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公开(公告)号：US09815044B2
公开(公告)日：2017-11-14
申请号：US15010391
申请日：2016-01-29
IPC分类号： B01J37/02 , B01J23/02 , B01J23/04 , B01J23/10 , B01J23/70 , B01J23/78 , B01J23/83 , B01D53/94 , B01J35/10
CPC分类号： B01J23/83 , B01D53/9413 , B01D53/945 , B01D2251/202 , B01D2255/202 , B01D2255/2022 , B01D2255/2025 , B01D2255/2027 , B01D2255/2065 , B01D2255/20715 , B01D2255/20738 , B01D2255/20746 , B01D2255/20761 , B01D2255/705 , B01J23/10 , B01J23/70 , B01J23/78 , B01J35/1019 , B01J37/0201 , B01J37/0203 , B01J37/0205 , B01J37/0219 , B01J37/024 , Y02A50/2324 , Y02T10/22
摘要： A composition and method for producing the same are provided. The composition includes transition metal oxides adhered to a surface of a cerium oxide support, and can additionally include alkali metal or alkaline earth metal promotors. The method includes incipient wetness impregnation of the support with metal salt in solution, and can include impregnation with a metal chelator salt. The composition can be useful as a catalyst for the reduction of noxious gases in combustion exhaust streams. The composition can be of particular use as a component of an automobile catalytic converter, for the specific catalytic reduction of nitrogen oxides to nitrogen gas.
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公开(公告)号：US20220251283A1
公开(公告)日：2022-08-11
申请号：US17433045
申请日：2020-02-14
发明人： Mihir Bhagat , Charmaine Bennett , Youlong Zhu , SonBinh T. Nguyen , Linda Broadbelt , Justin M. Notestein , Matthew E. Belowich , Arjun Raghuraman , William H. Heath , Sukrit Mukhopadhyay , Heather A. Spinney , David R. Wilson
摘要： A method of producing a polyether alcohol that includes feeding an initiator into a reactor, feeding one or more monomers into the reactor, feeding a polymerization catalyst into the reactor, the polymerization catalyst being a Lewis acid catalyst having a general formula M(R1)1(R2)1(R3)1(R4)0 or 1, separate from feeding the initiator into the reactor, feeding a hydrogen bond acceptor additive into the reactor, the hydrogen bond acceptor additive being a C2 to C20 organic molecule having at least two hydroxyl groups, of which two hydroxyl groups are situated in 1,2-, 1,3-, or 1,4- positions on the organic molecule, and allowing the initiator to react with the one or more monomers in the presence of the polymerization catalyst and the hydrogen bond acceptor additive to form a polyether alcohol having a number average molecular weight greater than a number average molecular weight of the initiator.
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公开(公告)号：US20210070920A1
公开(公告)日：2021-03-11
申请号：US16644310
申请日：2018-09-14
发明人： Arjun Raghuraman , William H. Heath , Sukrit Mukhopadhyay , Heather A. Spinney , David R. Wilson , Justin M. Notestein , SonBinh T. Nguyen
摘要： A method of producing a polyether polyol that includes reacting a low molecular weight initiator with ethylene oxide in the presence of a polymerization catalyst, the low molecular weight initiator having a number average molecular weight of less than 1,000 g/mol and a nominal hydroxyl functionality at least 2, and the polymerization catalyst being a Lewis acid catalyst having the general formula M(R1)1(R2)1(R3)1(R4)0 or 1. Whereas, M is boron, aluminum, indium, bismuth or erbium, R1, R2, and R3 each includes a same fluoroalkyl-substituted phenyl group, and optional R4 includes a functional group or functional polymer group. R1, R2, and R3 are the same fluoroalkyl-substituted phenyl group. The method further includes forming a polyether polyol having a number average molecular weight of greater than the number average molecular weight of the low molecular weight initiator in the presence of the Lewis acid catalyst.
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公开(公告)号：US10508032B2
公开(公告)日：2019-12-17
申请号：US15073892
申请日：2016-03-18
IPC分类号： B01J21/08 , C01B15/026 , C07D301/12 , C07C29/145 , B01J37/06 , B01J37/08 , B01J37/34 , B01J35/00 , B01J23/06 , B01J23/14 , B01J23/20 , B01J23/22 , B01J23/26 , B01J23/28 , B01J23/30 , B01J23/34 , B01J23/36 , B01J23/46 , B01J23/72 , B01J23/75 , B01J27/22 , B01J35/10 , B01J37/02
摘要： Catalysts, catalytic systems and related synthetic methods for in situ production of H2O2 and use thereof in reaction with oxidizable substrates.
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公开(公告)号：US11479642B2
公开(公告)日：2022-10-25
申请号：US16644284
申请日：2018-09-14
发明人： Arjun Raghuraman , William H. Heath , Sukrit Mukhopadhyay , Heather A. Spinney , David R. Wilson , Anthony P. Gies , Manjiri R. Paradkar , Justin M. Notestein , SonBinh T. Nguyen
摘要： A method of producing a polyether polyol that includes reacting a low molecular weight initiator with one or more monomers in the presence of a polymerization catalyst, the low molecular weight initiator having a number average molecular weight of less than 1,000 g/mol and a nominal hydroxyl functionality at least 2, the one or more monomers including at least one selected from propylene oxide and butylene oxide, and the polymerization catalyst being a Lewis acid catalyst having the general formula M(R1)1(R2)1(R3)1(R4)0 or 1. Whereas, M is boron, aluminum, indium, bismuth or erbium, R1, R2, and R3 each includes a same fluoroalkyl-substituted phenyl group, and optional R4 includes a functional group or functional polymer group. The method further includes forming a polyether polyol having a number average molecular weight of greater than the number average molecular weight of the low molecular weight initiator in the presence of the Lewis acid catalyst.
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公开(公告)号：US11186683B2
公开(公告)日：2021-11-30
申请号：US16645982
申请日：2018-09-14
发明人： Arjun Raghuraman , William H. Heath , Bruce D. Hook , Wanglin Yu , Sukrit Mukhopadhyay , Heather A. Spinney , David R. Wilson , Justin M. Notestein , SonBinh T. Nguyen
摘要： A method of producing an alcohol ethoxylate surfactant or lubricant includes reacting a low molecular weight initiator with ethylene oxide in the presence of a polymerization catalyst, the low molecular weight initiator having a nominal hydroxyl functionality at least 1, and the polymerization catalyst being a Lewis acid catalyst having the general formula M(R1)1(R2)1(R3)1(R4)0 or 1, whereas M is boron, aluminum, indium, bismuth or erbium, R1, R2 and R3 each includes a same fluoroalkyl-substituted phenyl group, and optional R4 includes a functional group or functional polymer group. R1, R2, and R3 are the same fluoroalkyl-substituted phenyl group. The method further includes forming the alcohol ethoxylate surfactant or lubricant having a number average molecular weight of greater than the number average molecular weight of the low molecular weight initiator in the presence of the Lewis acid catalyst.
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7.发明申请Catalysts and Related Methods for Photocatalytic Production of H2O2 and Thermocatalytic Reactant Oxidation 审中-公开用于光催化生产H2O2和热催化反应物氧化的催化剂和相关方法公开(公告)号：US20160272495A1
公开(公告)日：2016-09-22
申请号：US15073892
申请日：2016-03-18
IPC分类号： C01B15/026 , C07C29/145 , B01J35/02 , B01J21/08 , B01J23/20 , C07D301/12 , B01J35/00
CPC分类号： C01B15/026 , B01J21/08 , B01J23/06 , B01J23/14 , B01J23/20 , B01J23/22 , B01J23/26 , B01J23/28 , B01J23/30 , B01J23/34 , B01J23/36 , B01J23/466 , B01J23/468 , B01J23/72 , B01J23/75 , B01J27/22 , B01J35/0006 , B01J35/002 , B01J35/004 , B01J35/008 , B01J35/0086 , B01J35/1057 , B01J37/0209 , B01J37/06 , B01J37/08 , B01J37/34 , C07C29/145 , C07D301/12
摘要： Catalysts, catalytic systems and related synthetic methods for in situ production of H2O2 and use thereof in reaction with oxidizable substrates.
摘要翻译： 用于H 2 O 2原位生产的催化剂，催化体系和相关合成方法及其与可氧化底物的反应。
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公开(公告)号：US10807868B2
公开(公告)日：2020-10-20
申请号：US16680675
申请日：2019-11-12
IPC分类号： C07D301/12 , C01B15/026 , C07C29/145 , B01J21/08 , B01J35/00 , B01J23/14 , B01J23/46 , B01J37/02 , B01J37/06 , B01J23/26 , B01J23/06 , B01J23/28 , B01J27/22 , B01J37/08 , B01J23/36 , B01J23/30 , B01J23/75 , B01J23/22 , B01J23/34 , B01J37/34 , B01J35/10 , B01J23/72 , B01J23/20
摘要： Catalysts, catalytic systems and related synthetic methods for in situ production of H2O2 and use thereof in reaction with oxidizable substrates.
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公开(公告)号：US20200231738A1
公开(公告)日：2020-07-23
申请号：US16644284
申请日：2018-09-14
发明人： Arjun Raghuraman , William H. Heath , Sukrit Mukhopadhyay , Heather A. Spinney , David R. Wilson , Anthony P. Gies , Manjiri R. Paradkar , Justin M. Notestein , SonBinh T. Nguyen
摘要： A method of producing a polyether polyol that includes reacting a low molecular weight initiator with one or more monomers in the presence of a polymerization catalyst, the low molecular weight initiator having a number average molecular weight of less than 1,000 g/mol and a nominal hydroxyl functionality at least 2, the one or more monomers including at least one selected from propylene oxide and butylene oxide, and the polymerization catalyst being a Lewis acid catalyst having the general formula M(R1)1(R2)1(R3)1(R4)0 or 1. Whereas, M is boron, aluminum, indium, bismuth or erbium, R1, R2, and R3 each includes a same fluoroalkyl-substituted phenyl group, and optional R4 includes a functional group or functional polymer group. The method further includes forming a polyether polyol having a number average molecular weight of greater than the number average molecular weight of the low molecular weight initiator in the presence of the Lewis acid catalyst.
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10.发明申请公开(公告)号：US20200095126A1
公开(公告)日：2020-03-26
申请号：US16680675
申请日：2019-11-12
IPC分类号： C01B15/026 , C07D301/12 , C07C29/145 , B01J21/08 , B01J35/00 , B01J23/14 , B01J23/46 , B01J37/02 , B01J37/06 , B01J23/26 , B01J23/06 , B01J23/28 , B01J27/22 , B01J37/08 , B01J23/36 , B01J23/30 , B01J23/75 , B01J23/22 , B01J23/34 , B01J37/34 , B01J35/10 , B01J23/72 , B01J23/20
摘要： Catalysts, catalytic systems and related synthetic methods for in situ production of H2O2 and use thereof in reaction with oxidizable substrates.
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