公开(公告)号：US20120235098A1

公开(公告)日：2012-09-20

申请号：US13501306

申请日：2010-12-07

申请人： Yuichi Ishikawa ,  Koji Tanoue ,  Takatoshi Fujino

发明人： Yuichi Ishikawa ,  Koji Tanoue ,  Takatoshi Fujino

IPC分类号： H01B1/00 ,  H01B1/20 ,  B32B5/16 ,  B82Y40/00 ,  B82Y30/00

CPC分类号： C01G15/006 ,  B82Y30/00 ,  C01B19/002 ,  C01G3/006 ,  C01P2002/50 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/52 ,  C01P2004/64 ,  C01P2006/40 ,  C01P2006/80 ,  H01L21/02568 ,  H01L21/02601 ,  H01L21/02628 ,  H01L31/0322 ,  Y02E10/541 ,  Y02P70/521 ,  Y10T428/2982

摘要： Chalcogen compound powder containing Cu—In—Ga—Se and having an average particle diameter (DSEM) of 80 nm or less and a low content of carbon is obtained by forming a mixed solvent by mixing together at least any one of a mixture of copper salt and indium salt, a composite hydroxide of copper and indium, and a composite oxide of copper and indium, any one of selenium and a selenium compound, and a solvent having a boiling point of 250° C. or less, and heating the mixed solvent to a temperature of 220° C. to 500° C. A thin film containing Cu—In—Ga—Se and having low resistance is obtained by using paste of the chalcogen compound powder.

摘要翻译： 通过将混合溶剂混合在一起混合至少一种铜的混合物，得到含Cu-In-Ga-Se的平均粒径（DSEM）为80nm以下且碳含量低的硫族化合物粉末 盐和铟盐，铜和铟的复合氢氧化物，以及铜和铟的复合氧化物，硒和硒化合物中的任何一种，以及沸点为250℃或更低的溶剂，加热混合 溶剂至220℃至500℃的温度。通过使用硫属化合物粉末的糊料获得含有Cu-In-Ga-Se并且具有低电阻的薄膜。

公开(公告)号：US20110175041A1

公开(公告)日：2011-07-21

申请号：US13002995

申请日：2009-06-30

申请人： Atsushi Muramatsu ,  Kiyoshi Kanie ,  Kazuhisa Saito ,  Koji Tanoue ,  Akira Nagatomi

发明人： Atsushi Muramatsu ,  Kiyoshi Kanie ,  Kazuhisa Saito ,  Koji Tanoue ,  Akira Nagatomi

IPC分类号： H01B1/02

CPC分类号： B82Y30/00 ,  C01G15/00 ,  C01G19/00 ,  C01P2002/54 ,  C01P2002/72 ,  C01P2004/04 ,  C01P2004/64 ,  C01P2004/84 ,  C01P2006/40 ,  C08K3/22 ,  C08K9/02 ,  C09D5/032 ,  C09D5/24 ,  C09D7/62 ,  C09D7/67 ,  C09D7/70

摘要： ITO powder and a producing method of the same, capable of producing ITO particles without using a solvent with a high boiling point by a simple treatment method without a heating process in an atmosphere which causes sintering. Also, an ITO powder is provided, which is suitable for a coating material for a transparent electroconductive material, the ITO powder being produced by a first step of dissolving salt containing indium and salt containing tin into an organic solvent, then adding to this organic solvent, an organic solvent containing a basic precipitant, to manufacture a precursor; and a second step of applying heat treatment to the precursor in a pressurizing vessel, to thereby generate ITO particles.

摘要翻译： ITO粉末及其制造方法，能够在不引起烧结的气氛中通过简单的处理方法在不使用具有高沸点的溶剂的情况下生产ITO颗粒而不进行加热处理。 另外，提供ITO粉末，其适用于透明导电材料用涂料，ITO粉末是通过将含有铟和含有锡的盐的盐溶解在有机溶剂中的第一步骤制备的，然后加入到该有机溶剂中 ，含有碱性沉淀剂的有机溶剂，以制备前体; 以及在加压容器中对前体进行热处理的第二步骤，从而产生ITO颗粒。

公开(公告)号：US20060222932A1

公开(公告)日：2006-10-05

申请号：US11387806

申请日：2006-03-24

申请人： Koji Tanoue

发明人： Koji Tanoue

IPC分类号： H01M8/00

CPC分类号： H01M4/54 ,  C01G53/00 ,  C01P2002/72 ,  C01P2002/74 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/40 ,  H01M4/52 ,  H01M4/62 ,  H01M6/04 ,  Y10T29/49108

摘要： Material for the positive electrode of batteries is provided that has good conductivity and can be manufactured more cheaply than AgNiO2. The battery positive electrode material is a conductive chemical compound represented by the general formula AgxNiyO2 (wherein X/Y is smaller than 1 and not smaller than 0.25). The conductive chemical compound is constituted of a crystal that has an X-ray diffraction main peak that is the same as that of AgNiO2 (wherein X=Y=1), and does not exhibit a Ag2O or AgO peak. This conductive compound can be used as an additive to impart conductivity to the silver oxide (Ag2O) of the positive electrode material.

摘要翻译： 提供了电池正极的材料，其具有良好的导电性并且可以比AgNiO 2 2更便宜地制造。 电池正极材料是由通式Ag x x Y O 2 O 2（其中X / Y小于 1且不小于0.25）。 导电化合物由具有与AgNiO 2（X = Y = 1）相同的X射线衍射主峰的晶体构成，不呈现Ag < SUB> 2 O或AgO峰。 该导电性化合物可以用作添加剂以赋予正极材料的氧化银（Ag 2 O 2）导电性。

公开(公告)号：US08524122B2

公开(公告)日：2013-09-03

申请号：US13002995

申请日：2009-06-30

申请人： Atsushi Muramatsu ,  Kiyoshi Kanie ,  Kazuhisa Saito ,  Koji Tanoue ,  Akira Nagatomi

发明人： Atsushi Muramatsu ,  Kiyoshi Kanie ,  Kazuhisa Saito ,  Koji Tanoue ,  Akira Nagatomi

IPC分类号： H01B1/02

CPC分类号： B82Y30/00 ,  C01G15/00 ,  C01G19/00 ,  C01P2002/54 ,  C01P2002/72 ,  C01P2004/04 ,  C01P2004/64 ,  C01P2004/84 ,  C01P2006/40 ,  C08K3/22 ,  C08K9/02 ,  C09D5/032 ,  C09D5/24 ,  C09D7/62 ,  C09D7/67 ,  C09D7/70

摘要： A production method capable of producing ITO particles without using a solvent with a high boiling point as a solvent used in the producing step by a simple treatment method without through a heating process in an atmosphere which disadvantageously causes sintering among the ITO particles to coarsen the ITO particles. An ITO powder suitable for a coating material for a transparent electroconductive material, being produced by a first step of dissolving salt containing indium and salt containing tin into an organic solvent, then adding to this organic solvent, an organic solvent containing a basic precipitant, to thereby manufacture a mixture of a precursor containing indium and tin, and the organic solvent; and a second step of applying heat treatment to the mixture of the precursor containing indium and tin, and the organic solvent in a pressurizing vessel at 200° C. or more and 300° C. or less, to generate ITO particles.

摘要翻译： 能够通过简单的处理方法在不使用在气氛中通过加热处理的情况下，不使用高沸点的溶剂作为溶剂而制造ITO粒子的制造方法，其不利地导致ITO粒子之间的烧结使粗大的ITO 粒子。 一种适用于透明导电材料涂料的ITO粉末，其通过将含有铟和含有含锡的盐的盐溶解在有机溶剂中，然后将含有碱性沉淀剂的有机溶剂加入到含有碱性沉淀剂的有机溶剂中， 从而制造含有铟和锡的前体和有机溶剂的混合物; 以及在200℃以上且300℃以下的加压容器内对含有铟和锡的前体和有机溶剂的混合物进行热处理的第二工序，生成ITO粒子。

公开(公告)号：US07695866B2

公开(公告)日：2010-04-13

申请号：US11387806

申请日：2006-03-24

申请人： Koji Tanoue

发明人： Koji Tanoue

IPC分类号： H01M4/48 ,  H01M4/53 ,  H01M4/54

CPC分类号： H01M4/54 ,  C01G53/00 ,  C01P2002/72 ,  C01P2002/74 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/40 ,  H01M4/52 ,  H01M4/62 ,  H01M6/04 ,  Y10T29/49108

摘要： Material for the positive electrode of batteries is provided that has good conductivity and can be manufactured more cheaply than AgNiO2. The battery positive electrode material is a conductive chemical compound represented by the general formula AgxNiyO2 (wherein X/Y is smaller than 1 and not smaller than 0.25). The conductive chemical compound is constituted of a crystal that has an X-ray diffraction main peak that is the same as that of AgNiO2 (wherein X=Y=1), and does not exhibit a Ag2O or AgO peak. This conductive compound can be used as an additive to impart conductivity to the silver oxide (Ag2O) of the positive electrode material.

摘要翻译： 提供了具有良好导电性的电池正极材料，并且可以比AgNiO 2更便宜地制造。 电池正极材料是由通式Ag x N y O 2（其中X / Y小于1且不小于0.25）表示的导电化合物。 导电性化合物由具有与AgNiO 2（其中X = Y = 1）相同的X射线衍射主峰的晶体构成，不具有Ag 2 O或AgO峰。 该导电性化合物可以用作赋予正极材料的氧化银（Ag 2 O）导电性的添加剂。

公开(公告)号：US20060141360A1

公开(公告)日：2006-06-29

申请号：US11315207

申请日：2005-12-23

申请人： Koji Tanoue

发明人： Koji Tanoue

IPC分类号： H01M4/52 ,  H01M4/54 ,  C01G53/04 ,  C01G5/00

CPC分类号： H01M4/48 ,  H01M4/06 ,  H01M4/52 ,  H01M6/04

摘要： A material for the positive electrode of a silver oxide battery is provided that increases the discharge capacity of the battery. The positive electrode material is a conductive composite oxide represented by the general formula AgxNiyO2, in which X/Y is greater than 1 and does not exceed 1.9, and by the general formula AgxNiyMzO2, in which M represents at least one of Cu and Bi, X/(Y+Z) is greater than 1 and does not exceed 1.9, and Z does not exceed 0.4. These conductive oxides contain almost no free Ag2O and have a crystal structure similar to that of AgNiO2. As a result, the excess Ag—Ni oxide is conductive and has a high discharge capacity.

摘要翻译： 提供了用于氧化银电池的正极的材料，其增加了电池的放电容量。 正极材料是由通式为O x Y Y 2 O 2的通式表示的导电复合氧化物，其中X / Y大于 1，并且不超过1.9，并且通式为Ag x N 2 O x O 2 O 2，在 M表示Cu和Bi中的至少一种，X /（Y + Z）大于1且不超过1.9，Z不超过0.4。 这些导电氧化物几乎不含有游离的Ag 2 O，并且具有与AgNiO 2 O 2相似的晶体结构。 结果，过量的Ag-Ni氧化物是导电的并且具有高放电容量。

公开(公告)号：US20050266311A1

公开(公告)日：2005-12-01

申请号：US11165227

申请日：2005-06-24

申请人： Koji Tanoue ,  Yoshiyuki Shoji

发明人： Koji Tanoue ,  Yoshiyuki Shoji

IPC分类号： H01M4/34 ,  H01M4/54 ,  H01M10/32 ,  C01G5/00

CPC分类号： H01M4/34 ,  H01M4/54 ,  H01M10/32

摘要： Alkaline battery silver oxide powder when soaked in a 50° C. KOH 40% aqueous solution for 24 hours experiences dissolution of Ag into the solution of 40 mg/L. Alkaline battery silver oxide powder exhibits substantially no Ag peak by X-ray diffraction even after soaking in a 50° C. KOH 40% aqueous solution for 72 hours. This powder has a crystallite size calculated from the half value breadth of the (111) plane peak by powder X-ray diffraction of greater than 250 Angstrom and equal to or less than 1000 Angstrom, particle diameter such that the average diameter of secondary particles is equal to or greater than 1 μm and equal to or less than 500 μm and that of primary particles forming the secondary particles is equal to or greater than 0.1 μm and equal to or less than 10.0 μm, and specific surface area of 5 m2/g or less.

摘要翻译： 碱性电池氧化银粉末在50℃下浸泡时，KOH 40％水溶液24小时，经过Ag溶解至40mg / L的溶液中。 碱性电池氧化银粉末即使在50℃KOH 40％水溶液中浸泡72小时后也通过X射线衍射显示出基本上没有Ag峰。 该粉末具有由（111）面峰值的半值宽度计算的微晶尺寸，粉末X射线衍射大于250埃且等于或小于1000埃，二次颗粒的平均直径为 等于或大于1um且等于或小于500μm，并且形成二次粒子的一次粒子的粒子数大于等于或小于10.0μm，并且等于或小于10.0μm，比表面积为5μm > 2 / g以下。

公开(公告)号：US08512602B2

公开(公告)日：2013-08-20

申请号：US12733949

申请日：2008-09-26

申请人： Akira Nagatomi ,  Koji Tanoue

发明人： Akira Nagatomi ,  Koji Tanoue

IPC分类号： H01B1/02

CPC分类号： H01B1/20 ,  B82Y30/00 ,  C01G19/00 ,  C01P2004/04 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/60 ,  H01B1/08

摘要： ITO particles are provided, which are small in variations of particle diameters and used for an ITO coating material capable of forming a transparent conductive film having high transparency and low haze value. Also, ITO coating material is provided, containing such ITO particles, and a transparent conductive film containing such ITO particles. Further, ITO powders are provided, wherein 90% or more of ITO particles constituting the ITO powders have a primary particle diameter of 20 nm or less.

摘要翻译： 提供了粒径变化小的ITO颗粒，用于能够形成透明度高，雾度低的透明导电膜的ITO涂料。 此外，提供含有这种ITO颗粒的ITO涂层材料和含有这种ITO颗粒的透明导电膜。 此外，提供ITO粉末，其中构成ITO粉末的ITO颗粒的90％以上的初级粒径为20nm以下。

公开(公告)号：US20100252785A1

公开(公告)日：2010-10-07

申请号：US12733949

申请日：2008-09-26

申请人： Akira Nagatomi ,  Koji Tanoue

发明人： Akira Nagatomi ,  Koji Tanoue

IPC分类号： H01B1/08

CPC分类号： H01B1/20 ,  B82Y30/00 ,  C01G19/00 ,  C01P2004/04 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/60 ,  H01B1/08

摘要： ITO particles are provided, which are small in variations of particle diameters and used for an ITO coating material capable of forming a transparent conductive film having high transparency and low haze value. Also, ITO coating material is provided, containing such ITO particles, and a transparent conductive film containing such ITO particles. Further, ITO powders are provided, wherein 90% or more of ITO particles constituting the ITO powders have a primary particle diameter of 20 nm or less.

摘要翻译： 提供了粒径变化小的ITO颗粒，用于能够形成透明度高，雾度低的透明导电膜的ITO涂料。 此外，提供含有这种ITO颗粒的ITO涂层材料和含有这种ITO颗粒的透明导电膜。 此外，提供ITO粉末，其中构成ITO粉末的ITO颗粒的90％以上的初级粒径为20nm以下。

公开(公告)号：US20080081178A1

公开(公告)日：2008-04-03

申请号：US11902242

申请日：2007-09-20

申请人： Takashi Hinotsu ,  Koji Tanoue

发明人： Takashi Hinotsu ,  Koji Tanoue

IPC分类号： B32B5/16 ,  C23C14/28

CPC分类号： H01L31/1884 ,  C08J7/06 ,  C08J2367/02 ,  H01L31/022466 ,  Y02E10/50 ,  Y10T428/256

摘要： After fluid material containing transparent conducting fine particles is coated on a substrate to form a coating film, and the transparent conducting fine particles are sintered by irradiating an electromagnetic wave after pressure is added to this coating film. For example, the pressure is added to the coating film so that density of the coating film becomes 3.0 g/cm3 or more. Besides, for example, the pressure is added to a surface of the coating film by means of a roll press. Besides, for example, a line pressure of the roll press is set to be 200 kg/cm or more. Besides, for example, the irradiated electromagnetic wave is a microwave of 1 GHz to 1 THz.

摘要翻译： 将含有透明导电性微粒的流体材料涂布在基板上以形成涂膜后，在向该涂膜加压后，通过照射电磁波来对透明导电性微粒进行烧结。 例如，向涂膜添加压力，使得涂膜的密度为3.0g / cm 3以上。 此外，例如，通过辊压机将压力添加到涂膜的表面。 此外，例如，辊压机的管路压力设定为200kg / cm以上。 此外，例如，照射的电磁波是1GHz〜1Hz的微波。