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    Production of hydrogen peroxide
    3.
    发明授权
    Production of hydrogen peroxide 失效
    生产过氧化氢

    公开(公告)号：US5785943A

    公开(公告)日：1998-07-28

    申请号：US323423

    申请日：1994-10-14

    Applicant: James E. Guillet ,  Gad Friedman

    Inventor： James E. Guillet ,  Gad Friedman

    IPC: C01B15/023 ,  C01B15/026 ,  C07C45/36 ,  C07C45/39 ,  B05D7/24 ,  B32B17/02 ,  B32B18/00

    CPC classification number: C07C45/36 ,  C01B15/023 ,  C01B15/026 ,  C07C45/39 ,  Y10T428/2991 ,  Y10T428/2995 ,  Y10T428/2996

    Abstract: Hydrogen peroxide is produced by a process which uses solid, insoluble, supported anthraquinone as catalyst. The supported anthraquinone is converted to supported anthrahydroquinone utilizing soluble reducing agentsor by hydrogenation with a hydrogen-donating organic substrate such as an alcohol, followed by reaction with oxygen, to regenerate anthraquinone and to form hydrogen peroxide, which can be solvent extracted from the solid catalyst.

    Abstract translation: 过氧化氢通过使用固体，不溶性，负载的蒽醌作为催化剂的方法制备。 使用可溶性还原剂将支持的蒽醌转化为负载的蒽醌，或者通过用含氢的有机底物如醇进行氢化，然后与氧反应，再生蒽醌和形成过氧化氢，其可以从固体催化剂中萃取 。

    Nanocatalyst anchored onto acid functionalized solid support and methods of making and using same
    6.
    发明授权
    Nanocatalyst anchored onto acid functionalized solid support and methods of making and using same 失效
    锚定在酸官能化固体支持物上的纳米催化剂及其制备和使用方法

    公开(公告)号：US07045481B1

    公开(公告)日：2006-05-16

    申请号：US11103824

    申请日：2005-04-12

    Applicant: Sukesh Parasher ,  Michael Rueter ,  Bing Zhou

    Inventor： Sukesh Parasher ,  Michael Rueter ,  Bing Zhou

    IPC: B01J31/00

    CPC classification number: B01J35/0013 ,  B01J23/38 ,  B01J27/053 ,  B01J27/08 ,  B01J29/06 ,  B01J31/1625 ,  B01J37/0219 ,  C01B15/026

    Abstract: Supported catalysts include a solid support such as silica that is functionalized to have inorganic acid functional groups attached thereto. Active catalyst particles are supported on the functionalized support material. The acid functionalized support material is made by reacting a solid support with an inorganic acid containing agent such as sulfuric acid or para-toluene sulfonic acid. An organic anchoring agent is used to form and anchor catalyst nanoparticles to the acid functionalized support material. The supported catalyst can be sized and shaped for use in any type of reactor, including a fixed bed or fluidized bed reactor. The methods of the present invention also include a process for the direct synthesis of hydrogen peroxide using the supported catalyst.

    Abstract translation: 负载型催化剂包括固体载体如二氧化硅，其被官能化以具有连接到其上的无机酸官能团。 活性催化剂颗粒负载在官能化的载体材料上。 酸官能化的载体材料通过使固体载体与无机酸的试剂如硫酸或对甲苯磺酸反应制得。 使用有机锚固剂将催化剂纳米颗粒形成和锚定到酸官能化载体材料上。 负载催化剂的尺寸和形状可用于任何类型的反应器，包括固定床或流化床反应器。 本发明的方法还包括使用负载型催化剂直接合成过氧化氢的方法。

    Production of hydrogen peroxide
    7.
    发明授权
    Production of hydrogen peroxide 失效
    生产过氧化氢

    公开(公告)号：US5374339A

    公开(公告)日：1994-12-20

    申请号：US136020

    申请日：1993-10-14

    Applicant: James E. Guillet ,  Gad Friedman

    Inventor： James E. Guillet ,  Gad Friedman

    IPC: C01B15/023 ,  C01B15/026 ,  C07C45/36 ,  C07C45/39 ,  C01B15/024

    CPC classification number: C07C45/36 ,  C01B15/023 ,  C01B15/026 ,  C07C45/39 ,  Y10T428/2991 ,  Y10T428/2995 ,  Y10T428/2996

    Abstract: Hydrogen peroxide is produced by a process which uses solid, insoluble, supported anthraquinone as catalyst. The catalyst is reduced to supported anthrahydroquinone using a hydrogen-donating organic substrate such as an alcohol, followed by reaction with oxygen, suitably photochemical reaction, to regenerate anthraquinone and to form hydrogen peroxide, which can be solvent extracted from the solid catalyst.

    Abstract translation: 过氧化氢通过使用固体，不溶性，负载的蒽醌作为催化剂的方法制备。 使用供氢的有机底物如醇将催化剂还原成支持的蒽醌，随后与氧反应，适当地光化学反应，再生蒽醌和形成过氧化氢，其可以从固体催化剂中萃取。

    Production of hydrogen peroxide
    8.
    发明授权
    Production of hydrogen peroxide 失效
    生产过氧化氢

    公开(公告)号：US5039508A

    公开(公告)日：1991-08-13

    申请号：US554770

    申请日：1990-07-19

    Applicant: Robert N. Cochran ,  Lawrence M. Candela

    Inventor： Robert N. Cochran ,  Lawrence M. Candela

    IPC: C01B15/013 ,  C01B15/026 ,  C07C45/39

    CPC classification number: C01B15/026 ,  C01B15/013 ,  C07C45/39

    Abstract: Hydrogen peroxide is produced by liquid phase molecular oxygen oxidation of methyl benzyl alcohol, the reaction being carried out such that the oxygen absorption rate is 90% or more of the maximum at the reaction conditions and the exit gas oxygen partial pressure is not greater than 3.0, the minimum necessary to establish the maximum oxygen absorption rate.

    Abstract translation: 过氧化氢是通过甲基苄醇的液相分子氧氧化制备的，反应进行为使得氧气吸收速率在反应条件下为最大值的90％以上，出口气体氧分压不大于3.0 ，建立最大氧吸收速率所需的最小值。

    Preparation of hydrogen peroxide
    9.
    发明授权
    Preparation of hydrogen peroxide 失效
    过氧化氢的制备

    公开(公告)号：US4303632A

    公开(公告)日：1981-12-01

    申请号：US103061

    申请日：1979-12-14

    Applicant: Lawrence W. Gosser

    Inventor： Lawrence W. Gosser

    IPC: C01B15/026 ,  C07C45/39 ,  C07C49/784 ,  C07C49/788 ,  C01B15/02

    CPC classification number: C07C49/784 ,  C01B15/026 ,  C07C45/39 ,  C07C49/788

    Abstract: Process comprising contacting and reacting a diarylmethanol having 13 to 25 carbon atoms and of the formula RCHOHR' wherein each of R and R' is aryl, the same or different, in the liquid state, at a temperature of about 130.degree.-260.degree. C., with gaseous oxygen to produce hydrogen peroxide and diaryl ketone of the formula RCOR' wherein R and R' are the same as above.

    Abstract translation: 方法包括使具有13至25个碳原子和式RCHOHR'的二芳基甲醇接触和反应，其中R和R'各自为液态的相同或不同的，在约130-260℃的温度 用气态氧产生过氧化氢和式RCOR'的二芳基酮，其中R和R'与上述相同。

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