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    Highly active catalyst for atom transfer radical polymerization
    1.
    发明授权
    Highly active catalyst for atom transfer radical polymerization 有权
    用于原子转移自由基聚合的高活性催化剂

    公开(公告)号：US07994087B2

    公开(公告)日：2011-08-09

    申请号：US11599110

    申请日：2006-11-14

    申请人： Maciej Radosz ,  Youqing Shen ,  Huadong Tang

    发明人： Maciej Radosz ,  Youqing Shen ,  Huadong Tang

    IPC分类号： B01J31/00

    CPC分类号： C08F4/00 ,  C07D213/36 ,  C07F1/005

    摘要： A class of catalysts with unusually high activity for polymerizing vinyl monomers such as acrylates, methacrylates and styrene is described. The catalysts consists of a metal halide such as CuBr and FeBr2 ligated with multidentate amine-based ligands, for example N,N,N′,N′-tetra[(2-pyridal)methyl]ethylenediamine, and additives. The additives, which are tertiary amine compounds, can greatly increase the catalytic activity. The complex is capable of catalyzing a living polymerization reaction at a concentration of the complex below about 0.1 mol %.

    摘要翻译： 描述了一类用于聚合乙烯基单体如丙烯酸酯，甲基丙烯酸酯和苯乙烯的异常高活性的催化剂。 催化剂由诸如N，N，N'，N'-四[（2-吡啶基）甲基]乙二胺与多齿胺基配体连接的金属卤化物如CuBr和FeBr2和添加剂组成。 作为叔胺化合物的添加剂可以大大提高催化活性。 络合物能够催化在低于约0.1mol％的络合物浓度下的活性聚合反应。

    Highly active catalyst for atom transfer radical polymerization
    2.
    发明申请
    Highly active catalyst for atom transfer radical polymerization 有权
    用于原子转移自由基聚合的高活性催化剂

    公开(公告)号：US20070129239A1

    公开(公告)日：2007-06-07

    申请号：US11599110

    申请日：2006-11-14

    申请人： Maciej Radosz ,  Youqing Shen ,  Huadong Tang

    发明人： Maciej Radosz ,  Youqing Shen ,  Huadong Tang

    IPC分类号： B01J31/00

    CPC分类号： C08F4/00 ,  C07D213/36 ,  C07F1/005

    摘要： A class of catalysts with unusually high activity for polymerizing vinyl monomers such as acrylates, methacrylates and styrene is described. The catalysts consists of a metal halide such as CuBr and FeBr2 ligated with multidentate amine-based ligands, for example N,N,N′,N′-tetra[(2-pyridal)methyl]ethylenediamine, and additives. The additives, which are tertiary amine compounds, can greatly increase the catalytic activity. The complex is capable of catalyzing a living polymerization reaction at a concentration of the complex below about 0.1 mol %.

    摘要翻译： 描述了一类用于聚合乙烯基单体如丙烯酸酯，甲基丙烯酸酯和苯乙烯的异常高活性的催化剂。 催化剂由诸如N，N，N'，N'-四[（2-吡啶基）甲基]乙二胺与多齿胺类配体连接的金属卤化物如CuBr和FeBr 2 N 2结合。 ，和添加剂。 作为叔胺化合物的添加剂可以大大提高催化活性。 络合物能够催化在低于约0.1mol％的络合物浓度下的活性聚合反应。

    Polymers and copolymers of ionic liquids as radio frequency absorbing materials
    4.
    发明授权
    Polymers and copolymers of ionic liquids as radio frequency absorbing materials 有权
    离子液体的聚合物和共聚物作为射频吸收材料

    公开(公告)号：US08703902B2

    公开(公告)日：2014-04-22

    申请号：US11666900

    申请日：2005-11-10

    申请人： Maciej Radosz ,  Youqing Shen ,  Huadong Tang

    发明人： Maciej Radosz ,  Youqing Shen ,  Huadong Tang

    IPC分类号： C08G79/02 ,  C08G79/08 ,  C08G79/14 ,  C07D231/00

    CPC分类号： C08F8/44

    摘要： Polymerizable ionic liquid monomers and their corresponding polymers (poly(ionic liquid)s) are created and found to exhibit high absorption of radio frequency electromagnetic radiation, particularly in the microwave and radar bands. These materials are useful for coating objects to make them less reflective of radio frequency radiation and for making objects that absorb radio frequency radiation and are of minimal reflectivity to radio frequency radiation. Free-radical and condensation polymerization approaches are used in the preparation of the poly(ionic liquids).

    摘要翻译： 产生可聚合的离子液体单体及其相应的聚合物（聚（离子液体）），发现它们表现出对射频电磁辐射的高吸收，特别是在微波和雷达波段中。 这些材料对于涂覆物体是有用的，使得它们对射频辐射反射较少，并且用于吸收射频辐射并且对射频辐射具有最小反射率的物体。 自由基和缩聚方法用于制备聚（离子液体）。

    Amine-Containing Compounds for Enhancing the Activity of ATRP Catalysts and Removal of the Terminal Halogen Groups from the ATRP Polymer Products
    5.
    发明申请
    Amine-Containing Compounds for Enhancing the Activity of ATRP Catalysts and Removal of the Terminal Halogen Groups from the ATRP Polymer Products 审中-公开
    用于提高ATRP催化剂活性和从ATRP聚合物产品中除去末端卤素基团的含胺化合物

    公开(公告)号：US20090156771A1

    公开(公告)日：2009-06-18

    申请号：US11958336

    申请日：2007-12-17

    申请人： Youqing Shen ,  Huadong Tang ,  Maciej Radosz

    发明人： Youqing Shen ,  Huadong Tang ,  Maciej Radosz

    IPC分类号： C08F8/26 ,  C07F1/08

    CPC分类号： C07F1/005 ,  C08F2/38 ,  C08F4/00 ,  C08F4/10 ,  C08F8/26 ,  C08F12/06 ,  C08F120/14 ,  C08F112/08 ,  C08F20/12

    摘要： Disclosed are new, highly active and versatile atom transfer radical polymerization (ATRP) catalysts. These catalysts catalyze ATRP for acrylates, methacrylates, and styrenes at surprisingly low concentrations. These catalysts mediated ATRP at a catalyst/initiator molar ratio at 0.005 and produced polymers with well-controlled molecular weights and low polydispersities. ATRP occurred even at a catalyst/initiator molar ratio as low as 0.001 with metal concentration in the produced polymers as low as 6-8 ppm. Amine-containing compounds, such as triethylamine, can significantly increase the catalyst activity of theses catalysts. The amine compounds can also used to the terminal halogen groups such as Br and Cl in the polymers prepared by ATRP.

    摘要翻译： 公开了新的，高活性和通用的原子转移自由基聚合（ATRP）催化剂。 这些催化剂以令人惊讶的低浓度催化丙烯酸酯，甲基丙烯酸酯和苯乙烯的ATRP。 这些催化剂以0.005的催化剂/引发剂摩尔比介导ATRP，并产生具有良好控制的分子量和低多分散性的聚合物。 即使催化剂/引发剂摩尔比低至0.001，生成的聚合物中的金属浓度低至6-8ppm也发生ATRP。 含胺化合物如三乙胺可显着提高这些催化剂的催化剂活性。 在ATRP制备的聚合物中，胺化合物也可用于末端卤素基团如Br和Cl。

    Polymers and Copolymers of Ionic Liquids as Radio Frequency Absorbing Materials
    6.
    发明申请
    Polymers and Copolymers of Ionic Liquids as Radio Frequency Absorbing Materials 有权
    离子液体的聚合物和共聚物作为射频吸收材料

    公开(公告)号：US20080125559A1

    公开(公告)日：2008-05-29

    申请号：US11666900

    申请日：2005-11-10

    申请人： Maciej Radosz ,  Youqing Shen ,  Huadong Tang

    发明人： Maciej Radosz ,  Youqing Shen ,  Huadong Tang

    IPC分类号： C08F30/06 ,  C08G79/08

    CPC分类号： C08F8/44

    摘要： Polymerizable ionic liquid monomers and their corresponding polymers (poly(ionic liquid)s) are created and found to exhibit high absorption of radio frequency electromagnetic radiation, particularly in the microwave and radar bands. These materials are useful for coating objects to make them less reflective of radio frequency radiation and for making objects that absorb radio frequency radiation and are of minimal reflectivity to radio frequency radiation. Free-radical and condensation polymerization approaches are used in the preparation of the poly(ionic liquids).

    摘要翻译： 产生可聚合的离子液体单体及其相应的聚合物（聚（离子液体）），发现它们表现出对射频电磁辐射的高吸收，特别是在微波和雷达波段中。 这些材料对于涂覆物体是有用的，使得它们对射频辐射反射较少，并且用于吸收射频辐射并且对射频辐射具有最小反射率的物体。 自由基和缩聚方法用于制备聚（离子液体）。

    NOVEL APPLICATION OF FIBRINOGEN-420 AND ITS ACTIVE DOMAIN
    7.
    发明申请
    NOVEL APPLICATION OF FIBRINOGEN-420 AND ITS ACTIVE DOMAIN 审中-公开
    FIBRINOGEN-420及其活性域的新应用

    公开(公告)号：US20120165510A1

    公开(公告)日：2012-06-28

    申请号：US13254987

    申请日：2010-03-05

    申请人： Luo Yongzhang ,  Huadong Tang ,  Yan Fu

    发明人： Luo Yongzhang ,  Huadong Tang ,  Yan Fu

    IPC分类号： C07K14/75

    CPC分类号： C07K14/75 ,  A61K38/363

    摘要： The invention discloses a novel application of fibrinogen-420 and its active domain (alpha EC domain), and a separate alpha EC domain protein has the same or similar function with fibrinogen-420. Fibrinogen-420 and its active domain can be widely used in inhibiting protein aggregation, helping protein refolding, drugs which can prevent and/or treat protein conformation disease, detecting denatured protein in quality control and protect protein from denaturation.

    摘要翻译： 本发明公开了一种纤维蛋白原420及其活性结构域（αEC结构域）的新应用，单独的αEC结构域蛋白与纤维蛋白原-F4具有相同或相似的功能。 纤维蛋白原420及其活性结构域可广泛用于抑制蛋白质聚集，有助于蛋白质重折叠，可预防和/或治疗蛋白质构象疾病的药物，检测质量控制中的变性蛋白质，保护蛋白质免于变性。