公开(公告)号：US20010031845A1

公开(公告)日：2001-10-18

申请号：US09824072

申请日：2001-04-02

Inventor： Steven D. Ittel ,  Edward B. Coughlin ,  Ying Wang

IPC: C08F004/64

CPC classification number: C08F10/00 ,  C07F7/003 ,  C08F110/02 ,  C08F110/06 ,  C08F110/14 ,  C08F210/16 ,  C08F232/00 ,  C08F2410/04 ,  C08F4/69465 ,  C08F4/64186 ,  C08F4/68465 ,  C08F4/54 ,  C08F2500/20 ,  C08F2500/10 ,  C08F2500/12 ,  C08F2500/05 ,  C08F2500/04 ,  C08F210/14 ,  C08F2500/01 ,  C08F4/7042

Abstract: Olefins such as ethylene and propylene may be polymerized by using as catalysts novel selected transition metal complexes of bis(carboximidamidatonates) in which the carboximidamidatonate groups are connected together through covalent bonds by a bridging group. The resulting polymers are useful as molding and extrusion resins.

公开(公告)号：US20020099155A1

公开(公告)日：2002-07-25

申请号：US09897111

申请日：2001-07-03

Inventor： Yoshihisa Inoue ,  Shigekazu Matsui ,  Yasuhiko Suzuki ,  Yasunori Yoshida ,  Yukihiro Takagi ,  Terunori Fujita ,  Tomoaki Matsugi ,  Takashi Nakano

IPC: C08F004/06

CPC classification number: C08F210/02 ,  C08F4/619 ,  C08F4/639 ,  C08F4/659 ,  C08F10/00 ,  C08F4/54 ,  C08F4/64048 ,  C08F220/06 ,  C08F2500/20 ,  C08F2500/17 ,  C08F220/12 ,  C08F220/04 ,  C08F232/00 ,  C08F222/06 ,  C08F4/6812 ,  C08F4/6912 ,  C08F4/7022 ,  C08F4/64044 ,  C08F4/68112 ,  C08F4/69112 ,  C08F4/69474 ,  C08F4/68474 ,  C08F4/64189 ,  C08F4/64051 ,  C08F4/68129 ,  C08F4/69129 ,  C08F4/68293 ,  C08F4/64186 ,  C08F4/68465 ,  C08F4/69465 ,  C08F4/69103 ,  C08F4/68103

Abstract: A process for producing a polar olefin copolymer comprises copolymerizing a non-polar olefin and a polar olefin in the presence of a transition metal compound selected from Groups 4, 5, 6 and 11 of the periodic table, which is represented by the following formula (IV): 1 wherein Mnull is a transition metal atom selected from Groups 4, 5, 6 and 11 of the periodic table, m is an integer of 1 to 6, A is nullOnull, nullSinull, nullSenull, nullN(R6)null, n is a number satisfying a valence of Mnull, R1 to R4 and R6 are each a hydrogen atom, a halogen atom, a hydrocarbon group and the like, and X is a halogen atom, an oxygen atom, a hydrocarbon group and the like, and at least one compound (B) selected from the group consisting of an organometallic compound (B-1), an organoaluminum oxy-compound (B-2) and an ionic ionizing compound (B-3). Therefore, the process is capable of obtaining a polar olefin copolymer having excellent properties under mild polymerization conditions.

Abstract translation: 一种制备极性烯烃共聚物的方法，包括在选自元素周期表第4,5,6和11族的过渡金属化合物存在下使非极性烯烃和极性烯烃共聚合，其由下式（ IV）：其中M'是选自元素周期表第4,5,6和11族的过渡金属原子，m是1至6的整数，A是-O - ， - Si-，-Se-， - N（R6） - ，n为满足M'的化合价的数，R 1〜R 4，R 6为氢原子，卤素原子，烃基等，X为卤素原子，氧原子， 烃基等，以及选自有机金属化合物（B-1），有机铝氧化合物（B-2）和离子电离化合物（B-3）中的至少一种化合物（B） 。 因此，该方法能够获得在温和聚合条件下具有优异性能的极性烯烃共聚物。

公开(公告)号：US07053159B2

公开(公告)日：2006-05-30

申请号：US09897111

申请日：2001-07-03

Applicant: Yoshihisa Inoue ,  Shigekazu Matsui ,  Yasuhiko Suzuki ,  Yasunori Yoshida ,  Yukihiro Takagi ,  Terunori Fujita ,  Tomoaki Matsugi ,  Takashi Nakano

Inventor： Yoshihisa Inoue ,  Shigekazu Matsui ,  Yasuhiko Suzuki ,  Yasunori Yoshida ,  Yukihiro Takagi ,  Terunori Fujita ,  Tomoaki Matsugi ,  Takashi Nakano

IPC: C08F4/44 ,  C08F4/602 ,  C08F4/605 ,  C08F4/10

CPC classification number: C08F210/02 ,  C08F4/619 ,  C08F4/639 ,  C08F4/659 ,  C08F10/00 ,  C08F4/54 ,  C08F4/64048 ,  C08F220/06 ,  C08F2500/20 ,  C08F2500/17 ,  C08F220/12 ,  C08F220/04 ,  C08F232/00 ,  C08F222/06 ,  C08F4/6812 ,  C08F4/6912 ,  C08F4/7022 ,  C08F4/64044 ,  C08F4/68112 ,  C08F4/69112 ,  C08F4/69474 ,  C08F4/68474 ,  C08F4/64189 ,  C08F4/64051 ,  C08F4/68129 ,  C08F4/69129 ,  C08F4/68293 ,  C08F4/64186 ,  C08F4/68465 ,  C08F4/69465 ,  C08F4/69103 ,  C08F4/68103

Abstract: A process for producing a polar olefin copolymer comprises copolymerizing a non-polar olefin and a polar olefin in the presence of a transition metal compound selected from Groups 4, 5, 6 and 11 of the periodic table, which is represented by the following formula (IV): wherein M′ is a transition metal atom selected from Groups 4, 5, 6 and 11 of the periodic table, m is an integer of 1 to 6, A is —O—, —Si—, —Se—, —N(R6)—, n is a number satisfying a valence of M′, R1 to R4 and R6 are each a hydrogen atom, a halogen atom, a hydrocarbon group and the like, and X is a halogen atom, an oxygen atom, a hydrocarbon group and the like, and at least one compound (B) selected from the group consisting of an organometallic compound (B-1), an organoaluminum oxy-compound (B-2) and an ionic ionizing compound (B-3). Therefore, the process is capable of obtaining a polar olefin copolymer having excellent properties under mild polymerization conditions.

Abstract translation: 一种制备极性烯烃共聚物的方法，包括在选自元素周期表第4,5,6和11族的过渡金属化合物存在下使非极性烯烃和极性烯烃共聚合，其由下式（ IV）：其中M'是选自元素周期表第4,5,6和11族的过渡金属原子，m是1至6的整数，A是-O - ， - Si-，-Se-， - N（R 6） - ，n是满足M'，R 1至R 4和R 6的价数的数 各自为氢原子，卤素原子，烃基等，X为卤素原子，氧原子，烃基等，以及至少一种选自以下的化合物（B）： 由有机金属化合物（B-1），有机铝氧化合物（B-2）和离子电离化合物（B-3）组成的组。 因此，该方法能够获得在温和聚合条件下具有优异性能的极性烯烃共聚物。

公开(公告)号：US07312284B2

公开(公告)日：2007-12-25

申请号：US11253963

申请日：2005-10-20

Applicant: Yoshihisa Inoue ,  Shigekazu Matsui ,  Yasuhiko Suzuki ,  Yasunori Yoshida ,  Yukihiro Takagi ,  Terunori Fujita ,  Tomoaki Matsugi ,  Takashi Nakano

Inventor： Yoshihisa Inoue ,  Shigekazu Matsui ,  Yasuhiko Suzuki ,  Yasunori Yoshida ,  Yukihiro Takagi ,  Terunori Fujita ,  Tomoaki Matsugi ,  Takashi Nakano

IPC: C08F4/44 ,  C08F4/602 ,  C08F4/605 ,  C08F220/00

CPC classification number: C08F210/02 ,  C08F4/619 ,  C08F4/639 ,  C08F4/659 ,  C08F10/00 ,  C08F4/54 ,  C08F4/64048 ,  C08F220/06 ,  C08F2500/20 ,  C08F2500/17 ,  C08F220/12 ,  C08F220/04 ,  C08F232/00 ,  C08F222/06 ,  C08F4/6812 ,  C08F4/6912 ,  C08F4/7022 ,  C08F4/64044 ,  C08F4/68112 ,  C08F4/69112 ,  C08F4/69474 ,  C08F4/68474 ,  C08F4/64189 ,  C08F4/64051 ,  C08F4/68129 ,  C08F4/69129 ,  C08F4/68293 ,  C08F4/64186 ,  C08F4/68465 ,  C08F4/69465 ,  C08F4/69103 ,  C08F4/68103

Abstract: A process for producing a polar olefin copolymer comprises copolymerizing a non-polar olefin and a polar olefin in the presence of a transition metal compound selected from Groups 4, 5, 6 and 11 of the periodic table, which is represented by the following formula (IV): wherein M′ is a transition metal atom selected from Groups 4, 5, 6 and 11 of the periodic table, m is an integer of 1 to 6, A is —O—, —Si—, —Se—, —N(R6)—, n is a number satisfying a valence of M′, R1 to R4 and R6 are each a hydrogen atom, a halogen atom, a hydrocarbon group and the like, and X is a halogen atom, an oxygen atom, a hydrocarbon group and the like, and at least one compound (B) selected from the group consisting of an organometallic compound (B-1), an organoaluminum oxy-compound (B-2) and an ionic ionizing compound (B-3). Therefore, the process is capable of obtaining a polar olefin copolymer having excellent properties under mild polymerization conditions.

Abstract translation: 一种制备极性烯烃共聚物的方法，包括在选自元素周期表第4,5,6和11族的过渡金属化合物存在下使非极性烯烃和极性烯烃共聚合，其由下式（ IV）：其中M'是选自元素周期表第4,5,6和11族的过渡金属原子，m是1至6的整数，A是-O - ， - Si-，-Se-， - N（R 6） - ，n是满足M'，R 1至R 4和R 6的价数的数 各自为氢原子，卤素原子，烃基等，X为卤素原子，氧原子，烃基等，以及至少一种选自以下的化合物（B）： 由有机金属化合物（B-1），有机铝氧化合物（B-2）和离子电离化合物（B-3）组成的组。 因此，该方法能够获得在温和聚合条件下具有优异性能的极性烯烃共聚物。

公开(公告)号：US06255414B1

公开(公告)日：2001-07-03

申请号：US09383900

申请日：1999-08-26

Applicant: Steven Dale Ittel ,  Edward Bryan Coughlin ,  Ying Wang

Inventor： Steven Dale Ittel ,  Edward Bryan Coughlin ,  Ying Wang

IPC: C08F416

CPC classification number: C08F10/00 ,  C07F7/003 ,  C08F110/02 ,  C08F110/06 ,  C08F110/14 ,  C08F210/16 ,  C08F232/00 ,  C08F2410/04 ,  C08F4/69465 ,  C08F4/64186 ,  C08F4/68465 ,  C08F4/54 ,  C08F2500/20 ,  C08F2500/10 ,  C08F2500/12 ,  C08F2500/05 ,  C08F2500/04 ,  C08F210/14 ,  C08F2500/01 ,  C08F4/7042

Abstract: Olefins such as ethylene and propylene may be polymerized by using as catalysts novel selected transition metal complexes of bis(carboximidamidatonates) in which the carboximidamidatonate groups are connected together through covalent bonds by a bridging group. The resulting polymers are useful as molding and extrusion resins.

Abstract translation: 烯烃如乙烯和丙烯可以通过使用作为催化剂的新型选择的双（羧甲基脒基化合物）的过渡金属络合物来聚合，其中通过桥连基团通过共价键将甲脒基酰胺基团连接在一起。 所得聚合物可用作模制和挤出树脂。

公开(公告)号：US20060063898A1

公开(公告)日：2006-03-23

申请号：US11253963

申请日：2005-10-20

Applicant: Yoshihisa Inoue ,  Shigekazu Matsui ,  Yasuhiko Suzuki ,  Yasunori Yoshida ,  Yukihiro Takagi ,  Terunori Fujita ,  Tomoaki Matsugi ,  Takashi Nakano

Inventor： Yoshihisa Inoue ,  Shigekazu Matsui ,  Yasuhiko Suzuki ,  Yasunori Yoshida ,  Yukihiro Takagi ,  Terunori Fujita ,  Tomoaki Matsugi ,  Takashi Nakano

IPC: C08F4/44

CPC classification number: C08F210/02 ,  C08F4/619 ,  C08F4/639 ,  C08F4/659 ,  C08F10/00 ,  C08F4/54 ,  C08F4/64048 ,  C08F220/06 ,  C08F2500/20 ,  C08F2500/17 ,  C08F220/12 ,  C08F220/04 ,  C08F232/00 ,  C08F222/06 ,  C08F4/6812 ,  C08F4/6912 ,  C08F4/7022 ,  C08F4/64044 ,  C08F4/68112 ,  C08F4/69112 ,  C08F4/69474 ,  C08F4/68474 ,  C08F4/64189 ,  C08F4/64051 ,  C08F4/68129 ,  C08F4/69129 ,  C08F4/68293 ,  C08F4/64186 ,  C08F4/68465 ,  C08F4/69465 ,  C08F4/69103 ,  C08F4/68103

Abstract: A process for producing a polar olefin copolymer comprises copolymerizing a non-polar olefin and a polar olefin in the presence of a transition metal compound selected from Groups 4, 5, 6 and 11 of the periodic table, which is represented by the following formula (IV): wherein M′ is a transition metal atom selected from Groups 4, 5, 6 and 11 of the periodic table, m is an integer of 1 to 6, A is —O—, —Si—, —Se—, —N(R6)—, n is a number satisfying a valence of M′, R1 to R4 and R6 are each a hydrogen atom, a halogen atom, a hydrocarbon group and the like, and X is a halogen atom, an oxygen atom, a hydrocarbon group and the like, and at least one compound (B) selected from the group consisting of an organometallic compound (B-1), an organoaluminum oxy-compound (B-2) and an ionic ionizing compound (B-3). Therefore, the process is capable of obtaining a polar olefin copolymer having excellent properties under mild polymerization conditions.

Abstract translation: 一种制备极性烯烃共聚物的方法，包括在选自元素周期表第4,5,6和11族的过渡金属化合物存在下使非极性烯烃和极性烯烃共聚合，其由下式（ IV）：

公开(公告)号：US06506920B2

公开(公告)日：2003-01-14

申请号：US09824072

申请日：2001-04-02

Applicant: Steven Dale Ittel ,  Edward Bryan Coughlin ,  Ying Wang

Inventor： Steven Dale Ittel ,  Edward Bryan Coughlin ,  Ying Wang

IPC: C07F700

CPC classification number: C08F10/00 ,  C07F7/003 ,  C08F110/02 ,  C08F110/06 ,  C08F110/14 ,  C08F210/16 ,  C08F232/00 ,  C08F2410/04 ,  C08F4/69465 ,  C08F4/64186 ,  C08F4/68465 ,  C08F4/54 ,  C08F2500/20 ,  C08F2500/10 ,  C08F2500/12 ,  C08F2500/05 ,  C08F2500/04 ,  C08F210/14 ,  C08F2500/01 ,  C08F4/7042

Abstract: Olefins such as ethylene and propylene may be polymerized by using as catalysts novel selected transition metal complexes of bis(carboximidamidatonates) in which the carboximidamidatonate groups are connected together through covalent bonds by a bridging group. The resulting polymers are useful as molding and extrusion resins.

Abstract translation: 烯烃如乙烯和丙烯可以通过使用作为催化剂的新型选择的双（羧甲基脒基化合物）的过渡金属络合物来聚合，其中通过桥连基团通过共价键将甲脒基酰胺基团连接在一起。 所得聚合物可用作模制和挤出树脂。