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公开(公告)号：US20080293899A1
公开(公告)日：2008-11-27
申请号：US12188587
申请日：2008-08-08
申请人： David H. McConville , Lily Ackerman , Robert T. Li , Xiahong Bei , Matthew C. Kuchta , Tom Boussie , John F. Walzer, JR. , Gary Diamond , Francis C. Rix , Keith A. Hall , Anne LaPointe , James Longmire , Vince Murphy , Pu Sun , Dawn Verdugo , Susan Schofer , Eric Dias
发明人： David H. McConville , Lily Ackerman , Robert T. Li , Xiahong Bei , Matthew C. Kuchta , Tom Boussie , John F. Walzer, JR. , Gary Diamond , Francis C. Rix , Keith A. Hall , Anne LaPointe , James Longmire , Vince Murphy , Pu Sun , Dawn Verdugo , Susan Schofer , Eric Dias
IPC分类号： C08F2/00
CPC分类号： C07C2/32 , C07C2531/22 , C08F10/00 , C08F110/02 , C08F2500/02 , C08F4/69103 , C08F4/69146 , C08F4/69275 , C07C11/02 , C07C11/107
摘要： The present invention provides a method of producing oligomers of olefins, comprising reacting olefins with a catalyst under oligomerization conditions. The catalyst can be the product of the combination of a chromium compound and a pyridyl amine or a heteroaryl-amine compound. In particular embodiments, the catalyst compound can be used to trimerize or tetramerize ethylene to 1-hexene, 1-octene, or mixtures of 1-hexene and 1-octene.
摘要翻译： 本发明提供一种生产烯烃低聚物的方法，包括在低聚条件下使烯烃与催化剂反应。 催化剂可以是铬化合物和吡啶基胺或杂芳基 - 胺化合物的组合的产物。 在具体实施方案中，催化剂化合物可用于将乙烯三聚或四聚为1-己烯，1-辛烯或1-己烯和1-辛烯的混合物。
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2.发明授权Process for producing polar olefin copolymer and polar olefin copolymer obtained thereby 有权制备极性烯烃共聚物和极性烯烃共聚物的方法公开(公告)号：US07312284B2
公开(公告)日：2007-12-25
申请号：US11253963
申请日：2005-10-20
申请人： Yoshihisa Inoue , Shigekazu Matsui , Yasuhiko Suzuki , Yasunori Yoshida , Yukihiro Takagi , Terunori Fujita , Tomoaki Matsugi , Takashi Nakano
发明人： Yoshihisa Inoue , Shigekazu Matsui , Yasuhiko Suzuki , Yasunori Yoshida , Yukihiro Takagi , Terunori Fujita , Tomoaki Matsugi , Takashi Nakano
IPC分类号： C08F4/44 , C08F4/602 , C08F4/605 , C08F220/00
CPC分类号： C08F210/02 , C08F4/619 , C08F4/639 , C08F4/659 , C08F10/00 , C08F4/54 , C08F4/64048 , C08F220/06 , C08F2500/20 , C08F2500/17 , C08F220/12 , C08F220/04 , C08F232/00 , C08F222/06 , C08F4/6812 , C08F4/6912 , C08F4/7022 , C08F4/64044 , C08F4/68112 , C08F4/69112 , C08F4/69474 , C08F4/68474 , C08F4/64189 , C08F4/64051 , C08F4/68129 , C08F4/69129 , C08F4/68293 , C08F4/64186 , C08F4/68465 , C08F4/69465 , C08F4/69103 , C08F4/68103
摘要： A process for producing a polar olefin copolymer comprises copolymerizing a non-polar olefin and a polar olefin in the presence of a transition metal compound selected from Groups 4, 5, 6 and 11 of the periodic table, which is represented by the following formula (IV): wherein M′ is a transition metal atom selected from Groups 4, 5, 6 and 11 of the periodic table, m is an integer of 1 to 6, A is —O—, —Si—, —Se—, —N(R6)—, n is a number satisfying a valence of M′, R1 to R4 and R6 are each a hydrogen atom, a halogen atom, a hydrocarbon group and the like, and X is a halogen atom, an oxygen atom, a hydrocarbon group and the like, and at least one compound (B) selected from the group consisting of an organometallic compound (B-1), an organoaluminum oxy-compound (B-2) and an ionic ionizing compound (B-3). Therefore, the process is capable of obtaining a polar olefin copolymer having excellent properties under mild polymerization conditions.
摘要翻译： 一种制备极性烯烃共聚物的方法，包括在选自元素周期表第4,5,6和11族的过渡金属化合物存在下使非极性烯烃和极性烯烃共聚合，其由下式（ IV）：其中M'是选自元素周期表第4,5,6和11族的过渡金属原子，m是1至6的整数，A是-O - ， - Si-，-Se-， - N（R 6） - ，n是满足M'，R 1至R 4和R 6的价数的数 各自为氢原子，卤素原子，烃基等，X为卤素原子，氧原子，烃基等，以及至少一种选自以下的化合物（B）： 由有机金属化合物（B-1），有机铝氧化合物（B-2）和离子电离化合物（B-3）组成的组。 因此，该方法能够获得在温和聚合条件下具有优异性能的极性烯烃共聚物。
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3.发明授权Polymerization catalyst ligands, catalytic metal complexes and compositions and processes using and method of making same 失效聚合催化剂配体，催化金属络合物及其组合物和方法及其制备方法公开(公告)号：US06362309B1
公开(公告)日：2002-03-26
申请号：US09540480
申请日：2000-03-31
IPC分类号： C08G7500
CPC分类号： C07D333/20 , B01J2219/00283 , B01J2219/00315 , B01J2219/00477 , B01J2219/00495 , B01J2219/00585 , B01J2219/00599 , B01J2219/00601 , B01J2219/00736 , B01J2219/00738 , C07F9/5004 , C07F9/5022 , C07F11/005 , C07F15/0066 , C07F15/025 , C07F15/045 , C08F4/619 , C08F10/00 , C08F10/02 , C08F4/025 , C08F4/6002 , C08F4/69051 , C08F4/69103 , C08F4/7019 , C08F4/7018
摘要： New compositions, metal-ligand complexes and arrays are disclosed that catalyze the polymerization of monomers into polymers.
摘要翻译： 公开了新的组合物，金属 - 配体络合物和阵列，其催化单体聚合成聚合物。
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公开(公告)号：US07638670B2
公开(公告)日：2009-12-29
申请号：US12188587
申请日：2008-08-08
申请人： David H. McConville , Lily Ackerman , Robert T. Li , Xiaohong Bei , Matthew C. Kuchta , Tom Boussie , John F. Walzer, Jr. , Gary Diamond , Francis C. Rix , Keith A. Hall , Anne LaPointe , James Longmire , Vince Murphy , Pu Sun , Dawn Verdugo , Susan Schofer , Eric Dias
发明人： David H. McConville , Lily Ackerman , Robert T. Li , Xiaohong Bei , Matthew C. Kuchta , Tom Boussie , John F. Walzer, Jr. , Gary Diamond , Francis C. Rix , Keith A. Hall , Anne LaPointe , James Longmire , Vince Murphy , Pu Sun , Dawn Verdugo , Susan Schofer , Eric Dias
CPC分类号： C07C2/32 , C07C2531/22 , C08F10/00 , C08F110/02 , C08F2500/02 , C08F4/69103 , C08F4/69146 , C08F4/69275 , C07C11/02 , C07C11/107
摘要： The present invention provides a method of producing oligomers of olefins, comprising reacting olefins with a catalyst under oligomerization conditions. The catalyst can be the product of the combination of a chromium compound and a pyridyl amine or a heteroaryl-amine compound. In particular embodiments, the catalyst compound can be used to trimerize or tetramerize ethylene to 1-hexene, 1-octene, or mixtures of 1-hexene and 1-octene.
摘要翻译： 本发明提供一种生产烯烃低聚物的方法，包括在低聚条件下使烯烃与催化剂反应。 催化剂可以是铬化合物和吡啶基胺或杂芳基 - 胺化合物的组合的产物。 在具体实施方案中，催化剂化合物可用于将乙烯三聚或四聚为1-己烯，1-辛烯或1-己烯和1-辛烯的混合物。
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5.发明授权Process for producing polar olefin copolymer and polar olefin copolymer obtained thereby 有权制备极性烯烃共聚物和极性烯烃共聚物的方法公开(公告)号：US07053159B2
公开(公告)日：2006-05-30
申请号：US09897111
申请日：2001-07-03
申请人： Yoshihisa Inoue , Shigekazu Matsui , Yasuhiko Suzuki , Yasunori Yoshida , Yukihiro Takagi , Terunori Fujita , Tomoaki Matsugi , Takashi Nakano
发明人： Yoshihisa Inoue , Shigekazu Matsui , Yasuhiko Suzuki , Yasunori Yoshida , Yukihiro Takagi , Terunori Fujita , Tomoaki Matsugi , Takashi Nakano
CPC分类号： C08F210/02 , C08F4/619 , C08F4/639 , C08F4/659 , C08F10/00 , C08F4/54 , C08F4/64048 , C08F220/06 , C08F2500/20 , C08F2500/17 , C08F220/12 , C08F220/04 , C08F232/00 , C08F222/06 , C08F4/6812 , C08F4/6912 , C08F4/7022 , C08F4/64044 , C08F4/68112 , C08F4/69112 , C08F4/69474 , C08F4/68474 , C08F4/64189 , C08F4/64051 , C08F4/68129 , C08F4/69129 , C08F4/68293 , C08F4/64186 , C08F4/68465 , C08F4/69465 , C08F4/69103 , C08F4/68103
摘要： A process for producing a polar olefin copolymer comprises copolymerizing a non-polar olefin and a polar olefin in the presence of a transition metal compound selected from Groups 4, 5, 6 and 11 of the periodic table, which is represented by the following formula (IV): wherein M′ is a transition metal atom selected from Groups 4, 5, 6 and 11 of the periodic table, m is an integer of 1 to 6, A is —O—, —Si—, —Se—, —N(R6)—, n is a number satisfying a valence of M′, R1 to R4 and R6 are each a hydrogen atom, a halogen atom, a hydrocarbon group and the like, and X is a halogen atom, an oxygen atom, a hydrocarbon group and the like, and at least one compound (B) selected from the group consisting of an organometallic compound (B-1), an organoaluminum oxy-compound (B-2) and an ionic ionizing compound (B-3). Therefore, the process is capable of obtaining a polar olefin copolymer having excellent properties under mild polymerization conditions.
摘要翻译： 一种制备极性烯烃共聚物的方法，包括在选自元素周期表第4,5,6和11族的过渡金属化合物存在下使非极性烯烃和极性烯烃共聚合，其由下式（ IV）：其中M'是选自元素周期表第4,5,6和11族的过渡金属原子，m是1至6的整数，A是-O - ， - Si-，-Se-， - N（R 6） - ，n是满足M'，R 1至R 4和R 6的价数的数 各自为氢原子，卤素原子，烃基等，X为卤素原子，氧原子，烃基等，以及至少一种选自以下的化合物（B）： 由有机金属化合物（B-1），有机铝氧化合物（B-2）和离子电离化合物（B-3）组成的组。 因此，该方法能够获得在温和聚合条件下具有优异性能的极性烯烃共聚物。
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6.发明申请Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers 有权催化组合物及其制备和用于从烯属不饱和单体制备聚合物的用途公开(公告)号：US20050277749A1
公开(公告)日：2005-12-15
申请号：US11140287
申请日：2005-05-27
申请人： Brian Goodall , Jennifer Petoff , Han Shen
发明人： Brian Goodall , Jennifer Petoff , Han Shen
IPC分类号： B01J31/00 , B01J31/14 , B01J31/16 , B01J31/18 , B01J31/22 , B01J31/24 , C08F4/06 , C08F10/00 , C08F10/02 , C08F12/08 , C08F20/14 , C08F210/02 , C08F210/14
CPC分类号： B01J31/16 , B01J31/146 , B01J31/1805 , B01J31/182 , B01J31/183 , B01J31/2208 , B01J31/2243 , B01J31/2291 , B01J31/2404 , B01J2231/005 , B01J2231/12 , B01J2531/001 , B01J2531/0241 , B01J2531/0252 , B01J2531/0291 , B01J2531/16 , B01J2531/62 , B01J2531/72 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C08F4/639 , C08F4/7052 , C08F10/00 , C08F12/08 , C08F112/08 , C08F210/02 , C08F210/14 , C08F2410/03 , C08F4/695 , C08F220/14 , C08F2500/03 , C08F232/00 , C08F2500/25 , C08F212/08 , C08F4/60048 , C08F4/7006 , C08F4/7016 , C08F4/69103 , C08F4/60189 , C08F4/69112
摘要： A catalytic composition, including a cationic metal-pair complex, is disclosed, along with a method for its preparation. A method for the polymerization of ethylenically unsaturated monomers using the catalytic composition, and the addition polymers produced thereby are also disclosed.
摘要翻译： 公开了包括阳离子金属对络合物的催化组合物及其制备方法。 还公开了使用催化组合物聚合烯键式不饱和单体的方法和由其制备的加成聚合物。
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公开(公告)号：US20080269443A1
公开(公告)日：2008-10-30
申请号：US12215626
申请日：2008-06-27
申请人： David H. McConville , Lily Ackerman , Robert T. Li , Xiaohong Bei , Mathew C. Kuchta , Tom Boussie , John F. Walzer , Gary Diamond , Francis C. Rix , Keith A. Hall , Anne LaPointe , James Longmire , Vince Murphy , Pu Sun , Dawn Verdugo , Susan Schofer , Eric Dias
发明人： David H. McConville , Lily Ackerman , Robert T. Li , Xiaohong Bei , Mathew C. Kuchta , Tom Boussie , John F. Walzer , Gary Diamond , Francis C. Rix , Keith A. Hall , Anne LaPointe , James Longmire , Vince Murphy , Pu Sun , Dawn Verdugo , Susan Schofer , Eric Dias
IPC分类号： C08K5/56
CPC分类号： C07C2/32 , B01J31/1815 , B01J31/2208 , B01J2231/20 , B01J2531/62 , C07C2531/22 , C08F10/00 , C07C11/02 , C08F4/69146 , C08F4/69275 , C08F4/69103 , C08F4/69172
摘要： The present invention provides a method of producing oligomers of olefins, comprising reacting olefins with a catalyst under oligomerization conditions. The catalyst can be the product of the combination of a chromium compound and a heteroaryl-amine compound. In particular embodiments, the catalyst compound can be used to trimerize or tetramerize ethylene to 1-hexene, 1-octene, or mixtures of 1-hexene and 1-octene.
摘要翻译： 本发明提供一种生产烯烃低聚物的方法，包括在低聚条件下使烯烃与催化剂反应。 催化剂可以是铬化合物和杂芳基 - 胺化合物的组合的产物。 在具体实施方案中，催化剂化合物可用于将乙烯三聚或四聚为1-己烯，1-辛烯或1-己烯和1-辛烯的混合物。
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公开(公告)号：US07199074B2
公开(公告)日：2007-04-03
申请号：US11140287
申请日：2005-05-27
CPC分类号： B01J31/16 , B01J31/146 , B01J31/1805 , B01J31/182 , B01J31/183 , B01J31/2208 , B01J31/2243 , B01J31/2291 , B01J31/2404 , B01J2231/005 , B01J2231/12 , B01J2531/001 , B01J2531/0241 , B01J2531/0252 , B01J2531/0291 , B01J2531/16 , B01J2531/62 , B01J2531/72 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C08F4/639 , C08F4/7052 , C08F10/00 , C08F12/08 , C08F112/08 , C08F210/02 , C08F210/14 , C08F2410/03 , C08F4/695 , C08F220/14 , C08F2500/03 , C08F232/00 , C08F2500/25 , C08F212/08 , C08F4/60048 , C08F4/7006 , C08F4/7016 , C08F4/69103 , C08F4/60189 , C08F4/69112
摘要： A catalytic composition, including a cationic metal-pair complex, is disclosed, along with a method for its preparation. A method for the polymerization of ethylenically unsaturated monomers using the catalytic composition, and the addition polymers produced thereby are also disclosed.
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9.发明申请Process for producing polar olefin copolymer and polar olefin copolymer obtained thereby 有权制备极性烯烃共聚物和极性烯烃共聚物的方法公开(公告)号：US20060063898A1
公开(公告)日：2006-03-23
申请号：US11253963
申请日：2005-10-20
申请人： Yoshihisa Inoue , Shigekazu Matsui , Yasuhiko Suzuki , Yasunori Yoshida , Yukihiro Takagi , Terunori Fujita , Tomoaki Matsugi , Takashi Nakano
发明人： Yoshihisa Inoue , Shigekazu Matsui , Yasuhiko Suzuki , Yasunori Yoshida , Yukihiro Takagi , Terunori Fujita , Tomoaki Matsugi , Takashi Nakano
IPC分类号： C08F4/44
CPC分类号： C08F210/02 , C08F4/619 , C08F4/639 , C08F4/659 , C08F10/00 , C08F4/54 , C08F4/64048 , C08F220/06 , C08F2500/20 , C08F2500/17 , C08F220/12 , C08F220/04 , C08F232/00 , C08F222/06 , C08F4/6812 , C08F4/6912 , C08F4/7022 , C08F4/64044 , C08F4/68112 , C08F4/69112 , C08F4/69474 , C08F4/68474 , C08F4/64189 , C08F4/64051 , C08F4/68129 , C08F4/69129 , C08F4/68293 , C08F4/64186 , C08F4/68465 , C08F4/69465 , C08F4/69103 , C08F4/68103
摘要： A process for producing a polar olefin copolymer comprises copolymerizing a non-polar olefin and a polar olefin in the presence of a transition metal compound selected from Groups 4, 5, 6 and 11 of the periodic table, which is represented by the following formula (IV): wherein M′ is a transition metal atom selected from Groups 4, 5, 6 and 11 of the periodic table, m is an integer of 1 to 6, A is —O—, —Si—, —Se—, —N(R6)—, n is a number satisfying a valence of M′, R1 to R4 and R6 are each a hydrogen atom, a halogen atom, a hydrocarbon group and the like, and X is a halogen atom, an oxygen atom, a hydrocarbon group and the like, and at least one compound (B) selected from the group consisting of an organometallic compound (B-1), an organoaluminum oxy-compound (B-2) and an ionic ionizing compound (B-3). Therefore, the process is capable of obtaining a polar olefin copolymer having excellent properties under mild polymerization conditions.
摘要翻译： 一种制备极性烯烃共聚物的方法，包括在选自元素周期表第4,5,6和11族的过渡金属化合物存在下使非极性烯烃和极性烯烃共聚合，其由下式（ IV）：
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公开(公告)号：US07638671B2
公开(公告)日：2009-12-29
申请号：US12215626
申请日：2008-06-27
申请人： David H. McConville , Lily Ackerman , Robert T. Li , Xiaohong Bei , Matthew C. Kuchta , Tom Boussie , John F. Walzer, Jr. , Gary Diamond , Francis C. Rix , Keith A. Hall , Anne LaPointe , James Longmire , Vince Murphy , Pu Sun , Dawn Verdugo , Susan Schofer , Eric Dias
发明人： David H. McConville , Lily Ackerman , Robert T. Li , Xiaohong Bei , Matthew C. Kuchta , Tom Boussie , John F. Walzer, Jr. , Gary Diamond , Francis C. Rix , Keith A. Hall , Anne LaPointe , James Longmire , Vince Murphy , Pu Sun , Dawn Verdugo , Susan Schofer , Eric Dias
CPC分类号： C07C2/32 , B01J31/1815 , B01J31/2208 , B01J2231/20 , B01J2531/62 , C07C2531/22 , C08F10/00 , C07C11/02 , C08F4/69146 , C08F4/69275 , C08F4/69103 , C08F4/69172
摘要： The present invention provides a method of producing oligomers of olefins, comprising reacting olefins with a catalyst under oligomerization conditions. The catalyst can be the product of the combination of a chromium compound and a heteroaryl-amine compound. In particular embodiments, the catalyst compound can be used to trimerize or tetramerize ethylene to 1-hexene, 1-octene, or mixtures of 1-hexene and 1-octene.
摘要翻译： 本发明提供一种生产烯烃低聚物的方法，包括在低聚条件下使烯烃与催化剂反应。 催化剂可以是铬化合物和杂芳基 - 胺化合物的组合的产物。 在具体实施方案中，催化剂化合物可用于将乙烯三聚或四聚为1-己烯，1-辛烯或1-己烯和1-辛烯的混合物。
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