公开(公告)号：US09249024B2

公开(公告)日：2016-02-02

申请号：US13579961

申请日：2011-02-14

申请人： Yusuke Ohta ,  Takashi Inada ,  Makoto Mishiro ,  Yasushi Nishikawa ,  Takashi Inada

发明人： Yusuke Ohta ,  Takashi Inada ,  Makoto Mishiro ,  Yasushi Nishikawa ,  Takashi Inada

IPC分类号： C01B31/00 ,  B65H18/08 ,  B65H35/02 ,  B65H35/04 ,  C01B31/04 ,  C04B35/52 ,  C04B35/524 ,  C04B35/622 ,  C04B35/626 ,  C04B35/634

CPC分类号： B32B37/20 ,  B32B7/12 ,  B32B9/007 ,  B32B37/0053 ,  B32B37/12 ,  B32B38/10 ,  B32B38/18 ,  B32B2250/02 ,  B32B2313/04 ,  C01B32/20 ,  C04B35/522 ,  C04B35/524 ,  C04B35/62218 ,  C04B35/6269 ,  C04B35/63468 ,  C04B2235/604 ,  C04B2235/6581 ,  C04B2235/96 ,  C04B2235/9638

摘要： A graphite film showing an extremely low average tearing force is more likely to suffer from various kinds of defects, such as splitting, winding deviation, wrinkling, and poor dimensional accuracy, in a step of producing the graphite film and in a step of processing the graphite film. However, these defects can be prevented by using a graphite film that satisfies the following requirements: 1) having an average tearing force of not more than 0.08 N as determined by Trouser tear method in accordance with JIS K7128; and 2) having sag of not less than 5 mm and not greater than 80 mm as determined by a method of film windability evaluation in accordance with JIS C2151.

摘要翻译： 在制造石墨膜的步骤中，显示平均撕裂力极低的石墨膜在制造石墨膜的步骤中更可能遭受各种各样的缺陷，例如分裂，卷绕偏差，起皱和尺寸精度差， 石墨膜。 然而，通过使用满足以下要求的石墨膜可以防止这些缺陷：1）通过根据JIS K7128的裤子撕裂法测定的平均撕裂力不大于0.08N; 和2）根据JIS C2151通过膜卷取性评价方法确定的凹陷不小于5mm且不大于80mm。

公开(公告)号：US08883068B2

公开(公告)日：2014-11-11

申请号：US13700580

申请日：2011-05-12

申请人： Yusuke Ohta ,  Takashi Inada ,  Makoto Mishiro ,  Takashi Inada ,  Yasushi Nishikawa

发明人： Yusuke Ohta ,  Takashi Inada ,  Makoto Mishiro ,  Takashi Inada ,  Yasushi Nishikawa

IPC分类号： C01B31/04

CPC分类号： C01B31/04 ,  C01B32/20

摘要： When a raw material graphite film bad in flatness is laminated onto another material, creases and other defects may be caused. In particular, when a graphite film having a large area is laminated, defects such as creases may be often caused. In order to solve such defects, a flatness correction treatment step is performed wherein a raw material graphite film is subjected to heat treatment up to 2000° C. or higher while a pressure is applied thereto. This flatness correction treatment gives a graphite film good in flatness. Furthermore, when the flatness of the raw material graphite film is corrected by use of a thermal expansion of a core, a graphite film small in sagging can be obtained.

摘要翻译： 当将平坦度不好的原料石墨膜层压到另一种材料上时，可能引起折痕和其它缺陷。 特别地，当层压有大面积的石墨膜时，可能经常引起折痕等缺陷。 为了解决这种缺陷，进行平面度校正处理步骤，其中在施加压力的同时对原料石墨膜进行高达2000℃或更高的热处理。 该平坦度校正处理使得平坦度好的石墨膜。 此外，当通过使用芯的热膨胀来校正原料石墨膜的平坦度时，可以获得小的下垂的石墨膜。

公开(公告)号：US20130119571A1

公开(公告)日：2013-05-16

申请号：US13700580

申请日：2011-05-12

申请人： Yusuke Ohta ,  Takashi Inada ,  Makoto Mishiro ,  Takashi Inada ,  Yasushi Nishikawa

发明人： Yusuke Ohta ,  Takashi Inada ,  Makoto Mishiro ,  Takashi Inada ,  Yasushi Nishikawa

IPC分类号： C01B31/04

CPC分类号： C01B31/04 ,  C01B32/20

摘要： When a raw material graphite film bad in flatness is laminated onto another material, creases and other defects may be caused. In particular, when a graphite film having a large area is laminated, defects such as creases may be often caused. In order to solve such defects, a flatness correction treatment step is performed wherein a raw material graphite film is subjected to heat treatment up to 2000° C. or higher while a pressure is applied thereto. This flatness correction treatment gives a graphite film good in flatness. Furthermore, when the flatness of the raw material graphite film is corrected by use of a thermal expansion of a core, a graphite film small in sagging can be obtained.

公开(公告)号：US20130001350A1

公开(公告)日：2013-01-03

申请号：US13579961

申请日：2011-02-14

申请人： Yusuke Ohta ,  Takashi Inada ,  Makoto Mishiro ,  Yasushi Nishikawa ,  Takashi Inada

发明人： Yusuke Ohta ,  Takashi Inada ,  Makoto Mishiro ,  Yasushi Nishikawa ,  Takashi Inada

IPC分类号： C01B31/00 ,  C01B31/04 ,  B65H35/04 ,  B65H35/02 ,  B65H18/08

CPC分类号： B32B37/20 ,  B32B7/12 ,  B32B9/007 ,  B32B37/0053 ,  B32B37/12 ,  B32B38/10 ,  B32B38/18 ,  B32B2250/02 ,  B32B2313/04 ,  C01B32/20 ,  C04B35/522 ,  C04B35/524 ,  C04B35/62218 ,  C04B35/6269 ,  C04B35/63468 ,  C04B2235/604 ,  C04B2235/6581 ,  C04B2235/96 ,  C04B2235/9638

摘要： A graphite film showing an extremely low average tearing force is more likely to suffer from various kinds of defects, such as splitting, winding deviation, wrinkling, and poor dimensional accuracy, in a step of producing the graphite film and in a step of processing the graphite film. However, these defects can be prevented by using a graphite film that satisfies the following requirements: 1) having an average tearing force of not more than 0.08 N as determined by Trouser tear method in accordance with JIS K7128; and 2) having sag of not less than 5 mm and not greater than 80 mm as determined by a method of film windability evaluation in accordance with JIS C2151.

摘要翻译： 在制造石墨膜的步骤中，显示平均撕裂力极低的石墨膜在制造石墨膜的步骤中更可能遭受各种各样的缺陷，例如分裂，卷绕偏差，起皱和尺寸精度差， 石墨膜。 然而，通过使用满足以下要求的石墨膜可以防止这些缺陷：1）通过根据JIS K7128的裤子撕裂法测定的平均撕裂力不大于0.08N; 和2）根据JIS C2151通过膜卷取性评价方法确定的凹陷不小于5mm且不大于80mm。

公开(公告)号：US09266736B2

公开(公告)日：2016-02-23

申请号：US13380373

申请日：2009-06-22

申请人： Yusuke Ohta ,  Makoto Mishiro ,  Takashi Inada ,  Yasushi Nishikawa

发明人： Yusuke Ohta ,  Makoto Mishiro ,  Takashi Inada ,  Yasushi Nishikawa

IPC分类号： B32B9/00 ,  C01B31/04

CPC分类号： C04B35/524 ,  C01B32/19 ,  C01B32/20 ,  C01B32/205 ,  C01B32/225 ,  Y10T428/30

摘要： Provided is a long and large-area graphite film having improved thermal diffusivity and flex resistance, and accompanied by ameliorated ruffling. According to a method for producing a graphite film, in which graphitization of a heat-treated film consisting of a carbonized polymer film is carried out in a state being wrapped around an internal core, the method being characterized in that a heat treatment is executed by controlling distance(s) between the internal core and the film, and/or between the layers of the film, a graphite film accompanied by significantly ameliorated ruffling can be obtained.

摘要翻译： 提供了具有改善的热扩散率和抗弯曲性的长且大面积的石墨膜，并伴随着改善的褶皱。 根据石墨膜的制造方法，其特征在于，在由碳化聚合物膜构成的热处理膜的石墨化被包裹在内部芯部的状态下进行，其特征在于，通过以下方式进行热处理： 可以获得控制内芯和薄膜之间和/或薄膜之间的距离，可以获得伴随显着改善的褶皱的石墨薄膜。

公开(公告)号：US09187331B2

公开(公告)日：2015-11-17

申请号：US14008227

申请日：2012-03-26

申请人： Makoto Mishiro ,  Yusuke Ohta ,  Takashi Inada ,  Yasushi Nishikawa

发明人： Makoto Mishiro ,  Yusuke Ohta ,  Takashi Inada ,  Yasushi Nishikawa

IPC分类号： C01B31/02 ,  C01B31/04 ,  B29C35/00

CPC分类号： B65D85/671 ,  C01B32/00 ,  C01B32/05 ,  C01B32/20 ,  C08G73/10 ,  Y10T428/24744

摘要： Disclosed herein is a method for producing an elongated (rolled) carbonaceous film by polymer pyrolysis while suppressing the fusion bonding of the carbonaceous film. The method for producing a carbonaceous film includes the step of heat-treating a polymer film wound into a roll, wherein the heat treatment is performed after the polymer film is wound into a roll to have a gap between adjacent layers of the polymer film at a temperature lower than a pyrolysis onset temperature of the polymer film so that the roll of polymer film as a whole satisfies a relationship that a value obtained by dividing a thickness of a gap between adjacent layers of the polymer film (Ts) by a thickness of the polymer film (Tf) (Ts/Tf) is 0.16 or higher but 1.50 or lower. As a method for forming gaps between the layers of the polymer film, a method in which the polymer film is wound into a roll together with a slip sheet and then the slip sheet is removed can be used, which is effective at suppressing the fusion bonding of a carbonaceous film.

摘要翻译： 本文公开了一种通过聚合物热分解制备细长（滚动）碳质膜的方法，同时抑制碳质膜的熔融粘合。 碳质膜的制造方法包括对卷绕成卷的聚合物膜进行热处理的步骤，其中在将聚合物膜卷绕成辊之后进行热处理，以在聚合物膜的相邻层之间具有间隙 温度低于聚合物膜的热解开始温度，使得聚合物膜的整体整体满足通过将聚合物膜（Ts）的相邻层之间的间隙的厚度除以通过将聚合物膜 聚合物膜（Tf）（Ts / Tf）为0.16以上且1.50以下。 作为在聚合物膜之间形成间隙的方法，可以使用其中将聚合物膜与滑动片一起卷绕成卷并且然后除去滑动片的方法，其有效地抑制熔融粘合 的碳质膜。

公开(公告)号：US09067185B2

公开(公告)日：2015-06-30

申请号：US14007786

申请日：2012-03-26

申请人： Yusuke Ohta ,  Takashi Inada ,  Makoto Mishiro ,  Yasushi Nishikawa

发明人： Yusuke Ohta ,  Takashi Inada ,  Makoto Mishiro ,  Yasushi Nishikawa

IPC分类号： B01J6/00 ,  C01B31/04

CPC分类号： B01J6/008 ,  C01B32/20 ,  C01P2006/60

摘要： The present invention performs special heat treatment on a polymer film in a temperature range from (i) a lower limit to temperature rise being equal to or higher than a starting temperature of thermal decomposition of the polymer film, i.e., which is a temperature observed at an early stage of the thermal decomposition of the polymer film, to (ii) an upper limit to temperature rise being equal to or lower than an intermediate temperature of thermal decomposition of the polymer film. This reduces foaming in the film during graphitization treatment following the special heat treatment. Thus, even with a higher heating rate for graphitization, it is possible to produce a graphite film having good quality.

摘要翻译： 本发明在从（i）下限到升温等于或高于聚合物膜的热分解起始温度的温度范围内对聚合物膜进行特殊热处理，即，在 聚合物膜的热分解的早期阶段，（ii）升温的上限等于或低于聚合物膜的热分解中间温度。 这在特殊热处理之后的石墨化处理期间减少了膜中的起泡。 因此，即使用于石墨化的较高加热速率，也可以制造质量好的石墨膜。

公开(公告)号：US20140110869A1

公开(公告)日：2014-04-24

申请号：US14008227

申请日：2012-03-26

申请人： Makoto Mishiro ,  Yusuke Ohta ,  Takashi Inada ,  Yasushi Nishikawa

发明人： Makoto Mishiro ,  Yusuke Ohta ,  Takashi Inada ,  Yasushi Nishikawa

IPC分类号： C01B31/04

CPC分类号： B65D85/671 ,  C01B32/00 ,  C01B32/05 ,  C01B32/20 ,  C08G73/10 ,  Y10T428/24744

摘要： Disclosed herein is a method for producing an elongated (rolled) carbonaceous film by polymer pyrolysis while suppressing the fusion bonding of the carbonaceous film. The method for producing a carbonaceous film includes the step of heat-treating a polymer film wound into a roll, wherein the heat treatment is performed after the polymer film is wound into a roll to have a gap between adjacent layers of the polymer film at a temperature lower than a pyrolysis onset temperature of the polymer film so that the roll of polymer film as a whole satisfies a relationship that a value obtained by dividing a thickness of a gap between adjacent layers of the polymer film (Ts) by a thickness of the polymer film (Tf) (Ts/Tf) is 0.16 or higher but 1.50 or lower. As a method for forming gaps between the layers of the polymer film, a method in which the polymer film is wound into a roll together with a slip sheet and then the slip sheet is removed can be used, which is effective at suppressing the fusion bonding of a carbonaceous film.

摘要翻译： 本文公开了一种通过聚合物热分解制备细长（滚动）碳质膜的方法，同时抑制碳质膜的熔融粘合。 碳质膜的制造方法包括对卷绕成卷的聚合物膜进行热处理的步骤，其中在将聚合物膜卷绕成辊之后进行热处理，以在聚合物膜的相邻层之间具有间隙 温度低于聚合物膜的热解开始温度，使得聚合物膜的整体整体满足通过将聚合物膜（Ts）的相邻层之间的间隙的厚度除以通过将聚合物膜 聚合物膜（Tf）（Ts / Tf）为0.16以上且1.50以下。 作为在聚合物膜之间形成间隙的方法，可以使用其中将聚合物膜与滑动片一起卷绕成卷并且然后除去滑动片的方法，其有效地抑制熔融粘合 的碳质膜。

公开(公告)号：US20140004033A1

公开(公告)日：2014-01-02

申请号：US14005423

申请日：2012-03-15

申请人： Yusuke Ohta ,  Takashi Inada ,  Makoto Mishiro ,  Yasushi Nishikawa

发明人： Yusuke Ohta ,  Takashi Inada ,  Makoto Mishiro ,  Yasushi Nishikawa

IPC分类号： C01B31/04 ,  C01B31/02

CPC分类号： C01B31/04 ,  C04B35/522 ,  C04B35/524 ,  C04B35/62218 ,  H01L23/373 ,  H01L2924/0002 ,  H01L2924/00

摘要： A graphite film with fewer wrinkles and/or undulations is obtained providing two or more stages of heating space and carrying out continuous baking. Especially when a cooling space is provided between each of the heating spaces and another, a graphite film can be obtained which is excellent in flatness and has a high thermal diffusivity.

摘要翻译： 获得具有较少皱纹和/或起伏的石墨膜，其提供两个或多个加热空间阶段并进行连续烘烤。 特别是当在每个加热空间和另一个加热空间之间设置冷却空间时，可以获得平坦度优异并且具有高热扩散率的石墨膜。

公开(公告)号：US20120121880A1

公开(公告)日：2012-05-17

申请号：US13380373

申请日：2009-06-22

申请人： Yusuke Ohta ,  Makoto Mishiro ,  Takashi Inada ,  Yasushi Nishikawa

发明人： Yusuke Ohta ,  Makoto Mishiro ,  Takashi Inada ,  Yasushi Nishikawa

IPC分类号： B32B3/00 ,  C04B35/52

CPC分类号： C04B35/524 ,  C01B32/19 ,  C01B32/20 ,  C01B32/205 ,  C01B32/225 ,  Y10T428/30

摘要： Provided is a long and large-area graphite film having improved thermal diffusivity and flex resistance, and accompanied by ameliorated ruffling. According to a method for producing a graphite film, in which graphitization of a heat-treated film consisting of a carbonized polymer film is carried out in a state being wrapped around an internal core, the method being characterized in that a heat treatment is executed by controlling distance(s) between the internal core and the film, and/or between the layers of the film, a graphite film accompanied by significantly ameliorated ruffling can be obtained.

摘要翻译： 提供了具有改善的热扩散率和抗弯曲性的长且大面积的石墨膜，并伴随着改善的褶皱。 根据石墨膜的制造方法，其特征在于，在由碳化聚合物膜构成的热处理膜的石墨化被包裹在内部芯部的状态下进行，其特征在于，通过以下方式进行热处理： 可以获得控制内芯和薄膜之间和/或薄膜之间的距离，可以获得伴随显着改善的褶皱的石墨薄膜。