-
公开(公告)号:US20130296616A1
公开(公告)日:2013-11-07
申请号:US13713930
申请日:2012-12-13
IPC分类号: C07C51/44
摘要: The phase separation in the decanter of a process for producing acetic acid by carbonylating methanol in the presence of a catalyst under low water-high acid conditions is improved by forming a liquid mixture (D) which has a water content of at most 20% by weight, based on the weight of the liquid mixture, and a weight ratio of acetic acid to water of at least 1:1, and partitioning the liquid mixture by providing for an alkane(s) content of D of from 0.1 to 15% by weight, based on the weight of D, to obtain a light, aqueous phase and a heavy, organic phase.
摘要翻译: 通过在低水 - 高酸条件下在催化剂存在下羰基化甲醇制备乙酸的方法中的滗析器中的相分离通过形成水含量至多为20%的液体混合物(D)而得到改善, 重量,基于液体混合物的重量,并且乙酸与水的重量比至少为1:1,并且通过将D的烷烃含量提供为0.1至15%,将液体混合物分配为 重量,基于D的重量,以获得轻的,水相和重的有机相。
-
公开(公告)号:US5625109A
公开(公告)日:1997-04-29
申请号:US342560
申请日:1994-11-21
申请人: Vijai P. Gupta
发明人: Vijai P. Gupta
CPC分类号: C07C1/24
摘要: A tertiary butyl alcohol feed is continuously dehydrated in the liquid phase, in a boiling reactor, a vapor mixture of isobutylene, water, tertiary butyl alcohol and isobutanol and/or secondary butanol is removed and cooled, isobutylene is recovered and the remaining product mixture is phase separated into an upper organic-rich phase which is recycled to dehydration and a lower aqueous phase which is purged.
摘要翻译: 叔丁醇进料在液相中连续脱水,在沸腾的反应器中,除去异丁烯,水,叔丁醇和异丁醇和/或仲丁醇的蒸气混合物,并冷却,回收异丁烯,剩余的产物混合物为 相分离成上部富含有机相,再循环至脱水和被清除的较低水相。
-
公开(公告)号:US3301530A
公开(公告)日:1967-01-31
申请号:US47681665
申请日:1965-08-03
申请人: GEN MOTORS CORP
发明人: LULL WILLIAM R
IPC分类号: C23C28/02
CPC分类号: C23C28/023 , C23C28/02 , Y10S416/50
-
公开(公告)号:US2361035A
公开(公告)日:1944-10-24
申请号:US45319442
申请日:1942-08-01
申请人: LUMMUS CO
发明人: KLAASSEN WILLEM J
IPC分类号: C10G73/06
CPC分类号: C10G73/06
-
公开(公告)号:US3051844A
公开(公告)日:1962-08-28
申请号:US77082258
申请日:1958-10-30
申请人: RCA CORP
发明人: BEAM WALTER R , FRED STERZER
IPC分类号: H03K3/47
CPC分类号: H03K3/47
-
公开(公告)号:US3000961A
公开(公告)日:1961-09-19
申请号:US78065958
申请日:1958-12-16
申请人: KOPPERS CO INC
发明人: DOBRATZ ELMER H
IPC分类号: C07F5/02
CPC分类号: C07F5/027
-
公开(公告)号:US2117448A
公开(公告)日:1938-05-17
申请号:US57798631
申请日:1931-11-30
申请人: GEN MOTORS CORP
CPC分类号: F04B49/24 , F04B27/0663 , F04B35/04 , Y10T137/108 , Y10T137/1135 , Y10T137/7922 , Y10T137/7936
-
公开(公告)号:US08124798B2
公开(公告)日:2012-02-28
申请号:US12653678
申请日:2009-12-17
申请人: Roger A. Grey , Robert N. Cochran , Bi Le-Khac
发明人: Roger A. Grey , Robert N. Cochran , Bi Le-Khac
IPC分类号: C07D301/12 , C07D301/06 , B01J29/06
CPC分类号: C07D301/06 , B01J21/06 , B01J21/063 , B01J23/44 , B01J23/628 , B01J29/405 , B01J29/44 , B01J35/0006 , B01J35/0013 , B01J35/023 , B01J2229/42
摘要: A catalyst, useful for the direct epoxidation of olefins, is disclosed. The catalyst comprises palladium nanoparticles, support nanoparticles, and a titanium zeolite having a particle size of 2 microns or greater. The palladium nanoparticles are deposited on the support nanoparticles to form supported palladium nanoparticles, and the supported palladium nanoparticles are deposited on the titanium zeolite; or the supported palladium nanoparticles are deposited on a carrier having a particle size of 2 microns or greater. The invention also includes a process for producing an epoxide comprising reacting an olefin, hydrogen and oxygen in the presence of the catalyst. The catalysts are more active in epoxidation reactions, while demonstrating the same or better selectivity.
摘要翻译: 公开了一种可用于烯烃直接环氧化的催化剂。 催化剂包括钯纳米颗粒,载体纳米颗粒和粒径为2微米或更大的钛沸石。 将钯纳米颗粒沉积在载体纳米颗粒上以形成负载的钯纳米颗粒,并将负载的钯纳米颗粒沉积在钛沸石上; 或者将负载的钯纳米颗粒沉积在粒径为2微米或更大的载体上。 本发明还包括一种生产环氧化物的方法,包括在催化剂存在下使烯烃,氢和氧反应。 催化剂在环氧化反应中更有活性,同时表现出相同或更好的选择性。
-
公开(公告)号:US08124797B2
公开(公告)日:2012-02-28
申请号:US12459065
申请日:2009-06-26
IPC分类号: C07D301/12 , C07D301/06
CPC分类号: C07D301/12 , C07D301/32
摘要: This invention is a process for producing propylene oxide. The process comprises first contacting a titanium zeolite with a reaction feed comprising propylene, hydrogen peroxide, tertiary butyl alcohol, and water to produce a product stream comprising propylene, propylene oxide, propylene glycol, tertiary butyl alcohol, and water. The product stream is distilled to produce a first overhead stream comprising propylene and a first bottoms stream comprising propylene oxide, propylene glycol, tertiary butyl alcohol, and water. The first bottoms stream is distilled to produce a second overhead stream comprising propylene oxide and a second bottoms product stream comprising propylene glycol, tertiary butyl alcohol, and water. The second bottoms stream is distilled to produce a third overhead stream comprising an azeotrope of tertiary butyl alcohol and water and a third bottoms stream comprising propylene glycol and water.
摘要翻译: 本发明是一种生产环氧丙烷的方法。 该方法包括首先使钛沸石与包含丙烯,过氧化氢,叔丁醇和水的反应进料接触,以产生包含丙烯,环氧丙烷,丙二醇,叔丁醇和水的产物流。 将产物流蒸馏以产生包含丙烯的第一塔顶物流和包含环氧丙烷,丙二醇,叔丁醇和水的第一塔底物流。 将第一塔底物流蒸馏以产生包含环氧丙烷的第二塔顶物流和包含丙二醇,叔丁醇和水的第二塔底物产物流。 蒸馏第二塔底物流以产生包含叔丁醇和水的共沸物的第三塔顶物流和包含丙二醇和水的第三塔底物流。
-
公开(公告)号:US5939569A
公开(公告)日:1999-08-17
申请号:US37399
申请日:1998-03-10
申请人: C. Andrew Jones , Roger A. Grey
发明人: C. Andrew Jones , Roger A. Grey
IPC分类号: C07B61/00 , C07D301/04 , C07D301/06 , C07D301/10 , C07D303/00
CPC分类号: C07D301/10 , C07D301/04 , C07D301/06
摘要: A process for converting an olefin such as propylene to the corresponding epoxide is described wherein the olefin, hydrogen and oxygen are contacted with a catalyst comprised of gold on a zirconium-containing support such as zirconia.
摘要翻译: 描述了将烯烃如丙烯转化成相应的环氧化物的方法,其中烯烃,氢和氧与含锆载体如氧化锆上的由金组成的催化剂接触。
-
-
-
-
-
-
-
-
-