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    SOLID CATALYST COMPONENT AND CATALYST FOR OLEFIN POLYMERIZATION
    1.
    发明申请
    SOLID CATALYST COMPONENT AND CATALYST FOR OLEFIN POLYMERIZATION 有权
    用于烯烃聚合的固体催化剂组分和催化剂

    公开(公告)号：US20130324682A1

    公开(公告)日：2013-12-05

    申请号：US13980359

    申请日：2012-01-19

    申请人： Zhong TAN ,  Lunjia Xie ,  Xiudong Xu ,  Yu Tian ,  Qilong Zhou ,  Zaixing Feng ,  Li'an Yan ,  Siyuan Zhao ,  Jinhua Yu ,  Zhufang Sun ,  Fengkui Li ,  Shanshan Yin ,  Weiwei Song

    发明人： Zhong TAN ,  Lunjia Xie ,  Xiudong Xu ,  Yu Tian ,  Qilong Zhou ,  Zaixing Feng ,  Li'an Yan ,  Siyuan Zhao ,  Jinhua Yu ,  Zhufang Sun ,  Fengkui Li ,  Shanshan Yin ,  Weiwei Song

    IPC分类号： C08F110/06

    CPC分类号： C08F110/06 ,  C08F10/06 ,  C08F4/651 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/15 ,  C08F4/6548

    摘要： Disclosed is a solid catalyst component for olefin polymerization. The catalyst component comprises a dialkoxy magnesium carrier, a titanium compound, and a product from an internal electron donor reacting in an inert solvent. Said internal electron donor compound comprises a 2,3-di-non-linear-alkyl-2-cyano succinic acid diester compound as presented in formula I: as in formula I, R1 and R2 radicals are independently chosen from linear or branched C1-C4 alkyl groups; R is chosen from C3-C6 iso-alkyl, sec-alkyl, or cycloalkyl groups. Also disclosed is another solid catalyst component. The catalyst component comprises a dialkoxy magnesium carrier, a titanium compound, and a product from an internal electron donor reacting in an inert solvent. In addition to a 2,3-di-non-linear-alkyl-2-cyano succinic acid diester compound as presented in formula I, the internal electron donor compound can also comprise 2-isopropyl-2-(3-methylbutyl)-1,3-dimethoxy propane and/or a carboxylic ester compound. Also disclosed is a catalyst containing the solid catalyst component. The catalyst is used for olefin polymerization, particularly propylene polymerization, and is relatively active during polymerization. The obtained polymer has the advantages of wide molecular weight distribution, high molecular bulk density, good hydrogen regulation sensitivity, good stereospecificity, good particle shape, and small fine powder content.

    摘要翻译： 公开了用于烯烃聚合的固体催化剂组分。 催化剂组分包括二烷氧基镁载体，钛化合物和在惰性溶剂中反应的内电子给体的产物。 所述内电子给体化合物包含式I所示的2,3-二 - 非线性 - 烷基-2-氰基琥珀酸二酯化合物：如式I所示，R 1和R 2基团独立地选自直链或支链C1- C4烷基; R选自C 3 -C 6异烷基，仲烷基或环烷基。 还公开了另一种固体催化剂组分。 催化剂组分包括二烷氧基镁载体，钛化合物和在惰性溶剂中反应的内电子给体的产物。 除了式I所示的2,3-二 - 非线性 - 烷基-2-氰基琥珀酸二酯化合物之外，内电子给体化合物还可以包含2-异丙基-2-（3-甲基丁基）-1 ，3-二甲氧基丙烷和/或羧酸酯化合物。 还公开了含有固体催化剂组分的催化剂。 该催化剂用于烯烃聚合，特别是丙烯聚合，并且在聚合期间相对有活性。 得到的聚合物具有分子量分布宽，分子体积密度高，调节灵敏度好，立体定向性好，粒子形状好，细粉含量低的优点。