Supramolecular star-shaped polymer with beta-CD as core and preparation method

    公开(公告)号:US11912802B2

    公开(公告)日:2024-02-27

    申请号:US18067512

    申请日:2022-12-16

    发明人: Yongming Li Qiang Ren

    摘要: A supramolecular star-shaped polymer with β-CD as a core and a preparation method thereof. The supramolecular star-shaped polymer with β-CD as a core has a β-cyclodextrin-modified branched monomer F-β-CD that serves as a core and is grafted with acrylamide, acrylic acid, hydrophobic monomers and surface-active macromolecular monomers to form a supramolecular star-shaped polymer. The hydrophobic monomer is one or more of N-benzyl-N alkyl (meth) acrylamide and N-phenethyl-N alkyl (meth) acrylamide; the surface-active macromolecular monomer is one or more of allyl polyoxyethylene ether, alkylphenol polyoxyethylene ether (meth)acrylate, allyl alkylphenol polyoxyethylene ether, alkyl alcohol polyoxyethylene ether (meth)acrylate and allyl alkyl alcohol polyoxyethylene ether. The method has cheapness and easiness to obtain raw materials, ease to control synthesis conditions, and high yield. The present invention has excellent tackifying performance, temperature resistance, salt resistance and hydrolysis resistance, so that it shows good application prospects in the aspect of enhancing recovery ratios and hydraulic fracturing in oilfields.

    Polyester diverting agents for low-temperature oil wells

    公开(公告)号:US11898096B2

    公开(公告)日:2024-02-13

    申请号:US17617729

    申请日:2020-06-15

    申请人: STEPAN COMPANY

    IPC分类号: C09K8/68 C09K8/72 C09K8/88

    摘要: A hydraulic fracturing method for recovering oil from a low-temperature subterranean oil formation is disclosed. Before, during, or after inducing hydraulic fracturing within the formation, a particulate, degradable polyester diverting agent is introduced into the formation in an amount effective to improve oil production from the formation. The diverting agent is allowed to degrade, and oil is recovered. The diverting agent has a melting point greater than the average temperature of the formation and is selected from: (i) ethylene glycol succinates; (ii) acid-terminated ethylene glycol succinates; (iii) acid-terminated polyglycolic acids; (iv) acid-terminated polylactic acids; (v) mixtures of any of (i) through (iv) with a half acid ester; and (vi) mixtures of polylactic acids or polyglycolic acids with a half acid ester. These easily synthesized classes of particulate polyester diverting agents degrade more effectively than polylactides under the conditions present in low-temperature wells and should help to enhance well productivity.

    DIVERTING MATERIALS FOR WELL STIMULATION
    4.
    发明公开

    公开(公告)号:US20230416600A1

    公开(公告)日:2023-12-28

    申请号:US17848143

    申请日:2022-06-23

    IPC分类号: C09K8/88 C09K8/92

    CPC分类号: C09K8/885 C09K8/92

    摘要: Compositions containing a diverting material, and related methods and systems for diverting a fluid from a high permeability zone in an underground formation to a low permeability zone in the underground formation. The diverter material contains a polyurethane and a second polymer. The compositions, methods and systems may be used to achieve more homogeneous stimulation during a well stimulation treatment.

    SUBTERRANEAN STIMULATION OPERATIONS UTILIZING DEGRADABLE PRE-COATED PARTICULATES

    公开(公告)号:US20180258344A1

    公开(公告)日:2018-09-13

    申请号:US15760214

    申请日:2015-11-16

    摘要: Degradable particulates may allow for temporary redirection or occlusion of a fluid within a subterranean formation. However, many types of degradable particulates can be problematic for large-scale use, such as during subterranean treatment operations. Methods for treating a subterranean formation using degradable particulates may comprise: providing pre-coated particulates comprising a latently dissolvable core and a transient coating surrounding the latently dissolvable core, the latently dissolvable core and the transient coating comprising different materials; and introducing a treatment fluid comprising a carrier fluid and a plurality of the pre-coated particulates into a wellbore penetrating a subterranean formation in conjunction with a stimulation operation, a material comprising the latently dissolvable core being soluble in the carrier fluid or a formation fluid present within the subterranean formation.