公开(公告)号：US20060041157A1

公开(公告)日：2006-02-23

申请号：US11165962

申请日：2005-06-24

申请人： Zoran Petrovic ,  Ivan Javni ,  Alisa Zlatanic ,  Andrew Guo

发明人： Zoran Petrovic ,  Ivan Javni ,  Alisa Zlatanic ,  Andrew Guo

IPC分类号： C07C67/31

CPC分类号： C08G18/36 ,  C07D303/42

摘要： Methods of making unsaturated modified vegetable oil-based polyols are described. Also described are methods of making oligomeric modified vegetable oil-based polyols. An oligomeric composition having a modified fatty acid triglyceride structure is also described. Also, methods of making a polyol including hydroformylation and hydrogenation of oils in the presence of a catalyst and support are described.

摘要翻译： 描述了制备不饱和改性植物油基多元醇的方法。 还描述了制备低聚改性植物油基多元醇的方法。 还描述了具有改性脂肪酸甘油三酯结构的低聚组合物。 另外，描述了在催化剂和载体的存在下制备包括加氢甲酰基化和油化氢化的多元醇的方法。

公开(公告)号：US07786239B2

公开(公告)日：2010-08-31

申请号：US11165962

申请日：2005-06-24

申请人： Zoran S. Petrovic ,  Ivan Javni ,  Alisa Zlatanic ,  Andrew Guo

发明人： Zoran S. Petrovic ,  Ivan Javni ,  Alisa Zlatanic ,  Andrew Guo

IPC分类号： C08G83/00 ,  C07D303/00

CPC分类号： C08G18/36 ,  C07D303/42

摘要： Methods of making unsaturated modified vegetable oil-based polyols are described. Also described are methods of making oligomeric modified vegetable oil-based polyols. An oligomeric composition having a modified fatty acid triglyceride structure is also described. Also, methods of making a polyol including hydroformylation and hydrogenation of oils in the presence of a catalyst and support are described.

摘要翻译： 描述了制备不饱和改性植物油基多元醇的方法。 还描述了制备低聚改性植物油基多元醇的方法。 还描述了具有改性脂肪酸甘油三酯结构的低聚组合物。 另外，描述了在催化剂和载体的存在下制备包括加氢甲酰基化和油化氢化的多元醇的方法。

公开(公告)号：US20100311992A1

公开(公告)日：2010-12-09

申请号：US12792318

申请日：2010-06-02

申请人： Zoran S. PETROVIC ,  Ivan Javni ,  Alisa Zlatanic ,  Andrew Guo

发明人： Zoran S. PETROVIC ,  Ivan Javni ,  Alisa Zlatanic ,  Andrew Guo

IPC分类号： C07C67/31 ,  C07D301/00

CPC分类号： C08G18/36 ,  C07D303/42

摘要： Methods of making unsaturated modified vegetable oil-based polyols are described. Also described are methods of making oligomeric modified vegetable oil-based polyols. An oligomeric composition having a modified fatty acid triglyceride structure is also described. Also, methods of making a polyol including hydroformylation and hydrogenation of oils in the presence of a catalyst and support are described.

摘要翻译： 描述了制备不饱和改性植物油基多元醇的方法。 还描述了制备低聚改性植物油基多元醇的方法。 还描述了具有改性脂肪酸甘油三酯结构的低聚组合物。 另外，描述了在催化剂和载体的存在下制备包括加氢甲酰基化和油化氢化的多元醇的方法。

公开(公告)号：US06573354B1

公开(公告)日：2003-06-03

申请号：US09567997

申请日：2000-05-10

申请人： Zoran Petrovic ,  Andrew Guo ,  Ivan Javni

发明人： Zoran Petrovic ,  Andrew Guo ,  Ivan Javni

IPC分类号： C08J300

CPC分类号： C08G18/36 ,  C07D303/42 ,  C08G2190/00

摘要： A vegetable oil-based polyol is made by adding a peroxyacid to vegetable oil wherein said peroxyacid reacts with said vegetable oil to form epoxidized vegetable oil and adding said epoxidized vegetable oil to a mixture of an alcohol, water, and a catalytic amount of fluoboric acid so as to form a vegetable oil-based polyol. A further embodiment of the present invention involves making a vegetable oil-based polyol using an epoxidized vegetable oil as the starting material. The epoxidized vegetable oil undergoes hydroxylation by the same process as outlined above. According to another aspect of the present invention, the vegetable oil-based polyol formed by the novel methods of this invention may be reacted with an isocyanate to form a polyurethane. Alternatively, a filler such as silica may be combined with the vegetable oil-based polyol before it is reacted with the isocyanate. These polyurethanes made from vegetable oil-based polyols may be used to form electroinsulating casting resins.

摘要翻译： 通过向植物油中加入过氧酸而制备植物油性多元醇，其中所述过氧酸与所述植物油反应形成环氧化植物油，并将所述环氧化植物油加入到醇，水和催化量的氟硼酸的混合物中 以形成植物油基多元醇。 本发明的另一个实施方案涉及使用环氧化植物油作为原料制备植物油基多元醇。 环氧化植物油通过与上述相同的方法进行羟基化。 根据本发明的另一方面，通过本发明的新方法形成的植物油基多元醇可以与异氰酸酯反应形成聚氨酯。 或者，诸如二氧化硅的填料可以在与异氰酸酯反应之前与植物油基多元醇组合。 这些由植物油基多元醇制成的聚氨酯可用于形成电绝缘铸塑树脂。

公开(公告)号：US6107433A

公开(公告)日：2000-08-22

申请号：US187992

申请日：1998-11-06

申请人： Zoran Petrovic ,  Andrew Guo ,  Ivan Javni

发明人： Zoran Petrovic ,  Andrew Guo ,  Ivan Javni

IPC分类号： C07D303/42 ,  C08G18/36 ,  C08G83/00 ,  C07D301/00 ,  C07D301/14 ,  C07D301/19 ,  C07D303/00

CPC分类号： C08G18/36 ,  C07D303/42 ,  C08G2190/00

摘要： A vegetable oil-based polyol is made by adding a peroxyacid to vegetable oil wherein said peroxyacid reacts with said vegetable oil to form epoxidized vegetable oil and adding said epoxidized vegetable oil to a mixture of an alcohol, water, and a catalytic amount of fluoboric acid so as to form a vegetable oil-based polyol. A further embodiment of the present invention involves making a vegetable oil-based polyol using an epoxidized vegetable oil as the starting material. The epoxidized vegetable oil undergoes hydroxylation by the same process as outlined above. According to another aspect of the present invention, the vegetable oil-based polyol formed by the novel methods of this invention may be reacted with an isocyanate to form a polyurethane. Alternatively, a filler such as silica may be combined with the vegetable oil-based polyol before it is reacted with the isocyanate. These polyurethanes made from vegetable oil-based polyols may be used to form electroinsulating casting resins.

摘要翻译： 通过向植物油中加入过氧酸而制备植物油性多元醇，其中所述过氧酸与所述植物油反应形成环氧化植物油，并将所述环氧化植物油加入到醇，水和催化量的氟硼酸的混合物中 以形成植物油基多元醇。 本发明的另一个实施方案涉及使用环氧化植物油作为原料制备植物油基多元醇。 环氧化植物油通过与上述相同的方法进行羟基化。 根据本发明的另一方面，通过本发明的新方法形成的植物油基多元醇可以与异氰酸酯反应形成聚氨酯。 或者，诸如二氧化硅的填料可以在与异氰酸酯反应之前与植物油基多元醇组合。 这些由植物油基多元醇制成的聚氨酯可用于形成电绝缘铸塑树脂。

公开(公告)号：US06433121B1

公开(公告)日：2002-08-13

申请号：US09612716

申请日：2000-07-10

申请人： Zoran Petrovic ,  Ivan Javni ,  Andrew Guo ,  Wei Zhang

发明人： Zoran Petrovic ,  Ivan Javni ,  Andrew Guo ,  Wei Zhang

IPC分类号： C08J300

CPC分类号： C07D303/42 ,  C08G18/36 ,  C08G2190/00

摘要： A method for making natural oil-based polyols directly from vegetable or animal oil using a consecutive two-step process involving epoxidation and hydroxylation is provided. Specifically, this process comprises adding a peroxyacid to a natural oil wherein said natural oil and said peroxyacid react to form an epoxidized natural oil and adding said epoxidized natural oil to a mixture of an alcohol, water, and a fluoboric acid catalyst. The catalytic amount of fluoboric acid is less than about 0.5% by weight of the entire reaction mixture, and the amount of water is about 10 to 30% by weight of the entire mixture. The epoxidized natural oil undergoes hydroxylation and forms a natural oil-based polyol. The present invention further includes a method for making natural oil-based polyols from epoxidized oil by hydroylating the epoxidized oil in the presence of fluoboric acid, alcohol and water in the amounts discussed above. The natural oil-based polyols created by this method may be reacted with isocyanates so as to form polyurethanes, which is another embodiment of the present invention. Alternatively, fillers such as silica may be combined with these natural oil-based polyols before they are reacted with isocyanates to form polyurethanes. In still another embodiment of the present invention, polyurethanes made from natural oil-based polyols may be used to form electroinsulating casting resins for use in electrical applications.

摘要翻译： 提供了一种使用直接由植物油或动物油直接制备天然油基多元醇的方法，该方法使用涉及环氧化和羟基化的连续两步法。 具体地，该方法包括向天然油中加入过氧酸，其中所述天然油和所述过氧酸反应形成环氧化天然油，并将所述环氧化天然油加入到醇，水和氟硼酸催化剂的混合物中。 氟硼酸的催化量小于整个反应混合物的约0.5重量％，水的量为整个混合物的约10至30重量％。 环氧化天然油经历羟基化，形成天然油基多元醇。 本发明还包括通过在上述量的氟硼酸，醇和水的存在下对环氧化油进行水解来制备环氧化油的天然油基多元醇的方法。通过该方法制备的天然油基多元醇可以是 与异氰酸酯反应以形成聚氨酯，这是本发明的另一个实施方案。 或者，诸如二氧化硅的填料可以在与异氰酸酯反应形成聚氨酯之前与这些天然油基多元醇组合。 在本发明的另一个实施方案中，由天然油基多元醇制成的聚氨酯可用于形成用于电气应用的电绝缘铸塑树脂。

公开(公告)号：US06686435B1

公开(公告)日：2004-02-03

申请号：US10176214

申请日：2002-06-20

申请人： Zoran Petrovic ,  Ivan Javni ,  Andrew Guo ,  Wei Zhang

发明人： Zoran Petrovic ,  Ivan Javni ,  Andrew Guo ,  Wei Zhang

IPC分类号： C08J300

CPC分类号： C07D303/42 ,  C08G18/36 ,  C08G2190/00

摘要： A method for making natural oil-based polyols directly from vegetable or animal oil using a consecutive two-step process involving epoxidation and hydroxylation is provided. Specifically, this process comprises adding a peroxyacid to a natural oil wherein said natural oil and said peroxyacid react to form an epoxidized natural oil and adding said epoxidized natural oil to a mixture of an alcohol, water, and a fluoboric acid catalyst. The catalytic amount of fluoboric acid is less than about 0.5% by weight of the entire reaction mixture, and the amount of water is about 10 to 30% by weight of the entire mixture. The epoxidized natural oil undergoes hydroxylation and forms a natural oil-based polyol. The present invention further includes a method for making natural oil-based polyols from epoxidized oil by hydroylating the epoxidized oil in the presence of fluoboric acid, alcohol and water in the amounts discussed above. The natural oil-based polyols created by this method may be reacted with isocyanates so as to form polyurethanes, which is another embodiment of the present invention. Alternatively, fillers such as silica may be combined with these natural oil-based polyols before they are reacted with isocyanates to form polyurethanes. In still another embodiment of the present invention, polyurethanes made from natural oil-based polyols may be used to form electroinsulating casting resins for use in electrical applications.

摘要翻译： 提供了一种使用直接由植物油或动物油直接制备天然油基多元醇的方法，该方法使用涉及环氧化和羟基化的连续两步法。 具体地，该方法包括向天然油中加入过氧酸，其中所述天然油和所述过氧酸反应形成环氧化天然油，并将所述环氧化天然油加入到醇，水和氟硼酸催化剂的混合物中。 氟硼酸的催化量小于整个反应混合物的约0.5重量％，水的量为整个混合物的约10至30重量％。 环氧化天然油经历羟基化，形成天然油基多元醇。 本发明还包括通过在上述量的氟硼酸，醇和水的存在下对环氧化油进行水解来制备环氧化油的天然油基多元醇的方法。通过该方法制备的天然油基多元醇可以是 与异氰酸酯反应以形成聚氨酯，这是本发明的另一个实施方案。 或者，诸如二氧化硅的填料可以在与异氰酸酯反应形成聚氨酯之前与这些天然油基多元醇组合。 在本发明的另一个实施方案中，由天然油基多元醇制成的聚氨酯可用于形成用于电气应用的电绝缘铸塑树脂。

公开(公告)号：US09487467B2

公开(公告)日：2016-11-08

申请号：US14004887

申请日：2012-03-07

申请人： Douglas Hillshafer ,  Andrew Guo

发明人： Douglas Hillshafer ,  Andrew Guo

IPC分类号： C07C67/08 ,  C08G18/08 ,  C08G18/34 ,  C08G18/42 ,  C08G63/181 ,  C09D175/06 ,  C09J175/06

CPC分类号： C07C67/08 ,  C08G18/14 ,  C08G18/341 ,  C08G18/4211 ,  C08G18/4252 ,  C08G63/181 ,  C09D175/06 ,  C09J175/06

摘要： A method for producing a polyester polyol is disclosed. The method comprises reacting phthalic anhydride with a diol selected from the group consisting of ethylene glycol, propylene glycol, 1,3-propanediol, 2-methyl-1,3-propanediol, neopentyl glycol, 1,6-hexanediol, polyethylene glycols having a number average molecular weight within the range of 200 g/mol to 600 g/mol, and mixtures thereof at a diol to phthalic anhydride molar ratio within the range of 1.1 to 1.6. The resulting o-phthalate polyester polyol has a hydroxyl value in the range of 18 to 400 mg KOH/g, an acid value in the range of 0.2 to 5.0 mg KOH/g, and 1 wt. % or less of cyclic esters.

摘要翻译： 公开了一种聚酯多元醇的制造方法。 该方法包括使邻苯二甲酸酐与选自乙二醇，丙二醇，1,3-丙二醇，2-甲基-1,3-丙二醇，新戊二醇，1,6-己二醇，具有 数均分子量在200g / mol至600g / mol的范围内，以及其在二醇与邻苯二甲酸酐摩尔比在1.1至1.6范围内的混合物。 得到的邻苯二甲酸酯聚酯多元醇的羟基值在18-400mg KOH / g的范围内，酸值在0.2-5.0mg KOH / g的范围内，和1wt。 ％以下的环状酯。

公开(公告)号：US20140018458A1

公开(公告)日：2014-01-16

申请号：US14004887

申请日：2012-03-07

申请人： Douglas Hillshafer ,  Andrew Guo

发明人： Douglas Hillshafer ,  Andrew Guo

IPC分类号： C07C67/08 ,  C09D175/06 ,  C08G18/34 ,  C09J175/06

CPC分类号： C07C67/08 ,  C08G18/14 ,  C08G18/341 ,  C08G18/4211 ,  C08G18/4252 ,  C08G63/181 ,  C09D175/06 ,  C09J175/06

摘要： A method for producing a polyester polyol is disclosed. The method comprises reacting phthalic anhydride with a diol selected from the group consisting of ethylene glycol, propylene glycol, 1,3-propanediol, 2-meth-1,3-propanediol, neopentyl glycol, 1,6-hexanediol, polyethylene glycols having a number average molecular weight within the range of 200 g/mol to 600 g/mol, and mixtures thereof at a diol to phthalic anhydride molar ratio within the range of 1.1 to 1.6. The resulting o-phthalate polyester polyol has a hydroxyl value in the range of 18 to 400 mg KOH/g, an acid value in the range of 0.2 to 5.0 mg KOH/g, and 1 wt. % or less of cyclic esters.

摘要翻译： 公开了一种聚酯多元醇的制造方法。 该方法包括使邻苯二甲酸酐与选自乙二醇，丙二醇，1,3-丙二醇，2-甲基-1,3-丙二醇，新戊二醇，1,6-己二醇，具有 数均分子量在200g / mol至600g / mol的范围内，以及其在二醇与邻苯二甲酸酐摩尔比在1.1至1.6范围内的混合物。 得到的邻苯二甲酸酯聚酯多元醇的羟基值在18-400mg KOH / g的范围内，酸值在0.2-5.0mg KOH / g的范围内，和1wt。 ％以下的环状酯。