公开(公告)号：US20130011572A1

公开(公告)日：2013-01-10

申请号：US13635318

申请日：2011-03-24

申请人： Yusuke Nakai ,  Tadashi Nakamura ,  Tetsuya Jigami ,  Satoru Ozawa ,  Eiko Okamoto

发明人： Yusuke Nakai ,  Tadashi Nakamura ,  Tetsuya Jigami ,  Satoru Ozawa ,  Eiko Okamoto

IPC分类号： B29C33/58

CPC分类号： G02B1/118 ,  B29C33/58 ,  B29C39/148 ,  B29C39/18 ,  B29C59/046 ,  B29C2035/0827 ,  B29C2035/0833 ,  B29K2995/0093 ,  C08G65/3351 ,  C08G65/3353 ,  C08L71/02 ,  C09D171/02 ,  G02B27/0006

摘要： The present invention relates to a production method for a product having a cured resin layer with a fine concave-convex structure formed on the surface of a substrate, the method including filling the space between a mold having a fine concave-convex structure composed of anodized alumina on the surface and a substrate with an active energy ray-curable resin composition, and curing the composition by irradiation with active energy rays, thereby forming a cured resin layer into which the fine concave-convex structure has been transferred on the surface of the substrate, wherein (A) the method includes treating the surface of the mold with a release agent, at least at transfer initiation, and (B) the active energy ray-curable resin composition includes a polymerizable compound, a polymerization initiator and a (poly)oxyethylene alkyl phosphate ester compound.

摘要翻译： 本发明涉及一种具有形成在基材表面上的具有细凹凸结构的固化树脂层的产品的制造方法，该方法包括填充具有由阳极氧化处理的细凹凸结构的模具之间的空间 氧化铝和具有活性能量射线固化树脂组合物的基材，通过用活性能量射线照射固化该组合物，从而形成在该表面上转印有微细凹凸结构的固化树脂层 基材，其中（A）所述方法包括至少在转移开始时用脱模剂处理模具的表面，和（B）活性能量射线固化树脂组合物包括可聚合化合物，聚合引发剂和（聚 ）氧乙烯烷基磷酸酯化合物。

公开(公告)号：US09052444B2

公开(公告)日：2015-06-09

申请号：US13635318

申请日：2011-03-24

申请人： Yusuke Nakai ,  Tadashi Nakamura ,  Tetsuya Jigami ,  Satoru Ozawa ,  Eiko Okamoto

发明人： Yusuke Nakai ,  Tadashi Nakamura ,  Tetsuya Jigami ,  Satoru Ozawa ,  Eiko Okamoto

IPC分类号： H05H1/30 ,  H05H1/46 ,  B29C33/58 ,  B29C39/14 ,  B29C39/18 ,  B29C59/04 ,  C08G65/335 ,  C08L71/02 ,  G02B27/00 ,  C09D171/02 ,  B29C35/08

CPC分类号： G02B1/118 ,  B29C33/58 ,  B29C39/148 ,  B29C39/18 ,  B29C59/046 ,  B29C2035/0827 ,  B29C2035/0833 ,  B29K2995/0093 ,  C08G65/3351 ,  C08G65/3353 ,  C08L71/02 ,  C09D171/02 ,  G02B27/0006

摘要： The present invention relates to a production method for a product having a cured resin layer with a fine concave-convex structure formed on the surface of a substrate, the method including filling the space between a mold having a fine concave-convex structure composed of anodized alumina on the surface and a substrate with an active energy ray-curable resin composition, and curing the composition by irradiation with active energy rays, thereby forming a cured resin layer into which the fine concave-convex structure has been transferred on the surface of the substrate, wherein (A) the method includes treating the surface of the mold with a release agent, at least at transfer initiation, and (B) the active energy ray-curable resin composition includes a polymerizable compound, a polymerization initiator and a (poly)oxyethylene alkyl phosphate ester compound.

摘要翻译： 本发明涉及一种具有形成在基材表面上的具有细凹凸结构的固化树脂层的产品的制造方法，该方法包括填充具有由阳极氧化处理的细凹凸结构的模具之间的空间 氧化铝和具有活性能量射线固化树脂组合物的基材，通过用活性能量射线照射固化该组合物，从而形成在该表面上转印有微细凹凸结构的固化树脂层 基材，其中（A）所述方法包括至少在转移开始时用脱模剂处理模具的表面，和（B）活性能量射线固化树脂组合物包括可聚合化合物，聚合引发剂和（聚 ）氧乙烯烷基磷酸酯化合物。

公开(公告)号：US20110318539A1

公开(公告)日：2011-12-29

申请号：US13254322

申请日：2010-03-02

申请人： Satoru Ozawa ,  Tadashi Nakamura ,  Eiko Okamoto ,  Katsuhiro Kojima

发明人： Satoru Ozawa ,  Tadashi Nakamura ,  Eiko Okamoto ,  Katsuhiro Kojima

IPC分类号： B32B3/10 ,  B29C35/08

CPC分类号： G02B1/118 ,  B29C33/60 ,  B29C39/148 ,  B29C39/18 ,  B29C43/222 ,  B29C43/28 ,  Y10T428/24612

摘要： The present invention provides a method making it possible to stably prepare a transparent film in which a cured layer having a micro protrusion and recess face structure is formed on the surface of a base material film. The preparation method of the present invention includes a step of sandwiching an active energy beam-curable resin composition including a photopolymerization initiator which can initiate polymerization of a polymerizable compound by absorbing light between the surface of a base material film which is supported by a supporting film, and a mold which has an inverse structure of the micro protrusion and recess face structure on the surface; a step of obtaining the transparent film supported by the supporting film by means of irradiating the active energy beam-curable resin composition with ultraviolet rays from the supporting film side; and a step of separating the transparent film and the mold.

摘要翻译： 本发明提供一种可以稳定地制备其中在基材膜的表面上形成具有微突起和凹面结构的固化层的透明膜的方法。 本发明的制备方法包括夹持包含光聚合引发剂的活性能量束固化树脂组合物的步骤，该光聚合引发剂可以通过在由支撑膜支撑的基材膜的表面之间吸收光而引发可聚合化合物的聚合 以及表面上具有微突起和凹面结构的相反结构的模具; 通过用支撑膜侧的紫外线照射活性能量束固化树脂组合物获得由支撑膜支撑的透明膜的步骤; 以及分离透明膜和模具的步骤。

公开(公告)号：US09138775B2

公开(公告)日：2015-09-22

申请号：US13990183

申请日：2012-05-25

申请人： Go Otani ,  Yusuke Nakai ,  Satoru Ozawa

发明人： Go Otani ,  Yusuke Nakai ,  Satoru Ozawa

IPC分类号： B05D5/02 ,  B29C59/04 ,  B29C33/60 ,  B29C39/14 ,  G02B1/118 ,  B29C35/08 ,  B29C59/02 ,  B29C33/42

CPC分类号： B05D5/02 ,  B29C33/424 ,  B29C33/60 ,  B29C39/148 ,  B29C59/046 ,  B29C2035/0827 ,  B29C2059/023 ,  G02B1/118 ,  G02B1/18

摘要： A method for preparing an article having an uneven microstructure on a surface thereof, including coating a surface of a mold having an uneven microstructure formed from an anodized alumina oxide on a surface with a release treatment solution including a mold release agent that includes one or more kinds of phosphoric ester compound and the pH of the aqueous solution when extracted with 50 mL of water with respect to 1 g of the mold release agent is 3.0 or more; and interposing an active energy ray curable resin composition including a polymerizable compound, a polymerization initiator, and an internal release agent between the mold and the substrate, and curing the active energy ray curable resin composition by the irradiation with active energy rays to form a cured resin layer having the uneven microstructure transferred on a surface of the substrate.

摘要翻译： 一种制备在其表面上具有不均匀微观结构的制品的方法，包括用包括脱模剂的脱模处理溶液在表面上涂覆具有由阳极氧化氧化铝形成的不均匀微观结构的模具的表面，所述脱模处理溶液包括一个或多个 各种磷酸酯化合物和相对于1g脱模剂以50mL水萃取时的水溶液的pH为3.0以上; 在该模具与基板之间插入含有聚合性化合物，聚合引发剂和内部脱模剂的活性能量射线固化型树脂组合物，并且通过用活性能量射线照射来固化活性能量射线固化性树脂组合物， 在基板的表面上具有不均匀的微结构的树脂层。

公开(公告)号：US20130270748A1

公开(公告)日：2013-10-17

申请号：US13990426

申请日：2012-01-31

申请人： Satoru Ozawa ,  Katsuhiro Kojima ,  Yusuke Nakai

发明人： Satoru Ozawa ,  Katsuhiro Kojima ,  Yusuke Nakai

IPC分类号： B29C43/28 ,  B29C59/04

CPC分类号： B29C43/28 ,  B29C59/04 ,  B29C59/046 ,  C08G65/3353 ,  C08K5/0025 ,  C08K5/521 ,  C08K5/5397

摘要： Described are: an active-energy-ray-curable composition (38) containing a phosphate ester compound of which an aqueous solution prepared by extracting with 50 mL of water per 1 g of the phosphate ester compound has a pH value of 6.5 to 7.5 at 25° C., wherein the value of (the concentration of phosphoric acid in the aqueous solution, expressed in mass ppm)×(the content of the phosphate ester compound in the active-energy-ray-curable composition, expressed in mass %) is 50 or less; and a process for producing a transparent film (40) which includes the active-energy-ray-curable composition (38) and in which a cured resin layer (44) having a fine uneven structure is formed on the surface of a base film (42).

摘要翻译： 描述了含有磷酸酯化合物的活性能量射线固化性组合物（38），其中通过每1g磷酸酯化合物用50mL水萃取而制备的水溶液的pH值为6.5〜7.5 25℃，其中（水溶液中的磷酸浓度，质量ppm表示）×（活性能量射线固化性组合物中的磷酸酯化合物的含量，以质量％表示） 为50以下; 以及包含活性能量射线固化性组合物（38）的透明膜（40）的制造方法，其中，在基材膜的表面上形成有具有微细凹凸结构的固化树脂层（44） 42）。

公开(公告)号：US09284445B2

公开(公告)日：2016-03-15

申请号：US14123801

申请日：2012-06-22

申请人： Masayuki Uchida ,  Katsuhiro Kojima ,  Shinji Makino ,  Yusuke Nakai ,  Satoru Ozawa ,  Haruo Unno ,  Isao Yamamoto ,  Takayuki Fukui

发明人： Masayuki Uchida ,  Katsuhiro Kojima ,  Shinji Makino ,  Yusuke Nakai ,  Satoru Ozawa ,  Haruo Unno ,  Isao Yamamoto ,  Takayuki Fukui

IPC分类号： G02B1/12 ,  C08L33/14 ,  C08F220/28 ,  G02B1/04 ,  G02B1/118 ,  C08F290/06 ,  G03F7/027

CPC分类号： C08L33/14 ,  C08F220/28 ,  C08F290/062 ,  G02B1/04 ,  G02B1/118 ,  G02B1/12 ,  G03F7/027 ,  Y10T428/24355 ,  C08L71/02 ,  C08L83/04 ,  C08L33/08 ,  C08F222/10 ,  C08F220/10

摘要： The present invention relates to a resin composition for a nano concave-convex structure, including 0.01 to 10 parts by mass of an active energy ray polymerization initiator (D), 0.01 to 3 parts by mass of a release agent (E), and 0.01 to 3 parts by mass of a lubricant (F), relative to 100 parts by mass of a polymerization reactive monomer component containing 50 to 95 parts by mass of a tetrafunctional (meth)acrylate monomer (A), 5 to 35 parts by mass of a difunctional (meth)acrylate monomer (B) in which the total number of repeating units within a polyalkylene glycol structure is from 4 to 25, and not more than 15 parts by mass of a monofunctional (meth)acrylate monomer (C) which is copolymerizable with the monomers (A) and (B), and relates to a transparent member for the monitor of a vehicle navigation device and the cover of a vehicle meter.

摘要翻译： 本发明涉及一种纳米凹凸结构用树脂组合物，其含有0.01〜10质量份的活性能量射线聚合引发剂（D），0.01〜3质量份的脱模剂（E），0.01 相对于100质量份含有50〜95质量份的四官能（甲基）丙烯酸酯单体（A）的聚合反应性单体成分，相对于3质量份的润滑剂（F）为5质量份， 聚亚烷基二醇结构中的重复单元总数为4〜25，双官能（甲基）丙烯酸酯单体（C）为15质量份以下的双官能（甲基）丙烯酸酯单体（B） 可与单体（A）和（B）共聚，涉及用于车辆导航装置的监视器和车辆仪表的盖的透明构件。

公开(公告)号：US09266262B2

公开(公告)日：2016-02-23

申请号：US13976193

申请日：2011-12-28

申请人： Satoru Ozawa ,  Katsuhiro Kojima ,  Yusuke Nakai ,  Hiroshi Onomoto

发明人： Satoru Ozawa ,  Katsuhiro Kojima ,  Yusuke Nakai ,  Hiroshi Onomoto

IPC分类号： C07F9/02 ,  B29C43/00 ,  B29C39/14 ,  B29C33/60 ,  C08K5/521 ,  B29C43/28 ,  B29C59/04 ,  B29C39/18

CPC分类号： B29C43/003 ,  B29C33/60 ,  B29C39/148 ,  B29C39/18 ,  B29C43/28 ,  B29C59/04 ,  C08K5/521

摘要： A method for manufacturing a light transmissive film having a cured resin layer with a fine concavo-convex structure on a surface of a base material film is provided. The method includes sandwiching an active energy ray-curable composition including a mold dissolving component between a mold having an inversion structure of the fine concavo-convex structure and the base material film, obtaining a light transmissive film in which a cured resin layer having the inversion structure of the mold transferred is formed on one surface of the base material film, and separating the obtained light transmissive film and the mold. Thus, it is possible to productively manufacture a light transmissive film, and to prevent the deposition of an attachment on the mold surface and the contamination of the mold surface. Moreover, a light transmissive film can be manufactured having excellent performances, such as antireflection properties.

摘要翻译： 提供了在基材膜的表面上制造具有微细凹凸结构的固化树脂层的透光膜的方法。 该方法包括将具有模具溶解成分的活性能量射线固化性组合物夹在具有微细凹凸结构的反转结构的模具和基材膜之间，得到透光膜，其中具有反转的固化树脂层 转印模具的结构形成在基材薄膜的一个表面上，并分离所得的透光膜和模具。 因此，可以有效地制造透光膜，并且防止附着在模具表面上的沉积和模具表面的污染。 此外，可以制造具有优异性能的透光膜，例如抗反射性能。

公开(公告)号：US20140077418A1

公开(公告)日：2014-03-20

申请号：US13990183

申请日：2012-05-25

申请人： Go Otani ,  Yusuke Nakai ,  Satoru Ozawa

发明人： Go Otani ,  Yusuke Nakai ,  Satoru Ozawa

IPC分类号： B05D5/02

CPC分类号： B05D5/02 ,  B29C33/424 ,  B29C33/60 ,  B29C39/148 ,  B29C59/046 ,  B29C2035/0827 ,  B29C2059/023 ,  G02B1/118 ,  G02B1/18

摘要： A method for preparing an article having an uneven microstructure on a surface thereof, including coating a surface of a mold having an uneven microstructure formed from an anodized alumina oxide on a surface with a release treatment solution including a mold release agent that includes one or more kinds of phosphoric ester compound and the pH of the aqueous solution when extracted with 50 mL of water with respect to 1 g of the mold release agent is 3.0 or more; andinterposing an active energy ray curable resin composition including a polymerizable compound, a polymerization initiator, and an internal release agent between the mold and the substrate, and curing the active energy ray curable resin composition by the irradiation with active energy rays to form a cured resin layer having the uneven microstructure transferred on a surface of the substrate.

摘要翻译： 一种制备在其表面上具有不均匀微观结构的制品的方法，包括用包括脱模剂的脱模处理溶液在表面上涂覆具有由阳极氧化氧化铝形成的不均匀微观结构的模具的表面，所述脱模处理溶液包括一个或多个 各种磷酸酯化合物和相对于1g脱模剂以50mL水萃取时的水溶液的pH为3.0以上; 在该模具与基板之间插入含有聚合性化合物，聚合引发剂和内部脱模剂的活性能量射线固化型树脂组合物，并且通过用活性能量射线照射来固化活性能量射线固化性树脂组合物， 在基板的表面上具有不均匀的微结构的树脂层。

公开(公告)号：US09975282B2

公开(公告)日：2018-05-22

申请号：US13990426

申请日：2012-01-31

申请人： Satoru Ozawa ,  Katsuhiro Kojima ,  Yusuke Nakai

发明人： Satoru Ozawa ,  Katsuhiro Kojima ,  Yusuke Nakai

IPC分类号： B29C43/28 ,  B29C59/04 ,  C08G65/335 ,  C08K5/521 ,  C08K5/00 ,  C08K5/5397

CPC分类号： B29C43/28 ,  B29C59/04 ,  B29C59/046 ,  C08G65/3353 ,  C08K5/0025 ,  C08K5/521 ,  C08K5/5397

摘要： Described are: an active-energy-ray-curable composition (38) containing a phosphate ester compound of which an aqueous solution prepared by extracting with 50 mL of water per 1 g of the phosphate ester compound has a pH value of 6.5 to 7.5 at 25° C., wherein the value of (the concentration of phosphoric acid in the aqueous solution, expressed in mass ppm)×(the content of the phosphate ester compound in the active-energy-ray-curable composition, expressed in mass %) is 50 or less; and a process for producing a transparent film (40) which includes the active-energy-ray-curable composition (38) and in which a cured resin layer (44) having a fine uneven structure is formed on the surface of a base film (42).

公开(公告)号：US20140120313A1

公开(公告)日：2014-05-01

申请号：US14123801

申请日：2012-06-22

申请人： Masayuki Uchida ,  Katsuhiro Kojima ,  Shinji Makino ,  Yusuke Nakai ,  Satoru Ozawa ,  Haruo Unno ,  Isao Yamamoto ,  Takayuki Fukui

发明人： Masayuki Uchida ,  Katsuhiro Kojima ,  Shinji Makino ,  Yusuke Nakai ,  Satoru Ozawa ,  Haruo Unno ,  Isao Yamamoto ,  Takayuki Fukui

IPC分类号： C08L33/14 ,  G02B1/12

CPC分类号： C08L33/14 ,  C08F220/28 ,  C08F290/062 ,  G02B1/04 ,  G02B1/118 ,  G02B1/12 ,  G03F7/027 ,  Y10T428/24355 ,  C08L71/02 ,  C08L83/04 ,  C08L33/08 ,  C08F222/10 ,  C08F220/10

摘要： The present invention relates to a resin composition for a nano concave-convex structure, including 0.01 to 10 parts by mass of an active energy ray polymerization initiator (D), 0.01 to 3 parts by mass of a release agent (E), and 0.01 to 3 parts by mass of a lubricant (F), relative to 100 parts by mass of a polymerization reactive monomer component containing 50 to 95 parts by mass of a tetrafunctional (meth)acrylate monomer (A), 5 to 35 parts by mass of a difunctional (meth)acrylate monomer (B) in which the total number of repeating units within a polyalkylene glycol structure is from 4 to 25, and not more than 15 parts by mass of a monofunctional (meth)acrylate monomer (C) which is copolymerizable with the monomers (A) and (B), and relates to a transparent member for the monitor of a vehicle navigation device and the cover of a vehicle meter.

摘要翻译： 本发明涉及一种纳米凹凸结构用树脂组合物，其含有0.01〜10质量份的活性能量射线聚合引发剂（D），0.01〜3质量份的脱模剂（E），0.01 相对于100质量份含有50〜95质量份的四官能（甲基）丙烯酸酯单体（A）的聚合反应性单体成分，相对于3质量份的润滑剂（F）为5质量份， 聚亚烷基二醇结构中的重复单元总数为4〜25，双官能（甲基）丙烯酸酯单体（C）为15质量份以下的双官能（甲基）丙烯酸酯单体（B） 可与单体（A）和（B）共聚，涉及用于车辆导航装置的监视器和车辆仪表的盖的透明构件。