urethane resin lens is here disclosed which comprises mixing polyisocyanate having two or more isocyanato groups, polythiol having two or more thiol groups and one or more surface active agent selected from the group consisting of fluorine-containing nonionic surface active agents, silicone-containing nonionic surface active agents, alkyl quaternary ammonium salts and acid phosphoric esters and then cast polymerizing the mixture in a mold made of a glass or a metal. Lenses prepared by the processes are also disclosed.

摘要翻译： 本发明的一个方面涉及一种制备具有高折射率的塑料透镜的方法，包括形成含有一种或多种多异氰酸酯化合物的混合物; 一种或多种选自不含硫原子的多元醇化合物的活性氢化合物，至少一个硫原子的多元醇化合物，以及巯基中含有硫原子以外还具有至少一个硫原子的多硫醇化合物 和至少一种内部脱模剂，然后浇铸和聚合该混合物。 本发明的第二方面涉及一种制备含硫聚氨酯树脂透镜的方法，其包括混合具有两个或多个异氰酸酯基的多异氰酸酯，具有两个或更多个硫醇基的多硫醇和一种或多种选自以下的表面活性剂： 由含氟非离子表面活性剂，含硅氧烷的非离子表面活性剂，烷基季铵盐和酸性磷酸酯组成的组，然后将混合物浇铸在由玻璃或金属制成的模具中。 还披露了由该方法制备的镜片。