公开(公告)号：US6028265A

公开(公告)日：2000-02-22

申请号：US988399

申请日：1997-12-10

申请人： Yoshiyuki Ono ,  Akira Imai ,  Hidekazu Hirose ,  Katsuhiro Sato

发明人： Yoshiyuki Ono ,  Akira Imai ,  Hidekazu Hirose ,  Katsuhiro Sato

IPC分类号： H01L31/04 ,  H01G9/20 ,  H01L51/00 ,  H01L51/30 ,  H01M14/00 ,  H01L31/0224 ,  H01L31/042 ,  H01L31/055

CPC分类号： H01G9/2031 ,  H01L51/0073 ,  H01L51/0077 ,  H01L51/4226 ,  H01L51/005 ,  H01L51/0053 ,  H01L51/0078 ,  Y02E10/542 ,  Y02E10/549

摘要： The photo-semiconducting electrode of the present invention comprises a semiconducting substrate, a chemically adsorbed film formed thereon composed of at least one compound selected from the compounds represented by the formulas: formulas (I) R.sup.1 M.sup.1 Y.sub.1.sub.3, (II) R.sup.1 R.sup.2 M.sup.1 Y.sup.1.sub.2, (III) R.sup.1 R.sup.2 R.sup.3 M.sup.1 Y.sup.1 and (IV) R.sup.1 --SH, respectively, and a dye which is fixed to the surface of the chemically adsorbed film and has a functional group capable of reacting with a halogen atom. Because of this, the photo-semiconductor electrode of the present invention is capable of efficiently absorbing solar light and performing energy conversion and superior in photoelectric conversion efficiency, stability and durability. In addition, it can be easily produced.

摘要翻译： 本发明的光半导体电极包括半导体衬底，在其上形成的化学吸附膜，由至少一种选自下式表示的化合物：式（I）R1M1Y13，（Ⅱ）R1R2M1Y12，（Ⅲ）R1R2R3M1Y1 和（IV）R1-SH，以及固定在化学吸附膜表面并具有与卤原子反应的官能团的染料。 因此，本发明的光电半导体电极能够有效地吸收太阳光并进行能量转换，光电转换效率，稳定性和耐久性优异。 此外，它可以很容易地生产。

公开(公告)号：US06252156B1

公开(公告)日：2001-06-26

申请号：US09098519

申请日：1998-06-17

申请人： Yoshiyuki Ono ,  Hidekazu Hirose ,  Katsuhiro Sato ,  Akira Imai

发明人： Yoshiyuki Ono ,  Hidekazu Hirose ,  Katsuhiro Sato ,  Akira Imai

IPC分类号： H01L310264

CPC分类号： H01G9/2031 ,  H01G9/2059 ,  H01L51/0086 ,  H01L51/009 ,  Y02E10/542 ,  Y02P70/521

摘要： Disclosed is an aggregate of metal oxide fine particles having fine pores whose size frequency distribution has a plurality of peaks. Disclosed also is a method preferably used for producing the aggregate of metal oxide fine particles. The method comprises a step of reacting a precursor of a metal oxide with a compound interacting with the precursor in a solvent to yield metal oxide fine particles. Also disclosed are a photosensitive semiconductor comprising a substrate, and a metal oxide porous body having fine pores whose size frequency distribution has a plurality of peaks and a method preferably used for manufacturing the photosensitive semiconductor electrode. This photosensitive semiconductor electrode has a high energy conversion efficiency and is preferably used in a photoelectric converter.

摘要翻译： 公开了具有细孔的具有多个峰的金属氧化物微粒的集合体。 还公开了一种优选用于制造金属氧化物微粒聚集体的方法。 该方法包括使金属氧化物的前体与在溶剂中与前体相互作用的化合物反应以产生金属氧化物细颗粒的步骤。 还公开了一种光敏半导体，其包含基板和具有细孔的金属氧化物多孔体，其尺寸频率分布具有多个峰，以及优选用于制造感光半导体电极的方法。 该感光性半导体电极具有高的能量转换效率，优选用于光电转换器。

公开(公告)号：US6153824A

公开(公告)日：2000-11-28

申请号：US227814

申请日：1999-01-11

申请人： Hokuto Takada ,  Hidekazu Hirose ,  Yoshiyuki Ono ,  Akira Imai ,  Katsuhiro Sato

发明人： Hokuto Takada ,  Hidekazu Hirose ,  Yoshiyuki Ono ,  Akira Imai ,  Katsuhiro Sato

IPC分类号： H01L51/42 ,  H01G9/20 ,  H01L51/00 ,  H01L51/30 ,  H01L51/40 ,  H01M14/00 ,  H01L31/0224 ,  C25B11/06

CPC分类号： H01L51/0086 ,  H01G9/2059 ,  H01L51/0078 ,  H01L51/0084 ,  H01L51/0085 ,  H01L51/0089 ,  H01L51/0003 ,  H01L51/004 ,  H01L51/0053 ,  H01L51/424 ,  Y02E10/542 ,  Y02E10/549

摘要： Disclosed are a photo-semiconductive electrode that has a high light-to-electricity conversion efficiency and excellent stability and can be prepared economically and easily, and a photo-electric cell using the photo-semiconductive electrode. The photo-electric cell comprises a photo-semiconductive electrode having an electroconductive base and a light-to-electricity conversion layer formed thereon, and a counter electrode, such that the photo-semiconductive electrode and the counter electrode contact an electrolyte, wherein the light-to-electricity conversion layer holds an organic pigment. In the photo-electric cell, the photo-semiconductive electrode and the counter electrode are used integrally and disposed so that these electrodes contact the electrolyte. The organic pigment suited for use in the layer is selected from the group consisting of: phthalocyanine pigment such as titanyl phthalocyanine, chlorogallium phthalocyanine and hydroxygallium phthalocyanine; and naphthalocyanine pigments.

摘要翻译： 公开了一种具有高的光电转换效率和优异的稳定性并且可以经济且容易地制备的光半导体电极，以及使用光半导体电极的光电池。 光电池包括具有形成在其上的导电基底和光电转换层的光半导体电极和对电极，使得光半导体电极和对电极接触电解质，其中光 电转换层保持有机颜料。 在光电池中，光半导体电极和对电极被一体地使用并且被设置成使得这些电极接触电解质。 适用于该层的有机颜料选自：酞菁颜料如氧钛酞菁，氯镓酞菁和羟基镓酞菁; 和萘酞菁颜料。

公开(公告)号：US06284365B1

公开(公告)日：2001-09-04

申请号：US08916787

申请日：1997-08-25

申请人： Hidekazu Hirose ,  Yoshiyuki Ono ,  Katsuhiro Sato ,  Akira Imai

发明人： Hidekazu Hirose ,  Yoshiyuki Ono ,  Katsuhiro Sato ,  Akira Imai

IPC分类号： C09K300

CPC分类号： B05D1/185 ,  B01J31/1633 ,  B01J31/1805 ,  B01J31/1815 ,  B01J31/183 ,  B01J2531/025 ,  B01J2531/821 ,  B01J2531/845 ,  B82Y30/00 ,  B82Y40/00 ,  Y10T428/261 ,  Y10T428/2993 ,  Y10T428/2995 ,  Y10T428/31536 ,  Y10T428/31612 ,  Y10T428/31663 ,  Y10T428/31667

摘要： A method for producing a composite material, wherein compound A having a group selected from an aliphatic hydrocarbon group, aromatic hydrocarbon group and heterocycle-containing group which comprises a functional group which can bond to a compound B allowed to bond to a substrate, then compound B having a functional group which can bond to said functional group in compound A is allowed to bond to compound A is disclosed. Embodiments in which compound A is represented by formula (1); R1M1Y13, formula (2); R1R2M1Y12, formula (3); R1R2R3M1Y1 and formula (4); R1—SH: embodiments in which compound A is a silane compound: the functional group of compound A is a halogen group or an epoxy group: and embodiments in which compound B is selected from aliphatic hydrocarbon compounds, aromatic hydrocarbon compounds and heterocycle-containing compounds having an amino group, carboxyl group or hydroxyl group, are preferred.

摘要翻译： 一种复合材料的制造方法，其中，具有选自脂肪族烃基，芳香族烃基，含有杂环基团的化合物A，所述基团含有可与键合到基材上的化合物B键合的官能团， 公开了具有与化合物A中的所述官能团结合的官能团的B可以与化合物A键合。 化合物A由式（1）表示的实施方案; R1M1Y13，式（2）; R1R2M1Y12，式（3）; R1R2R3M1Y1和式（4）; R1-SH：化合物A为硅烷化合物的实施方案：化合物A的官能团为卤素基团或环氧基，其中化合物B选自脂族烃化合物，芳族烃化合物和含杂环化合物 具有氨基，羧基或羟基。

公开(公告)号：US06653701B1

公开(公告)日：2003-11-25

申请号：US09520441

申请日：2000-03-07

申请人： Yoshihisa Yamazaki ,  Yoshiyuki Ono ,  Hokuto Takada ,  Katsuhiro Sato ,  Akira Imai ,  Hidekazu Hirose

发明人： Yoshihisa Yamazaki ,  Yoshiyuki Ono ,  Hokuto Takada ,  Katsuhiro Sato ,  Akira Imai ,  Hidekazu Hirose

IPC分类号： H01L5120

CPC分类号： H01L51/4233 ,  H01G9/2031 ,  H01L31/0322 ,  H01L31/072 ,  H01L31/0749 ,  H01L31/18 ,  H01L31/1836 ,  H01L51/0086 ,  H01L51/422 ,  H01L51/4226 ,  Y02E10/541 ,  Y02E10/542 ,  Y02E10/549 ,  Y02P70/521

摘要： A semiconductor device having laminated successively a porous semiconductor layer, an inorganic semiconductor layer, and optionally an organic substance layer formed therebetween is disclosed. The semiconductor device is produced by immersing a porous semiconductor layer or a semiconductor layer having an organic substance layer on the surface thereof in a solution containing the elements constituting an inorganic semiconductor or compounds of the elements and forming the inorganic semiconductor layer on the porous semiconductor layer or the organic substance layer in the solution.

摘要翻译： 公开了一种半导体器件，其间依次层叠多孔半导体层，无机半导体层和可选地在其间形成的有机物质层。 半导体器件通过将表面上具有有机物质层的多孔半导体层或半导体层浸渍在含有构成无机半导体的元素的溶液或元素化合物的溶液中，并在多孔半导体层上形成无机半导体层 或溶液中的有机物质层。

公开(公告)号：US08264140B2

公开(公告)日：2012-09-11

申请号：US12051479

申请日：2008-03-19

申请人： Koji Horiba ,  Hidekazu Hirose ,  Tadayoshi Ozaki ,  Yohei Nishino ,  Mieko Seki ,  Takeshi Agata ,  Akira Imai ,  Katsuhiro Sato ,  Kiyokazu Mashimo ,  Hirohito Yoneyama ,  Toru Ishii ,  Daisuke Okuda

发明人： Koji Horiba ,  Hidekazu Hirose ,  Tadayoshi Ozaki ,  Yohei Nishino ,  Mieko Seki ,  Takeshi Agata ,  Akira Imai ,  Katsuhiro Sato ,  Kiyokazu Mashimo ,  Hirohito Yoneyama ,  Toru Ishii ,  Daisuke Okuda

IPC分类号： H01L51/54 ,  H05B33/14 ,  C09K11/06 ,  C08G63/66

CPC分类号： C09K11/06 ,  C07D413/14 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1014 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/1048 ,  C09K2211/1092 ,  H01L51/0035 ,  H01L51/5012 ,  H01L51/5048 ,  H05B33/14 ,  Y10T428/31786

摘要： An organic electroluminescence element includes a pair of electrodes composed of an anode and a cathode, at least one of which is transparent or semitransparent, and one or more organic compound layers disposed between the pair of electrodes, wherein at least one of the organic compound layers comprises at least one charge-transporting polyester consisting of repeating units containing, as a partial structure, at least one structure represented by the following formula (I-1).

摘要翻译： 有机电致发光元件包括由阳极和阴极组成的一对电极，其中至少一个是透明或半透明的，并且一个或多个有机化合物层设置在该对电极之间，其中至少一个有机化合物层 包含至少一种由包含由下式（I-1）表示的至少一种结构作为部分结构的重复单元组成的电荷输送性聚酯。

公开(公告)号：US08420814B2

公开(公告)日：2013-04-16

申请号：US13490826

申请日：2012-06-07

申请人： Akira Imai ,  Hidekazu Hirose ,  Koji Horiba ,  Takeshi Agata ,  Katsuhiro Sato

发明人： Akira Imai ,  Hidekazu Hirose ,  Koji Horiba ,  Takeshi Agata ,  Katsuhiro Sato

IPC分类号： C07D403/14 ,  C07D409/14 ,  H01J1/63 ,  C09K11/06

CPC分类号： C07D409/04

摘要： A nitrogen-containing heterocyclic compound is represented by Formula (I): wherein R1 represents a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, or a substituted or unsubstituted alkoxy group having 1 to 20 carbon atoms; A represents a heterocyclic residue that contains at least one nitrogen atom and forms a six-membered aromatic heterocyclic ring; and n represents an integer of from 1 to 3.

摘要翻译： 含氮杂环化合物由式（I）表示：其中R1表示氢原子，取代或未取代的碳原子数1〜20的烷基或取代或未取代的碳原子数1〜20的烷氧基。 A表示含有至少一个氮原子并形成六元芳族杂环的杂环残基; n表示1〜3的整数。

公开(公告)号：US07902382B2

公开(公告)日：2011-03-08

申请号：US12591678

申请日：2009-11-27

申请人： Yoshihiro Ohba ,  Kazuaki Sato ,  Mieko Seki ,  Hidekazu Hirose ,  Takeshi Agata ,  Koji Horiba ,  Akira Imai ,  Tadayoshi Ozaki ,  Yohei Nishino ,  Hirohito Yoneyama ,  Daisuke Okuda ,  Toru Ishii ,  Kiyokazu Mashimo ,  Katsuhiro Sato

发明人： Yoshihiro Ohba ,  Kazuaki Sato ,  Mieko Seki ,  Hidekazu Hirose ,  Takeshi Agata ,  Koji Horiba ,  Akira Imai ,  Tadayoshi Ozaki ,  Yohei Nishino ,  Hirohito Yoneyama ,  Daisuke Okuda ,  Toru Ishii ,  Kiyokazu Mashimo ,  Katsuhiro Sato

IPC分类号： C07D333/22

CPC分类号： C07D333/08 ,  C07D333/18 ,  C07D409/10 ,  C07D409/14 ,  H01L51/0036 ,  H01L51/0052 ,  H01L51/006 ,  H01L51/0061 ,  H01L51/0068

摘要： A thiophene-containing compound polymer represented by Y represents a bivalent hydrocarbon group; R5 represents a hydrogen atom; Z represents a bivalent hydrocarbon group; m represents 1; p represents an integer of 5 to 5,000; B and B′ each represent OCH2CH2OH, and A represents a group represented by the following formula (X-III): Ar1 is a substituted or unsubstituted monovalent aromatic group; R1 to R3 each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted aralkyl group; and n representing an integer of 1 to 5.

摘要翻译： 由Y表示的含噻吩的化合物聚合物表示二价烃基; R5代表氢原子; Z表示二价烃基; m表示1; p表示5〜5000的整数， B和B'各自表示OCH 2 CH 2 OH，A表示由下式（X-III）表示的基团：Ar 1表示取代或未取代的1价芳香族基团。 R 1至R 3各自独立地表示氢原子，取代或未取代的烷基，取代或未取代的芳基或取代或未取代的芳烷基; n表示1〜5的整数。

公开(公告)号：US07812172B2

公开(公告)日：2010-10-12

申请号：US12430361

申请日：2009-04-27

申请人： Koji Horiba ,  Hidekazu Hirose ,  Akira Imai ,  Katsuhiro Sato ,  Takeshi Agata

发明人： Koji Horiba ,  Hidekazu Hirose ,  Akira Imai ,  Katsuhiro Sato ,  Takeshi Agata

IPC分类号： C07D513/04

CPC分类号： C07D513/04

摘要： A thiazolothiazole derivative is represented by the following Formula (I). In Formula (I), each R1 independently represents a straight chain alkyl group having 3 to 20 carbon atoms, a straight chain alkoxy group having 3 to 20 carbon atoms, a branched alkyl group having 3 to 20 carbon atoms, or a branched alkoxy group having 3 to 20 carbon atoms; and each R2 independently represents a hydrogen atom, a straight chain alkyl group having 1 to 20 carbon atoms, a straight chain alkoxy group having 1 to 20 carbon atoms, a branched alkyl group having 3 to 20 carbon atoms, or a branched alkoxy group having 3 to 20 carbon atoms.

摘要翻译： 噻唑并噻唑衍生物由下式（I）表示。 式（I）中，R 1各自独立地表示碳原子数3〜20的直链烷基，碳原子数3〜20的直链烷氧基，碳原子数3〜20的支链烷基或支链烷氧基 具有3至20个碳原子; R2各自独立地表示氢原子，碳原子数1〜20的直链烷基，碳原子数1〜20的直链烷氧基，碳原子数3〜20的支链烷基，或具有 3至20个碳原子。

公开(公告)号：US20100133995A1

公开(公告)日：2010-06-03

申请号：US12591681

申请日：2009-11-27

申请人： Yoshihiro Ohba ,  Kazuaki Sato ,  Mieko Seki ,  Hidekazu Hirose ,  Takeshi Agata ,  Koji Horiba ,  Akira Imai ,  Tadayoshi Ozaki ,  Yohei Nishino ,  Hirohito Yoneyama ,  Daisuke Okuda ,  Toru Ishii ,  Kiyokazu Mashimo ,  Katsuhiro Sato

发明人： Yoshihiro Ohba ,  Kazuaki Sato ,  Mieko Seki ,  Hidekazu Hirose ,  Takeshi Agata ,  Koji Horiba ,  Akira Imai ,  Tadayoshi Ozaki ,  Yohei Nishino ,  Hirohito Yoneyama ,  Daisuke Okuda ,  Toru Ishii ,  Kiyokazu Mashimo ,  Katsuhiro Sato

IPC分类号： H01J1/63

CPC分类号： C07D333/08 ,  C07D333/18 ,  C07D409/10 ,  C07D409/14 ,  H01L51/0036 ,  H01L51/0052 ,  H01L51/006 ,  H01L51/0061 ,  H01L51/0068

摘要： An organic electroluminescent device with a pair of electrodes having an anode and a cathode, and one or more organic compound layers disposed therebetween. One of the anode or the cathode is transparent or semitransparent. One of the organic compound layers includes a charge-transporting polyester having a repeating structure containing at least one structure selected from the structures represented by the following formulae as a partial structure: Ar represents an unsubstituted monovalent phenyl group, an unsubstituted monovalent polynuclear aromatic hydrocarbon having 2 to 10 aromatic rings, an unsubstituted monovalent fused aromatic hydrocarbon having 2 to 10 aromatic rings, or an unsubstituted monovalent fused aromatic hydrocarbon having 2 to 10 aromatic rings, or an unsubstituted monovalent aromatic heterocyclic ring; X represents a group represented by the following formula (II); T represents a bivalent straight-chain hydrocarbon group having 1 to 6 carbon atoms; k represents O; and l represents 1: R1 and R2 each represent a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted aralkyl group; and n represents an integer of 1 to 10.

摘要翻译： 一种具有一对具有阳极和阴极的电极以及一个或多个有机化合物层的有机电致发光器件。 阳极或阴极中的一个是透明或半透明的。 有机化合物层之一包括具有重复结构的电荷输送性聚酯，该重复结构含有至少一种选自下式所示结构的部分结构：Ar表示未取代的一价苯基，未取代的一价多价芳族烃，具有 2〜10个芳香环，2〜10个芳香环的未取代单价稠合芳香烃，或2〜10个芳香环的未取代单价稠合芳香烃，或未取代的1价芳香族杂环; X表示由下式（II）表示的基团。 T表示碳原子数为1〜6的二价直链烃基。 k表示O; 和l表示1：R1和R2各自表示氢原子，取代或未取代的烷基，取代或未取代的芳基或取代或未取代的芳烷基; n表示1〜10的整数。