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    Process for preparing polyolefins
    1.
    发明授权
    Process for preparing polyolefins 失效
    聚烯烃的制备方法

    公开(公告)号：US4410670A

    公开(公告)日：1983-10-18

    申请号：US45961

    申请日：1979-06-06

    申请人： Yoshio Tajima ,  Kazuo Matsuura ,  Nobuyuki Kuroda ,  Mituji Miyoshi

    发明人： Yoshio Tajima ,  Kazuo Matsuura ,  Nobuyuki Kuroda ,  Mituji Miyoshi

    IPC分类号： C08F10/00 ,  C08F4/66

    CPC分类号： C08F10/00

    摘要： This invention provides a process for preparing polyolefins using a new catalyst. According to this invention, .alpha.-olefins can be polymerized or copolymerized to have good stereoregularity and at a high activity by the use of such new catalyst. The new catalyst used in this invention consists of [A] a solid component obtained by contacting (1) a magnesium oxide, (2) an aluminum trihalide, (3) a hydroxy compound represented by the general formula ROH wherein R is an organic radical having 1 to 20 carbon atoms and (4) a titanium halide and/or an addition product of a titanium halide and an aromatic carboxylic acid ester, and [B] an organometallic compound and/or an addition product of an organometallic compound and an aromatic carboxylic acid ester; or it consists of the solid component of the above [A], the organometallic compound and/or the addition product of an organometallic compound and an aromatic carboxylic acid ester of the above [B], and [C] an aromatic carboxylic acid ester. The said catalyst is prepared, in one of the most preferred embodiments thereof, by using the solid component of the above [A] which is obtained by first co-pulverizing the compounds of the above (1),(2) and (3), then washing the co-pulverized product with an aromatic compound, separating the liquid phase to give a solid substance (a) and contacting the latter with the compound and/or the addition product of the above (4).

    摘要翻译： 本发明提供使用新催化剂制备聚烯烃的方法。 根据本发明，通过使用这种新的催化剂，α-烯烃可以聚合或共聚以具有良好的立构规整性和高活性。 本发明中使用的新型催化剂由[A]一种固体组分组成，该固体组分通过使（1）氧化镁，（2）三卤化铝，（3）由通式ROH表示的羟基化合物，其中R是有机基团 具有1至20个碳原子和（4）卤化钛和/或卤化钛和芳族羧酸酯的加成产物，和[B]有机金属化合物和/或有机金属化合物和芳族化合物的加成产物 羧酸酯; 或者由上述[A]的固体组分，有机金属化合物和/或上述[B]的有机金属化合物和芳族羧酸酯的加成产物和[C]芳族羧酸酯组成。 所述催化剂在其最优选的实施方案之一中，通过使用上述[A]的固体成分，其是通过首先共混上述（1），（2）和（3）的化合物而获得的， ，然后用芳族化合物洗涤共粉碎产物，分离液相，得到固体物质（a），并使其与上述（4）的化合物和/或加成产物接触。

    Process for preparing polyolefins
    2.
    发明授权
    Process for preparing polyolefins 失效
    聚烯烃的制备方法

    公开(公告)号：US4525555A

    公开(公告)日：1985-06-25

    申请号：US561936

    申请日：1983-12-15

    申请人： Yoshio Tajima ,  Mituji Miyoshi ,  Shoji Sugita ,  Kiyoshi Kawabe ,  Kazuo Matsuura

    发明人： Yoshio Tajima ,  Mituji Miyoshi ,  Shoji Sugita ,  Kiyoshi Kawabe ,  Kazuo Matsuura

    IPC分类号： C08F4/10 ,  C08F4/12 ,  C08F4/16 ,  C08F4/50 ,  C08F4/64 ,  C08F10/00 ,  C08F4/44 ,  C08F10/04

    CPC分类号： C08F10/00

    摘要： Provided is a process for preparing a polyolefin, characterized by polymerizing at least one .alpha.-olefin in the presence of a catalyst which comprises the combination of:[I] a solid catalyst component comprising a solid substance obtained by contacting the following components (1) through (3) with one another and (4) a titanium compound supported on said solid substance:(1) a magnesium halide,(2) a compound represented by the general formula ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are each a hydrocarbon radical having 1 to 24 carbon atoms, an alkoxy group, hydrogen, or a halogen atom, R.sup.4 is a hydrocarbon radical having 1 to 24 carbon atoms and n is 1.ltoreq.n.ltoreq.30, and(3) at least one compound selected from the group consisting of:(a) compounds represented by the general formula ##STR2## wherein R is hydrogen, a halogen atom, or a hydrocarbon radical having 1 to 24 carbon atoms, and r, p and q are integers satisfying the following conditions:1.ltoreq.r.ltoreq.3, 0.ltoreq.p

    摘要翻译： 提供了一种制备聚烯烃的方法，其特征在于在催化剂存在下使至少一种α-烯烃聚合，所述催化剂包含以下组合：[I]包含通过使下列组分（1）接触获得的固体物质的固体催化剂组分， 通过（3）彼此和（4）负载在所述固体物质上的钛化合物：（1）卤化镁，（2）由通式“IMAGE”表示的化合物，其中R 1，R 2和R 3各自为烃 具有1至24个碳原子的基团，烷氧基，氢或卤素原子，R 4是具有1至24个碳原子的烃基，n是1≤n≤30，和（3）至少一个 选自以下的化合物：（a）由通式表示的化合物，其中R是氢，卤素原子或具有1至24个碳原子的烃基，并且r，p和q是满足 以下条件：1 r + p + q <6，（b）烷基 亚磷酸酯，（c） - （e）氧，氮或含硫杂环羧酸酯，（f）烷基硅烷醇，（g）烷氧基硼卤化物，（h）烷基和/或烷氧基取代的亚砜，和（i） 取代的氨基甲酸酯[II]有机金属化合物; 和[III]由通式表示的化合物，其中R 1，R 2和R 3各自为具有1至24个碳原子的烃基，烷氧基，氢或卤素原子，R 4为具有1 至24个碳原子，n为1

    Process for preparing polyolefins
    4.
    发明授权
    Process for preparing polyolefins 失效
    聚烯烃的制备方法

    公开(公告)号：US4093789A

    公开(公告)日：1978-06-06

    申请号：US705607

    申请日：1976-07-15

    申请人： Nobuyuki Kuroda ,  Toru Nakamura ,  Takeichi Shiraishi ,  Kazuo Matsuura ,  Mituji Miyoshi

    发明人： Nobuyuki Kuroda ,  Toru Nakamura ,  Takeichi Shiraishi ,  Kazuo Matsuura ,  Mituji Miyoshi

    IPC分类号： C08F4/00 ,  C08F4/02 ,  C08F4/60 ,  C08F4/64 ,  C08F10/00 ,  C08F10/02

    CPC分类号： C08F10/00 ,  C08F4/022 ,  Y10S526/903 ,  Y10S526/906

    摘要： According to the present invention, there is provided a process for preparing polyolefins by polymerizing or copolymerizing olefins in the presence of a catalyst consisting of a solid component and an organometallic compound component, characterized in that said solid component is obtained by copulverizing(1) a magnesium halide and/or a manganese halide,(2) an aromatic hydrocarbon,(3) a tetravalent titanium compound, and(4) a trivalent titanium compoundAnd in that said organometallic compound component is a mixture of(5) a trialkylaluminum and(6) a compound represented by the general formula AlR.sub.n X.sub.3-n wherein R is alkyl having 1 to 10 carbon atoms and may be the same or different, X is halogen and O

    摘要翻译： 根据本发明，提供一种通过在由固体成分和有机金属化合物成分组成的催化剂存在下聚合或共聚烯烃制备聚烯烃的方法，其特征在于所述固体组分通过共混（1）A （2）芳族碳氢化合物，（3）四价钛化合物，和（4）多价钛化合物，以及所述有机元素化合物组分是（5）三烯丙基铝和（ 6）由通式AlRnX 3-n表示的化合物，其中R是具有1至10个碳原子的烷基并且可以相同或不同，X是卤素且O

    Process for preparing a copolymer
    6.
    发明授权
    Process for preparing a copolymer 失效
    制备共聚物的方法

    公开(公告)号：US4322514A

    公开(公告)日：1982-03-30

    申请号：US122987

    申请日：1980-02-20

    申请人： Mituji Miyoshi ,  Kazuo Matsuura ,  Yoshio Tajima

    发明人： Mituji Miyoshi ,  Kazuo Matsuura ,  Yoshio Tajima

    IPC分类号： C08F4/00 ,  C08F4/02 ,  C08F4/60 ,  C08F4/64 ,  C08F210/00 ,  C08F210/06 ,  C08F210/16 ,  C08F10/00

    CPC分类号： C08F210/06 ,  Y10S526/916

    摘要： According to this invention, there is provided a process for preparing a non- or low-crystalline soft copolymer, characterized in that 50 to 98 mole % of propylene, 0.2 to 30 mole % of ethylene and 0.2 to 45 mole % of a straight-chained .alpha.-olefin having not less than four carbon atoms are copolymerized using a catalyst, said catalyst comprising (1) a solid substance containing magnesium and titanium and (2) an organometallic compound.

    摘要翻译： 根据本发明，提供了一种制备非 - 或低 - 结晶软共聚物的方法，其特征在于，50-98摩尔％的丙烯，0.2-30摩尔％的乙烯和0.2-45摩尔％的直链 - 具有不少于4个碳原子的链状α-烯烃使用催化剂共聚，所述催化剂包含（1）含镁和钛的固体物质和（2）有机金属化合物。

    Continuous process for the preparation of polyolefins having widely distributed molecular weights
    8.
    发明授权
    Continuous process for the preparation of polyolefins having widely distributed molecular weights 失效
    用于制备具有广泛分布分子量的聚烯烃的连续方法

    公开(公告)号：US4414369A

    公开(公告)日：1983-11-08

    申请号：US138104

    申请日：1980-04-07

    申请人： Nobuyuki Kuroda ,  Tatsuo Horie ,  Kazuo Matsuura ,  Kunimichi Kubo ,  Mituji Miyoshi

    发明人： Nobuyuki Kuroda ,  Tatsuo Horie ,  Kazuo Matsuura ,  Kunimichi Kubo ,  Mituji Miyoshi

    IPC分类号： C08F10/00 ,  C08F2/14 ,  C08F4/66

    CPC分类号： C08F10/00 ,  Y10S526/905

    摘要： Polyolefins having a wide distribution of molecular weights are prepared in a plural stage process, by initially polymerizing the olefins in the presence of a solvent, hydrogen and a highly active Ziegler type catalyst under pressure, and beneath a gas phase containing an inert gas, to form in the first stage a polymer having a relatively high molecular weight. The polymerization reaction mixture from the first stage is continuously flowed to a second stage reactor. The second stage reactor is maintained at a relatively lower pressure, such that the flow is driven by the higher pressure in the first stage. The second stage is agitated and the polymerization reaction mixture is maintained beneath an atmosphere containing olefins and hydrogen gas. Polymers of relatively low molecular weight are formed in the second stage. The product continuously removed from the second stage contains a polymer having a wide distribution of molecular weight.

    摘要翻译： 通过在溶剂，氢气和高活性齐格勒型催化剂的存在下，在压力下，在含有惰性气体的气相之下，在烯烃存在下，首先使烯烃聚合，在多级方法中制备分子量分布广泛的聚烯烃， 在第一阶段形成具有相对较高分子量的聚合物。 将来自第一阶段的聚合反应混合物连续流入第二级反应器。 第二级反应器保持在相对较低的压力下，使得流在第一级中被较高的压力驱动。 搅拌第二阶段，聚合反应混合物保持在含有烯烃和氢气的气氛下。 在第二阶段形成相对低分子量的聚合物。 从第二阶段连续除去的产物含有分子量分布广泛的聚合物。

    Process for preparing polyolefins
    9.
    发明授权
    Process for preparing polyolefins 失效
    聚烯烃的制备方法

    公开(公告)号：US4022958A

    公开(公告)日：1977-05-10

    申请号：US604442

    申请日：1975-08-13

    申请人： Kazuo Matsuura ,  Nobuyuki Kuroda ,  Toru Nakamura ,  Mituji Miyoshi

    发明人： Kazuo Matsuura ,  Nobuyuki Kuroda ,  Toru Nakamura ,  Mituji Miyoshi

    IPC分类号： C08F10/00 ,  C08F4/02 ,  C08F10/02

    CPC分类号： C08F10/00

    摘要： The present invention relates to a process for preparing polyolefins using an improved polymerization catalyst. According to the invention, there is provided a process for preparing polyolefins by polymerizing or copolymerizing olefins using a catalyst prepared from a component with a titanium compound and/or a vanadium compound supported on a solid carrier and an organoaluminum compound and/or an organozinc compound, said solid carrier comprising a member selected from the group consisting of a reaction product A obtained by reacting (1) an organic carboxylate salt of magnesium and (2) an aluminum compound represented by the general formula Al(OR).sub.3 wherein R may be same as or different from each other and each R is an organic radical containing from 1 to 20 carbon atoms under such a condition that the aluminum compound is present in excess of a (2):(1) molar ratio of at least 1.6:1 and a reaction product B obtained by treating said reaction product A with a halogenating agent.

    摘要翻译： 本发明涉及使用改进的聚合催化剂制备聚烯烃的方法。 根据本发明，提供了一种通过使用由具有钛化合物和/或负载在固体载体上的钒化合物和有机铝化合物和/或有机锌化合物的组分制备的催化剂聚合或共聚烯烃来制备聚烯烃的方法 所述固体载体包含选自由以下组成的组的成员：（1）镁的有机羧酸盐与（2）由通式Al（OR）3表示的铝化合物反应得到的反应产物A，其中R可以是 相同或不同，每个R是含有1至20个碳原子的有机基团，条件是铝化合物以超过（2）：（1）摩尔比为至少1.6：1 和通过用卤化剂处理所述反应产物A得到的反应产物B.