公开(公告)号：US09512251B2

公开(公告)日：2016-12-06

申请号：US14404723

申请日：2013-05-30

Applicant: ZEON CORPORATION

Inventor： Kei Sakamoto ,  Kumi Okuyama

IPC: C08F122/24 ,  G02B1/08 ,  C08F222/24 ,  C07D513/04 ,  C07D277/82 ,  C09K19/24 ,  C09K19/32 ,  C09K19/34 ,  C09K19/38 ,  G02B5/30 ,  C09K19/04 ,  C09K19/20 ,  C08F222/10

CPC classification number: C08F22/24 ,  C07D277/82 ,  C07D513/04 ,  C08F122/24 ,  C08F222/24 ,  C08F2222/102 ,  C09K19/24 ,  C09K19/322 ,  C09K19/348 ,  C09K19/3486 ,  C09K19/3488 ,  C09K19/3497 ,  C09K19/3852 ,  C09K19/3861 ,  C09K2019/0448 ,  C09K2019/2078 ,  G02B1/08 ,  G02B5/3016 ,  G02B5/3025

Abstract: The present invention relates to: a polymerizable compound (I), wherein Y1 to Y6 are a chemical single bond, —O—C(═O)—, —C(═O)—O— or the like, G1 and G2 are a divalent aliphatic group, Z1 and Z2 are an alkenyl group, Ax is a fused ring group represented by a formula (II), wherein X is —NR3—, an oxygen atom, a sulfur atom or the like, R3 is a hydrogen atom or an alkyl group having 1 to 6 carbon atoms, and D is a substituted or unsubstituted ring having 1 to 20 carbon atoms that includes at least one nitrogen atom, Ay is a hydrogen atom, an alkyl group, A1 is a trivalent aromatic group or the like, A2 and A3 are a divalent aromatic group having 6 to 30 carbon atoms or the like, and Q1 is a hydrogen atom, or an alkyl group having 1 to 6 carbon atoms.

Abstract translation: 本发明涉及：可聚合化合物（1），其中Y 1至Y 6为化学单键，-OC（= O） - ， - C（= O）-O-等，G 1和G 2为碳原子数为1〜20的二价脂肪族基团，Z 1和Z 2为未取代或被卤素原子取代的碳原子数2〜10的烯基，A x为 式（II）其中X为-NR 3 - ，氧原子，硫原子等，R 3为氢原子或碳原子数1〜6的烷基，D为取代或未取代的环 具有1至20个碳原子，包括至少一个氮原子，A y是氢原子，具有1至20个碳原子的烷基等，A 1是三价芳族基团等，A 2和A 3 是碳原子数为6〜30的二价芳香族基团，Q 1为氢原子或碳原子数为1〜6的烷基。 本发明提供一种具有实用低熔点，在通用溶剂中表现出优异溶解性的聚合性化合物，聚合性组合物和聚合物，可以制造出低成本的光学膜， 在宽波长带上的偏振光，以及光学各向异性物品。

公开(公告)号：US20160200841A1

公开(公告)日：2016-07-14

申请号：US14913233

申请日：2014-08-14

Applicant: ZEON CORPORATION

Inventor： Kei SAKAMOTO

IPC: C08F122/24 ,  C07D277/82

CPC classification number: C08F122/24 ,  C07D277/82 ,  C08F122/12 ,  C08F220/30 ,  C08F222/10 ,  C08F222/1006 ,  C08F2222/102 ,  C08F2222/1013

Abstract: The present invention relates to: a polymerizable compound represented by a formula (I), wherein each of Y1 to Y8 independently represents —O—, —O—C(═O)—, —C(═O)—O— or the like; each of A2, A3, G1, and G2 independently represents a divalent linear aliphatic group having 1 to 20 carbon atoms or the like; each of Z1 and Z2 independently represents an alkenyl group having 2 to 10 carbon atoms or the like; Ax represents an organic group having 2 to 30 carbon atoms that includes at least one aromatic ring; Ay represents a hydrogen atom, an alkyl group having 1 to 20 carbon atoms or the like; A1 represents a trivalent aromatic group or the like; each of A4 and A5 independently represents a divalent aromatic group having 6 to 30 carbon atoms or the like; and Q1 represents a hydrogen atom, an alkyl group having 1 to 6 carbon atoms or the like; and others. According to the present invention, it becomes possible to provide: a polymerizable compound that have a practical low melting point, exhibit excellent solubility in a general-purpose solvent, can be produced inexpensively, can be dried at a lower temperature, has excellent energy efficiency, and can produce an optical film that achieves uniform conversion of polarized light over a wide wavelength band; and others.

Abstract translation: 本发明涉及：由式（I）表示的可聚合化合物，其中Y 1至Y 8各自独立地表示-O-，-O-C（= O） - ， - C（= O）-O-或 喜欢; A2，A3，G1和G2各自独立地表示具有1至20个碳原子的二价直链脂肪族基团等; Z 1和Z 2各自独立地表示具有2〜10个碳原子的链烯基等; Ax表示包含至少一个芳环的具有2-30个碳原子的有机基团; Ay表示氢原子，碳原子数1〜20的烷基等; A1表示三价芳族基团等; A4和A5各自独立地表示碳原子数为6〜30的二价芳香族基团等。 Q 1表示氢原子，碳原子数1〜6的烷基等; 和别的。 根据本发明，可以提供：具有实用的低熔点，在通用溶剂中表现出优异的溶解性的可聚合化合物可以廉价地生产，可以在较低的温度下干燥，具有优异的能量效率 并且可以产生在宽波长带上实现偏振光的均匀转换的光学膜; 和别的。

公开(公告)号：US09207360B2

公开(公告)日：2015-12-08

申请号：US14114073

申请日：2012-04-27

Applicant: Kei Sakamoto ,  Kumi Okuyama

Inventor： Kei Sakamoto ,  Kumi Okuyama

IPC: C07C251/82 ,  C07C251/86 ,  C07D277/82 ,  G02B1/08 ,  G02B5/30 ,  C07D215/38 ,  C07D237/34 ,  C07D263/58 ,  C08F220/34 ,  C08F222/10

CPC classification number: C08F122/24 ,  C07C69/92 ,  C07C243/20 ,  C07C251/86 ,  C07D215/38 ,  C07D237/34 ,  C07D263/58 ,  C07D277/82 ,  C07D487/04 ,  C08F122/22 ,  C08F220/34 ,  C08F222/1006 ,  G02B1/08 ,  G02B5/3016 ,  G02B5/3083

Abstract: The present invention relates to a polymerizable compound represented by a formula (I). The present invention provides a polymerizable compound, a polymerizable composition, a polymer, and an optically anisotropic article that are capable of obtaining an optical film having a low melting point, having excellent solubility, capable of being manufactured at low cost, and capable of uniform polarized light conversion across a broad wavelength region. [In formula: Y1 to Y6 are independently a chemical single bond, —O—, —O—C(═O)—, —C(═O)—O— etc.; G1 and G2 are independently a divalent C1-C20 aliphatic group etc.; Z1 and Z2 are independently C2-C10 alkenyl group that is substituted with a halogen atom etc.; Ax is a C2-C30 organic group that includes at least one aromatic ring selected from a group consisting of an aromatic hydrocarbon ring and an aromatic hetero ring; Ay is a hydrogen atom, a C1-C20 alkyl group, a C2-C20 alkenyl group, a C3-C12 cycloalkyl group etc.; A1 is a trivalent aromatic group etc.; A2 and A3 are independently a divalent C6-C30 aromatic group etc.; and Q1 is a hydrogen atom, or a C1-C6 alkyl group etc.]

Abstract translation: 本发明涉及由式（I）表示的可聚合化合物。 本发明提供一种能够得到低熔点，溶解性优异的光学膜的聚合性化合物，聚合性组合物，聚合物和光学各向异性物品，能够以低成本制造，能够均匀 在宽波长区域的偏振光转换。 [式中，Y1〜Y6独立地为化学单键，-O - ， - O-C（= O） - ， - C（= O）-O-等）。 G1和G2独立地是二价C1-C20脂族基团等; Z 1和Z 2独立地为被卤素原子等取代的C 2 -C 10烯基; Ax是包含至少一个选自芳族烃环和芳族杂环的芳环的C 2 -C 30有机基团; Ay是氢原子，C1-C20烷基，C2-C20烯基，C3-C12环烷基等; A1是三价芳族基团等。 A2和A3独立地为二价C 6 -C 30芳族基团等; 并且Q 1是氢原子或C 1 -C 6烷基等]

公开(公告)号：US20170260150A1

公开(公告)日：2017-09-14

申请号：US15532224

申请日：2015-12-01

Applicant: DIC Corporation

Inventor： Sayaka Nose ,  Yuji Ohashi ,  Junichi Mamiya ,  Akihiro Koiso ,  Tatsufumi Yamazaki

IPC: C07D277/82 ,  C07D277/84 ,  C07D263/58 ,  H01L51/00 ,  C07D277/50 ,  C08F122/24 ,  H01L51/52 ,  C07C243/22 ,  C07D209/40

CPC classification number: C07D277/82 ,  C07C243/22 ,  C07C251/80 ,  C07C251/88 ,  C07C2601/14 ,  C07C2602/42 ,  C07C2603/18 ,  C07D209/40 ,  C07D263/58 ,  C07D277/50 ,  C07D277/84 ,  C07D409/14 ,  C07D417/12 ,  C08F20/34 ,  C08F122/24 ,  C08G59/02 ,  C08G65/18 ,  G02B5/3016 ,  G02F1/133528 ,  G02F2202/022 ,  H01L51/0036 ,  H01L51/004 ,  H01L51/0043 ,  H01L51/5012 ,  H01L51/5293

Abstract: It is an object of the present invention to provide a polymerizable compound having a good liquid crystal property, a good alignment property, sufficient solubility in solvents, high preservation stability in a solution state, and high optical stability; a composition including the polymerizable compound; a polymer produced by polymerizing the polymerizable compound, such as a resin produced using the polymerizable compound; an optically anisotropic body including the polymer; and a liquid crystal display element and an organic EL device that include the optically anisotropic body. As a result of conducting intensive studies in order to achieve the above object, the compound represented by General Formula (I) is developed.

公开(公告)号：US20170037159A1

公开(公告)日：2017-02-09

申请号：US15100108

申请日：2014-11-27

Applicant: DIC CORPORATION

Inventor： Hiroshi Hasebe ,  Yoshio Aoki ,  Kunihiko Kotani ,  Akihiro Koiso ,  Hidetoshi Nakata

IPC: C08F122/24 ,  C07D409/04 ,  C07D417/04 ,  C07D413/04 ,  C07D471/04 ,  H01L51/52 ,  C09K19/02 ,  C09K19/34 ,  H01L51/00 ,  G02F1/13363 ,  G02B5/30 ,  C07D339/06 ,  C09K19/38

CPC classification number: C08F122/24 ,  C07D339/06 ,  C07D409/04 ,  C07D413/04 ,  C07D417/04 ,  C07D471/04 ,  C08F222/10 ,  C08F2222/1013 ,  C09K19/02 ,  C09K19/32 ,  C09K19/34 ,  C09K19/3483 ,  C09K19/3486 ,  C09K19/3491 ,  C09K19/3497 ,  C09K19/38 ,  C09K19/3861 ,  C09K2019/0448 ,  G02B5/3016 ,  G02F1/13363 ,  G02F2001/133633 ,  H01L51/004 ,  H01L51/0074 ,  H01L51/5281

Abstract: An object of the invention is to provide polymerizable compounds having excellent optical characteristics and suited as materials for optically anisotropic articles, compositions containing the polymerizable compounds, polymers obtained by polymerising the polymerizable compounds, optically anisotropic articles formed of the polymers, and liquid crystal display devices including the optically anisotropic articles.

Abstract translation: 本发明的目的是提供具有优异的光学特性并且适合作为光学各向异性物品的材料的聚合性化合物，含有可聚合化合物的组合物，聚合化合物得到的聚合物，由该聚合物形成的光学各向异性物品和液晶显示装置 包括光学各向异性物品。

公开(公告)号：US20140142266A1

公开(公告)日：2014-05-22

申请号：US14114073

申请日：2012-04-27

Applicant: Kei Sakamoto ,  Kumi Okuyama

Inventor： Kei Sakamoto ,  Kumi Okuyama

IPC: G02B1/08

CPC classification number: C08F122/24 ,  C07C69/92 ,  C07C243/20 ,  C07C251/86 ,  C07D215/38 ,  C07D237/34 ,  C07D263/58 ,  C07D277/82 ,  C07D487/04 ,  C08F122/22 ,  C08F220/34 ,  C08F222/1006 ,  G02B1/08 ,  G02B5/3016 ,  G02B5/3083

Abstract: The present invention relates to a polymerizable compound represented by a formula (I). The present invention provides a polymerizable compound, a polymerizable composition, a polymer, and an optically anisotropic article that are capable of obtaining an optical film having a low melting point, having excellent solubility, capable of being manufactured at low cost, and capable of uniform polarized light conversion across a broad wavelength region. [In formula: Y1 to Y6 are independently a chemical single bond, —O—, —O—C(═O)—, —C(═O)—O— etc.; G1 and G2 are independently a divalent C1-C20 aliphatic group etc.; Z1 and Z2 are independently C2-C10 alkenyl group that is substituted with a halogen atom etc.; Ax is a C2-C30 organic group that includes at least one aromatic ring selected from a group consisting of an aromatic hydrocarbon ring and an aromatic hetero ring; Ay is a hydrogen atom, a C1-C20 alkyl group, a C2-C20 alkenyl group, a C3-C12 cycloalkyl group etc.; A1 is a trivalent aromatic group etc.; A2 and A3 are independently a divalent C6-C30 aromatic group etc.; and Q1 is a hydrogen atom, or a C1-C6 alkyl group etc.]

Abstract translation: 本发明涉及由式（I）表示的可聚合化合物。 本发明提供一种能够得到低熔点，溶解性优异的光学膜的聚合性化合物，聚合性组合物，聚合物和光学各向异性物品，能够以低成本制造，能够均匀 在宽波长区域的偏振光转换。 [式中，Y1〜Y6独立地为化学单键，-O - ， - O-C（= O） - ， - C（= O）-O-等）。 G1和G2独立地是二价C1-C20脂族基团等; Z 1和Z 2独立地为被卤素原子等取代的C 2 -C 10烯基; Ax是包含至少一个选自芳族烃环和芳族杂环的芳环的C 2 -C 30有机基团; Ay是氢原子，C1-C20烷基，C2-C20烯基，C3-C12环烷基等; A1是三价芳族基团等。 A2和A3独立地为二价C 6 -C 30芳族基团等; 并且Q 1是氢原子或C 1 -C 6烷基等]

公开(公告)号：US09856333B2

公开(公告)日：2018-01-02

申请号：US15338987

申请日：2016-10-31

Applicant: ZEON CORPORATION

Inventor： Kei Sakamoto ,  Kumi Okuyama

IPC: C08F22/24 ,  C07D277/82 ,  G02B5/30 ,  C09K19/34 ,  G02B1/08 ,  C07D513/04 ,  C09K19/38 ,  C09K19/24 ,  C09K19/32 ,  C08F122/24 ,  C08F222/24 ,  C09K19/04 ,  C09K19/20 ,  C08F222/10

CPC classification number: C08F22/24 ,  C07D277/82 ,  C07D513/04 ,  C08F122/24 ,  C08F222/24 ,  C08F2222/102 ,  C09K19/24 ,  C09K19/322 ,  C09K19/348 ,  C09K19/3486 ,  C09K19/3488 ,  C09K19/3497 ,  C09K19/3852 ,  C09K19/3861 ,  C09K2019/0448 ,  C09K2019/2078 ,  G02B1/08 ,  G02B5/3016 ,  G02B5/3025

Abstract: The present invention relates to: a polymerizable compound (I), wherein Y1 to Y6 are a chemical single bond, —O—C(═O)—, —C(═O)—O— or the like, G1 and G2 are a divalent aliphatic group, Z1 and Z2 are an alkenyl group, Ax is a fused ring group represented by a formula (II), wherein X is —NR3—, an oxygen atom, a sulfur atom or the like, R3 is a hydrogen atom or an alkyl group having 1 to 6 carbon atoms, and D is a substituted or unsubstituted ring having 1 to 20 carbon atoms that includes at least one nitrogen atom, Ay is a hydrogen atom, an alkyl group, A1 is a trivalent aromatic group or the like, A2 and A3 are a divalent aromatic group having 6 to 30 carbon atoms or the like, and Q1 is a hydrogen atom, or an alkyl group having 1 to 6 carbon atoms.

公开(公告)号：US09777093B2

公开(公告)日：2017-10-03

申请号：US15228584

申请日：2016-08-04

Applicant: SHIN-ETSU CHEMICAL CO., LTD.

Inventor： Jun Hatakeyama ,  Takayuki Fujiwara ,  Takayuki Nagasawa ,  Koji Hasegawa

IPC: C08F220/38 ,  C08F120/38 ,  C08F212/14 ,  H01B1/12 ,  C08F20/38 ,  C08F228/02 ,  C08F28/02 ,  C08F14/18 ,  C08F122/24 ,  C08F128/02 ,  C08F12/20 ,  C08F12/30 ,  C08F16/30

CPC classification number: C08F220/38 ,  C08F12/20 ,  C08F12/30 ,  C08F14/18 ,  C08F16/30 ,  C08F20/38 ,  C08F28/02 ,  C08F120/38 ,  C08F122/24 ,  C08F128/02 ,  C08F212/14 ,  C08F228/02 ,  C08F2220/387 ,  H01B1/122 ,  H01B1/124 ,  H01B1/125

Abstract: A polymer compound for a conductive polymer including one or more repeating units “a” shown by the following general formula (1), and having a weight-average molecular weight in the range of 1,000 to 500,000, wherein R1 represents a hydrogen atom or a methyl group; R2 represents any of a single bond, an ester group, and a linear, branched, or cyclic hydrocarbon group having 1 to 12 carbon atoms and optionally containing either or both of an ether group and an ester group; R3 represents a linear or branched alkyl group having 1 to 4 carbon atoms with one or more hydrogen atoms in R3 being substituted by a fluorine atom(s); “Z” represents any of a single bond, a phenylene group, a naphthylene group, an ether group, and an ester group; and “a” is a number satisfying 0

公开(公告)号：US20170029655A1

公开(公告)日：2017-02-02

申请号：US15039668

申请日：2014-11-27

Applicant: DIC Corporation

Inventor： Hiroshi HASEBE ,  Yoshio AOKI ,  Kunihiko KOTANI ,  Akihiro KOISO ,  Hidetoshi NAKATA

IPC: C09D135/02 ,  C07D277/82 ,  G02B5/30 ,  H01L51/52 ,  H01L51/00 ,  G02F1/13363 ,  C07D277/64 ,  C08F122/24

CPC classification number: C09D135/02 ,  C07D277/64 ,  C07D277/66 ,  C07D277/82 ,  C08F22/10 ,  C08F122/24 ,  C08F222/1006 ,  C08F2222/102 ,  C08F2500/26 ,  C09K19/3068 ,  C09K19/3497 ,  C09K2019/0448 ,  G02B5/3083 ,  G02F1/13363 ,  H01L51/004 ,  H01L51/0076 ,  H01L51/5262

Abstract: It is an object of the present invention to provide a polymerizable compound suitable as a material for optically anisotropic bodies having excellent optical properties, a composition containing the polymerizable compound, a polymer obtained by polymerizing the polymerizable compound, an optically anisotropic body formed of the polymer, and a liquid crystal display device including the optically anisotropic body.

公开(公告)号：US20180072830A1

公开(公告)日：2018-03-15

申请号：US15818095

申请日：2017-11-20

Applicant: Asahi Glass Company, Limited

Inventor： Jun YOSHIDA ,  Keisuke TAKAGI ,  Hidenobu MUROFUSHI ,  Tomoaki SAKURADA

IPC: C08F122/22 ,  C07C271/16 ,  C07C323/43 ,  C07D303/28 ,  C08G59/68 ,  C08F122/24 ,  C08G59/30

CPC classification number: C08F122/22 ,  C07C271/16 ,  C07C323/12 ,  C07C323/43 ,  C07D303/28 ,  C08F122/24 ,  C08F2222/225 ,  C08G59/04 ,  C08G59/308 ,  C08G59/687 ,  C08G65/007 ,  C08G65/3312 ,  C08G65/33306 ,  C08G65/33348 ,  C08G65/3342

Abstract: To provide a fluorinated compound capable of obtaining a cured product which is excellent in heat resistance and mold release and has a high Abbe number; a curable composition containing such a compound; and a cured product which is excellent in heat resistance and mold release and has a high Abbe number. The fluorinated compound is represented by the following formula (A): [Z—OCH2CF2CF2CF2OCFHCF2—X-]nQ  (A) where n is an integer of at least 1, Q is a n-valent organic group, X is —O—, —NH— or —S—, and Z is a group having at least one polymerizable functional group.