-
1.发明授权
公开(公告)号：US5250640A
公开(公告)日：1993-10-05
申请号：US865865
申请日：1992-04-09
申请人： Yoshio Irie , Takumi Hatsuda , Koichi Yonemura , Kazumasa Kimura
发明人： Yoshio Irie , Takumi Hatsuda , Koichi Yonemura , Kazumasa Kimura
CPC分类号： C08J3/12 , B01J19/20 , B01J20/26 , B29B7/183 , C08J2300/14
摘要： A method for the production of a particulate hydrogel polymer by the exposure of a hydrogel polymer possessing a cross-linked structure to shear force in a vessel thereby finely dividing said hydrogel polymer, which method comprises exerting shear force repeatedly on said hydrogel polymer while keeping said hydrogel polymer at a temperature in the range of from 40.degree. to 110.degree. C. under a mechanical pressure in the range of from 0.01 to 1.5 kg/cm.sup.2, and method for the production of an absorbent resin comprising drying the resultant particulate hydrogel polymer.
-
2.发明授权Method for production of particulate hydrated gel polymer and absorbent resin 失效颗粒状水合凝胶聚合物和吸水树脂的生产方法
公开(公告)号：US5275773A
公开(公告)日：1994-01-04
申请号：US827444
申请日：1992-01-29
申请人： Yoshio Irie , Takumi Hatsuda , Koichi Yonemura
发明人： Yoshio Irie , Takumi Hatsuda , Koichi Yonemura
IPC分类号： C08J3/12 , C08F220/06
CPC分类号： C08J3/12 , C08J2300/14 , Y10S524/916
摘要： A method for the production of a particulate hydrated gel polymer, which includes heating a hydrated gel polymer possessed of a cross-linked structure to a temperature in the range of from 45.degree. to 90.degree. C. and extruding the resultant hot hydrated gel polymer through a perforated plate containing holes of a diameter in the range of from 6.5 to 18 mm and an absorbent resin which includes drying the resultant particulate hydrated gel polymer.
摘要翻译： 一种用于生产颗粒状水合凝胶聚合物的方法，其包括将具有交联结构的水合凝胶聚合物加热至45℃至90℃的温度，并将所得热水凝胶聚合物挤出 包含直径在6.5至18mm范围内的孔的多孔板和包括干燥所得颗粒状水合凝胶聚合物的吸收性树脂。
-
公开(公告)号：US4985514A
公开(公告)日：1991-01-15
申请号：US229988
申请日：1988-08-09
申请人： Kazumasa Kimura , Takumi Hatsuda , Yoshio Irie , Tadao Shimomura
发明人： Kazumasa Kimura , Takumi Hatsuda , Yoshio Irie , Tadao Shimomura
IPC分类号： C08F220/06 , B01J20/26 , C08F2/10 , C08F8/12 , C08F20/04
CPC分类号： B01J20/26 , C08F20/04 , Y10S526/93
摘要： The present invention is a method for the production of a water absorbent resin, which comprises preparing a monomer component possessing an ability to form a cross-linked structure and convert itself into a hydrated gel polymer during the course of aqueous solution polymerization, possessing an acid group-containing monomer content of at least 50 mol %, and having 10 to 50 mol % of said acid group-containing monomer neutralized and subjecting said monomer component to aqueous solution polymerization within a reaction vessel having a plurality of rotary shafts each fitted with stirring blades.
-
4.发明授权
公开(公告)号：US4920202A
公开(公告)日：1990-04-24
申请号：US187866
申请日：1988-04-29
申请人： Yoshio Irie , Kaoru Iwasaki , Takumi Hatsuda , Kazumasa Kimura , Nobuyuki Harada , Kunihiko Ishizaki , Tadao Shimomura , Teruaki Fujiwara
发明人： Yoshio Irie , Kaoru Iwasaki , Takumi Hatsuda , Kazumasa Kimura , Nobuyuki Harada , Kunihiko Ishizaki , Tadao Shimomura , Teruaki Fujiwara
IPC分类号： C08F6/00
CPC分类号： C08F6/001
摘要： A method for the production of a hydrophilic polymer having a small residual monomer content from a hydrated gel polymer, which method comprises drying said hydrated gel polymer by contact thereof with a gas containing at least steam and having a dew point in the range of 50.degree. to 100.degree. C. at a temperature in the range of 80.degree. C. to 250.degree. C., and a hydrophilic polymer obtained therefrom.
-
公开(公告)号：US4734478A
公开(公告)日：1988-03-29
申请号：US748820
申请日：1985-06-26
申请人： Tsuneo Tsubakimoto , Tadao Shimomura , Yoshio Irie , Yoshihiko Masuda , Kazumasa Kimura , Takumi Hatsuda
发明人： Tsuneo Tsubakimoto , Tadao Shimomura , Yoshio Irie , Yoshihiko Masuda , Kazumasa Kimura , Takumi Hatsuda
CPC分类号： C08J3/12 , A61L15/18 , A61L15/60 , B01J20/26 , C08F8/14 , D21H17/28 , D21H17/43 , C08F2810/20 , C08J2300/14
摘要： The invention provides [I] a water-absorbing agent composed of a water-absorbing resin powder having the molecular chains near its surface being crosslinked, said powder being obtained by mixing 100 parts by weight of a powder of a carboxyl-containing water-absorbing resin selected from the group consisting of a hydrolyzate of a starch-acrylonitrile graft polymer, a partially neutralized product of a starch-acrylic acid graft polymer, a saponification product of a vinyl acetate-acrylic ester copolymer, a hydrolyzate of an acrylonitrile copolymer, a crosslinked product of a hydrolyzate of an acrylonitrile copolymer, a hydrolyzate of an acrylamide copolymer, a crosslinked product of a hydrolyzate of an acrylamide copolymer, a partially neutralized product of polyacrylic acid, and a crosslinked product of partially neutralized polyacrylic acid with 0.001 to 10 parts by weight of a polyhydric alcohol, 0.01 to 8 parts by weight of a hydrophilic organic solvent and 0 to 8 parts by weight of water, and heating the mixture at a temperature of at least 90.degree. C. to react the water-absorbing resin powder with the polyhydric alcohol; [II] a water-absorbing agent composed of a mixture of the water-absorbing agent [I] with finely divided silica; [III] a water-absorbing agent obtained by pulverizing and granulating a mixture of the water-absorbing agent [I] with an aqueous liquid; and [IV] a water-absorbing agent composed of a mixture of the water-absorbing agent [III] with finely divided silica.
摘要翻译： 本发明提供[I]一种由其表面附近的分子链交联的吸水性树脂粉末组成的吸水剂，所述粉末是通过将100重量份的含羧基的吸水性粉末 选自淀粉 - 丙烯腈接枝聚合物的水解产物，淀粉 - 丙烯酸接枝聚合物的部分中和产物，乙酸乙烯酯 - 丙烯酸酯共聚物的皂化产物，丙烯腈共聚物的水解产物， 丙烯腈共聚物的水解产物，丙烯酰胺共聚物的水解产物，丙烯酰胺共聚物的水解产物的交联产物，聚丙烯酸的部分中和产物和部分中和的聚丙烯酸的交联产物与0.001至10份的交联产物 的多元醇，0.01〜8重量份的亲水性有机溶剂和0〜8重量份的 水，并在至少90℃的温度下加热混合物以使吸水性树脂粉末与多元醇反应; [II]由吸水剂[I]与细碎二氧化硅的混合物组成的吸水剂; [III]通过将吸水剂[I]与水性液体的混合物粉碎和造粒得到的吸水剂; 和[IV]由吸水剂[III]与细碎二氧化硅的混合物组成的吸水剂。
-
公开(公告)号：US07183456B2
公开(公告)日：2007-02-27
申请号：US10764535
申请日：2004-01-27
申请人： Takumi Hatsuda , Yoshio Irie , Masatoshi Nakamura , Katsuyuki Wada , Shinichi Fujino , Kazuki Kimura , Kunihiko Ishizaki
发明人： Takumi Hatsuda , Yoshio Irie , Masatoshi Nakamura , Katsuyuki Wada , Shinichi Fujino , Kazuki Kimura , Kunihiko Ishizaki
CPC分类号： C08J3/122 , A61L15/60 , C08J3/245 , C08J2300/14 , Y10S524/916 , Y10T428/2982
摘要： In a production process for a water-absorbent resin, comprising the steps of: blending a liquid material and a water-absorbent resin; and heating the resultant mixture in order to produce a modified water-absorbent resin, the present invention is to provide: a method for uniformly and efficiently treating a water-absorbent resin favorably in view of industry, and as a result, a good-balanced water-absorbent resin having various excellent properties, such absorption capacity without a load, absorption capacity under a load, and single-layer absorption capacity under a load in contact with an aqueous liquid. The production process comprises the step of spray-blending a water-absorbent resin (A) and a liquid material (B) with a blending apparatus equipped with a spray nozzle (C), wherein the liquid material (B) is sprayed from the spray nozzle (C) and its spray pattern is a circular and hollow cone shape or a double-convex-lens and elliptic cone shape. In addition, the production process comprises the step of heat-treating a water-absorbent resin under an atmosphere having a dew point of not higher than 60° C. and a temperature of not lower than 90° C., wherein the water-absorbent resin is obtained after a drying step following a pulverization step.
摘要翻译： 在吸水性树脂的制造方法中，包括以下步骤：将液体材料和吸水性树脂混合; 并加热得到的混合物以制备改性吸水性树脂，本发明提供一种从工业上有利地均匀有效地处理吸水性树脂的方法，结果是良好平衡 具有各种优异性能的吸水性树脂，这种无负载的吸收能力，负载下的吸收能力以及在与水性液体接触的负荷下的单层吸收能力。 制备方法包括用配有喷嘴（C）的混合装置将吸水性树脂（A）和液体材料（B）喷雾共混的步骤，其中液体材料（B）从喷雾 喷嘴（C）及其喷射图案是圆形和中空圆锥形或双凸透镜和椭圆锥形。 此外，制造方法包括在露点不高于60℃，温度不低于90℃的气氛下对吸水性树脂进行热处理的步骤，其中吸水剂 在粉碎步骤之后的干燥步骤之后获得树脂。
-
公开(公告)号：US07078458B2
公开(公告)日：2006-07-18
申请号：US11014969
申请日：2004-12-20
摘要： In the production of an acrylate polymer by the steps of preparing a water-soluble unsaturated monomer having a ratio of neutralization in the range of 30 to 100 mol % and containing 50 to 100 mol % of an acrylate and then polymerizing the monomer, a method for the production of a hydrophilic resin which comprises using a water-soluble unsaturated monomer having a β-hydroxy propionic acid (salt) content of not more than 1,000 ppm. The hydrophilic resin obtained by this method exhibits excellent physical properties and has only a small residual monomer content. Further, a residual monomer content neither occurs nor increases in any using conditions.
-
公开(公告)号：US06720389B2
公开(公告)日：2004-04-13
申请号：US09945812
申请日：2001-09-05
申请人： Takumi Hatsuda , Yoshio Irie , Masatoshi Nakamura , Katsuyuki Wada , Shinichi Fujino , Kazuki Kimura , Kunihiko Ishizaki
发明人： Takumi Hatsuda , Yoshio Irie , Masatoshi Nakamura , Katsuyuki Wada , Shinichi Fujino , Kazuki Kimura , Kunihiko Ishizaki
IPC分类号： C08J324
CPC分类号： C08J3/122 , A61L15/60 , C08J3/245 , C08J2300/14 , Y10S524/916 , Y10T428/2982
摘要： In a production process for a water-absorbent resin, comprising the steps of: blending a liquid material and a water-absorbent resin; and heating the resultant mixture in order to produce a modified water-absorbent resin, the present invention is to provide: a method for uniformly and efficiently treating a water-absorbent resin favorably in view of industry, and as a result, a good-balanced water-absorbent resin having various excellent properties, such absorption capacity without a load, absorption capacity under a load, and single-layer absorption capacity under a load in contact with an aqueous liquid. The production process comprises the step of spray-blending a water-absorbent resin (A) and a liquid material (B) with a blending apparatus equipped with a spray nozzle (C), wherein the liquid material (B) is sprayed from the spray nozzle (C) and its spray pattern is a circular and hollow cone shape or a double-convex-lens and elliptic cone shape. In addition, the production process comprises the step of heat-treating a water-absorbent resin under an atmosphere having a dew point of not higher than 60° C. and a temperature of not lower than 90° C., wherein the water-absorbent resin is obtained after a drying step following a pulverization step.
摘要翻译： 在吸水性树脂的制造方法中，包括以下步骤：将液体材料和吸水性树脂混合; 并加热得到的混合物以制备改性吸水性树脂，本发明提供一种从工业上有利地均匀有效地处理吸水性树脂的方法，结果是良好平衡 具有各种优异性能的吸水性树脂，这种无负载的吸收能力，负载下的吸收能力以及在与水性液体接触的负荷下的单层吸收能力。 制备方法包括用配有喷嘴（C）的混合装置将吸水性树脂（A）和液体材料（B）喷雾共混的步骤，其中液体材料（B）从喷雾 喷嘴（C）及其喷射图案是圆形和中空圆锥形或双凸透镜和椭圆锥形。 此外，制造方法包括在露点不高于60℃，温度不低于90℃的气氛下对吸水性树脂进行热处理的步骤，其中吸水剂 在粉碎步骤之后的干燥步骤之后获得树脂。
-
公开(公告)号：US06388000B1
公开(公告)日：2002-05-14
申请号：US08427734
申请日：1995-04-24
IPC分类号： C08F2006
摘要： In the production of an acrylate polymer by the steps of preparing a water-soluble unsaturated monomer having a ratio of neutralization in the range of 30 to 100 mol % and containing 50 to 100 mol % of an acrylate and then polymerizing the monomer, a method for the production of a hydrophilic resin which comprises using a water-soluble unsaturated monomer having a &bgr;-hydroxy propionic acid (salt) content of not more than 1,000 ppm. The hydrophilic resin obtained by this method exhibits excellent physical properties and has only a small residual monomer content. Further, a residual monomer content neither occurs nor increases in any using conditions.
摘要翻译： 在制备丙烯酸酯聚合物时，通过以下步骤制备中和度在30-100mol％范围内并含有50-100mol％丙烯酸酯的水溶性不饱和单体，然后使单体聚合， 用于生产亲水性树脂，其包括使用具有不超过1,000ppm的β-羟基丙酸（盐）含量的水溶性不饱和单体。 通过该方法获得的亲水性树脂显示出优异的物理性能，并且仅具有小的残留单体含量。 此外，残留的单体含量也不会发生，也不会在任何使用条件下增加。
-
公开(公告)号：US06562879B1
公开(公告)日：2003-05-13
申请号：US09502823
申请日：2000-02-11
IPC分类号： C08J916
CPC分类号： C08J3/12 , C08J3/122 , C08J2300/14
摘要： The present invention provides a water-absorbent resin powder and its production process and use, wherein the water-absorbent resin powder has high liquid permeability and high water absorbency. The production process for a water-absorbent resin powder, according to the present invention, comprises the step of obtaining water-absorbent crosslinked polymer particles by an aqueous solution polymerization step, and grinding the resultant crosslinked polymer particles until the bulk density thereof increases to not lower than 0.72 (g/ml). The water-absorbent resin powder is characterized by being arbitrarily pulverized and having a bulk density of not lower than 0.74 (g/ml) and a water absorption capacity of not lower than 20 (g/g) for 0.9 weight % physiological saline under a load of 0.7 psi (4.83 kPa). In addition, the absorbent structure comprises the above water-absorbent resin powder and a fibrous material. The absorbent article comprises an absorbent layer including the above absorbent structure.
摘要翻译： 本发明提供吸水性树脂粉末及其制造方法和用途，其中吸水性树脂粉末具有高透液性和高吸水性。 根据本发明的吸水性树脂粉末的制造方法包括通过水溶液聚合步骤获得吸水性交联聚合物颗粒的步骤，并研磨所得交联聚合物颗粒，直到其堆积密度增加至不 低于0.72（g / ml）。 吸水性树脂粉末的特征在于任意粉碎，堆积密度不低于0.74（g / ml），对于0.9重量％生理盐水的吸水能力不低于20（g / g） 负载0.7 psi（4.83 kPa）。 此外，吸收性结构体包含上述吸水性树脂粉末和纤维材料。 吸收性物品包括包含上述吸收结构的吸收层。
-
-
-
-
-
-
-
-
-
搜索结果
77 条记录 (耗时 0.031 秒)
