Process for producing polyethylene material of high strength and high
plastic modulus
    4.
    发明授权
    Process for producing polyethylene material of high strength and high plastic modulus 失效
    生产高强度,高塑性模量的聚乙烯材料的方法

    公开(公告)号:US5756660A

    公开(公告)日:1998-05-26

    申请号:US725058

    申请日:1996-10-02

    摘要: A polyethylene article such as film or fiber having high strength and high elastic modulus is produced by orienting an ultra-high molecular weight polyethylene having an intrinsic viscosity at 135.degree. C. in decalin of 5 to 50 dl/g, said ultra-high molecular weight polyethylene being prepared by homo- or copolymerizing ethylene in the presence of a catalyst system and hydrogen, said catalyst system comprising (1) a solid catalyst component containing at least magnesium, titanium and/or vanadium, (2) an organometallic compound and (3) a compound represented by the following general formula �I!: ##STR1## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each hydrogen or a hydrocarbon residue, with the proviso that any two of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 may conjointly form a cyclic hydrocarbon residue.

    摘要翻译: 聚萘乙烯制品如具有高强度和高弹性模量的薄膜或纤维通过在135℃的特性粘度在5至50分升/克的十氢化萘中取向,得到超高分子量聚乙烯 所述催化剂体系包含(1)至少含有镁,钛和/或钒的固体催化剂组分,(2)有机金属化合物和( 3)由以下通式[I]表示的化合物:原子或烃残基,条件是R 1,R 2,R 3和R 4中的任何两个可以结合形成环状烃残基。