Process for removing contaminant cations from a stream with high surface area triple layered perovskites
    1.
    发明授权
    Process for removing contaminant cations from a stream with high surface area triple layered perovskites 失效
    从具有高表面积三层钙钛矿的流中除去污染物阳离子的方法

    公开(公告)号:US06379557B1

    公开(公告)日:2002-04-30

    申请号:US09444649

    申请日:1999-11-22

    申请人: Robert L. Bedard

    发明人: Robert L. Bedard

    IPC分类号: B01D1504

    摘要: A process for synthesizing a family of non-pillared metal oxide triple layered perovskite has been developed. The perovskite has a surface area of at least 30 m2/g and an empirical formula of AB2M3O10−x where A is a monovalent exchangeable cation such as cesium, B is a divalent or trivalent cation such as strontium or lanthanum and M is a +2, +3, +4 or a +5 valent metal such as niobium, titanium, aluminum or copper. The process involves forming a reaction mixture containing reactive sources of A, B and M at a pH greater than seven and a temperature and time sufficient to form the perovskite. A process for removing contaminants from effluent streams using the above perovskites is also disclosed.

    摘要翻译: 已经开发了合成非柱状金属氧化物三层钙钛矿族的方法。 钙钛矿的表面积至少为30m2 / g,经验式为A,其中A为一价可交换阳离子,如铯,B为二价或三价阳离子如锶或镧,M为+2,+3, +4或+5价金属如铌,钛,铝或铜。 该方法包括在大于7的pH下形成含有A,B和M的反应性源的反应混合物,以及足以形成钙钛矿的温度和时间。 还公开了使用上述钙钛矿从流出物流中除去污染物的方法。

    Purification of produced water from coal seam natural gas wells using ion exchange and reverse osmosis
    2.
    发明授权
    Purification of produced water from coal seam natural gas wells using ion exchange and reverse osmosis 有权
    使用离子交换和反渗透从煤层天然气井净化产水

    公开(公告)号:US06372143B1

    公开(公告)日:2002-04-16

    申请号:US09669543

    申请日:2000-09-26

    申请人: Robert L. Bradley

    发明人: Robert L. Bradley

    IPC分类号: B01D1504

    摘要: A method and apparatus are provided for treating produced water to lower the total dissolved solids of the water for safe discharge to the environment. The produced water is passed through a weak acid cation resin in H+ form to remove cations in the produced water and then preferably through a decarbonator to remove formed CO2 and to provide a first discharge stream. The cation loaded resin is then regenerated using a dilute acid, preferably diluted with produced water, to regenerate the resin to the H+ form. The resultant acid regenerated waste stream is discharged to a reject deep well. The acid regenerated resin is then rinsed, preferably with produced water, to remove residual salts to form a residual salt containing rinse stream. This salt stream is passed into a reverse osmosis unit to form a high salt containing reject stream which is discharged to a waste deep well and a low salt containing product discharge stream which may be safely discharged to the environment.

    摘要翻译: 提供了一种用于处理生产水以降低水的总溶解固体以便安全排放到环境中的方法和装置。 所产生的水通过H +形式的弱酸性阳离子树脂以去除所生产的水中的阳离子,然后优选通过脱碳酸酯除去形成的CO 2并提供第一排出流。 然后将阳离子负载的树脂用稀酸再生,优选用产生的水稀释,以将树脂再生成H +形式。 所得到的酸再生废物流被排放到拒绝深井。 然后将酸再生树脂漂洗,优选用生成的水漂洗以除去残留的盐,形成含有残余盐的冲洗流。 将该盐流送入反渗透装置,以形成高盐含量的废弃物流,该排出物排放到废物深井中,而含有低盐的产物排出物流可以安全地排放到环境中。

    Water treatment process
    3.
    发明授权
    Water treatment process 失效
    水处理工艺

    公开(公告)号:US06669849B1

    公开(公告)日:2003-12-30

    申请号:US08809044

    申请日:1997-05-30

    IPC分类号: B01D1504

    摘要: The present invention relates to water treatment, in particular to a process for the removal of dissolved organic carbon from water. The process includes the following steps, adding an ion-exchange resin to water containing a contaminant such as dissolved organic carbon, dispersing the resin in the contaminated water to enable adsorption of the dissolved organic carbon onto the resin, and separating the resin loaded with contaminant from the water. In a preferred embodiment the process employs a magnetic ion-exchange resin.

    摘要翻译: 本发明涉及水处理,特别涉及从水中除去溶解的有机碳的方法。 该方法包括以下步骤:将离子交换树脂添加到含有溶解有机碳的污染物的水中,将树脂分散在污染的水中,以使溶解的有机碳吸附到树脂上,并分离负载有污染物的树脂 从水中。 在优选实施方案中,该方法采用磁性离子交换树脂。

    Water/oil separator and use thereof
    4.
    发明授权
    Water/oil separator and use thereof 失效
    水/油分离器及其用途

    公开(公告)号:US06641738B2

    公开(公告)日:2003-11-04

    申请号:US09931518

    申请日:2001-08-16

    申请人: Russ R. Hard

    发明人: Russ R. Hard

    IPC分类号: B01D1504

    CPC分类号: B01D17/045 B01D17/085

    摘要: A process for the removal of oil from oil-contaminated water is efficient, inexpensive, and capable of oil removal to a level where the water may be disposed of by conventional sewage treatment or reused. The apparatus which performs the process consists of an elongate housing having at least one upwardly extending oil collection tower and an oily water inlet mediate the oil or oil-enriched water outlet and the “clean” water outlet. The elongate housing and preferably also the oil collection tube are filled with beads of hydrophobic polymer.

    摘要翻译: 从油污水中去除油的过程是有效的,廉价的,并且能够将油去除到通过常规污水处理或再利用可以处理水的水平。 执行该过程的装置包括具有至少一个向上延伸的收集塔的细长壳体,并且油性水入口介入油或富油水出口和“清洁”出水口。 细长的壳体和优选地还有采油管中填充有疏水性聚合物珠。

    Method for treating metal-working fluid
    6.
    发明授权
    Method for treating metal-working fluid 失效
    处理金属加工液的方法

    公开(公告)号:US06712975B1

    公开(公告)日:2004-03-30

    申请号:US09812480

    申请日:2001-03-19

    IPC分类号: B01D1504

    摘要: A method for treating metal-working fluid comprises the steps of: a) transferring the metal-working fluid into a heating vessel; b) heating the metal-working fluid in the heating vessel to maintain the fluid at an elevated temperature during a heating period; c) agitating and aerating the fluid during the heating period; d) transferring the fluid out of the heating vessel into a holding vessel after the heating period; and e) transferring the fluid out of the holding vessel. The fluid may pass through a particle filter before entering the heating vessel, where it may be heated to between about 145° F. and about 210° F. for at least about 30 minutes. During heating, heated ambient air may be drawn through air inlets and through the fluid to agitate and aerate the fluid, thereby ensuring uniform heating and extracting gaseous contaminants. Mist and gaseous contaminants are removed from the airflow prior to its release into the environment. After the heating period the treated metal-working fluid is transferred into a holding vessel and ultimately back to a metal-working machine for re-use. An apparatus for treating metal-working fluid comprises: a) a heating vessel; b) a heater for heating the fluid in the heating vessel to an elevated temperature to maintain the fluid at the elevated temperature during a heating period; c) an agitator for agitating the fluid during the heating period; d) an aerator for aerating the fluid during the heating period; e) a holding vessel; and f) a pump for transferring the metal-working fluid from the heating vessel into the holding vessel after the heating period.

    摘要翻译: 一种处理金属工作流体的方法包括以下步骤:a)将金属工作流体转移到加热容器中; b)加热加热容器中的金属工作流体,以在加热期间将流体保持在升高的温度; c)在加热期间搅拌和充气流体; d)在加热期后将流体从加热容器中转移到保持容器中; 以及e)将流体从所述保持容器中移出。 流体可以在进入加热容器之前通过颗粒过滤器,其中可将其加热至约145°F至约210°F至少约30分钟。 在加热期间,加热的环境空气可以通过空气入口抽吸并通过流体搅拌和充气流体,从而确保均匀加热和提取气态污染物。 雾气和气态污染物在释放到环境中之前从气流中去除。 在加热期后,将经处理的金属工作流体转移到保持容器中,并最终返回到金属加工机器以供再利用。 一种用于处理金属工作流体的设备包括:a)加热容器; b)加热器,用于将加热容器中的流体加热到升高的温度,以在加热期间将流体保持在升高的温度; c)用于在加热期间搅拌流体的搅拌器; d)在加热期间使流体充气的充气器; e)持有船只 以及f)用于在加热期间将金属工作流体从加热容器转移到保持容器中的泵。

    Process and composition for removing toxins from bodily fluids
    7.
    发明授权
    Process and composition for removing toxins from bodily fluids 有权
    从体液中去除毒素的方法和组成

    公开(公告)号:US06579460B1

    公开(公告)日:2003-06-17

    申请号:US09805098

    申请日:2001-03-13

    IPC分类号: B01D1504

    摘要: A process and a composite for removing toxic cations and anions from blood or dialysate is disclosed. The process involves contacting blood or dialysate with a shaped ion exchange composite to remove ammonium and phosphate ions. The composite is a mixture of an anion exchange composition such as zirconia and a microporous cation exchange composition formed into a shaped article and optionally containing a binder such as hydrous zirconium oxide. The microporous cation exchangers are represented by the following empirical formula. ApMxZr1−xSinGeyOm  (I) or ApMxTi1−xSinGeyOm  (II)

    摘要翻译: 公开了一种用于从血液或透析液中除去有毒阳离子和阴离子的方法和复合物。 该过程包括使血液或透析液与成型的离子交换复合物接触以除去铵和磷酸根离子。 该复合物是阴离子交换组合物如氧化锆和形成成型制品的微孔阳离子交换组合物和任选地含有粘合剂如含水氧化锆的混合物。 微孔阳离子交换剂由以下经验公式表示

    Process for modifying the metal ion sorption capacity of a medium

    公开(公告)号:US06436294B1

    公开(公告)日:2002-08-20

    申请号:US09199296

    申请日:1998-11-24

    IPC分类号: B01D1504

    摘要: A process for modifying a medium is disclosed that includes treating a medium having a metal ion sorption capacity with a solution that includes: A) an agent capable of forming a complex with metal ions; and B) ions selected from the group consisting of sodium ions, potassium ions, magnesium ions, and combinations thereof, to create a medium having an increased capacity to sorb metal ions relative to the untreated medium.

    Process for drying CH2F2 refrigerant utilizing zeolite
    9.
    发明授权
    Process for drying CH2F2 refrigerant utilizing zeolite 有权
    使用沸石干燥CH2F2制冷剂的方法

    公开(公告)号:US06168720A

    公开(公告)日:2001-01-02

    申请号:US09376684

    申请日:1999-08-18

    IPC分类号: B01D1504

    摘要: Difluoromethane (R-32) is of current interest as a partial replacement for chlorodifluoromethane (R-22) refrigerant heretofore widely used in vapor compression refrigeration systems. R-32 has, however, proved to be more reactive than is desirable with the zeolite A adsorbent-desiccant compositions used in such systems to prevent corrosion and freeze-up problems. The potassium cation form of a zeolite A molecular sieve—with at least 60 percent of the sodium cations replaced with potassium ions, agglomerated with a clay binder, and pore-reduced to essentially exclude the adsorption of R-32 having essentially no reactivity with difluoromethane, and having a surface ratio of silicon to aluminum of less than about 1.7 mol/mol as determined by X-ray photoelectron spectroscopy—has been found to be an effective desiccant for refrigerants comprising difluoromethane.

    摘要翻译: 作为蒸气压缩制冷系统中广泛使用的氯二氟甲烷(R-22)制冷剂的部分替代品,目前感兴趣的是二氟甲烷(R-32)。 然而,R-32被证明比在这种系统中用于防止腐蚀和冷冻问题的沸石A吸附剂 - 干燥剂组合物所需要的反应性更强。 沸石A分子筛的钾离子形式 - 至少60%的钠阳离子用钾离子代替,用粘土粘合剂聚集,并且被孔隙还原,基本上排除了对二氟甲烷基本上没有反应性的R-32的吸附 ,并且通过X射线光电子能谱法测定的硅与铝的表面比率小于约1.7mol / mol已经被发现是用于包含二氟甲烷的制冷剂的有效干燥剂。

    Method for removing the gasoline additive MTBE from water using molecularly imprinted polymers
    10.
    发明授权
    Method for removing the gasoline additive MTBE from water using molecularly imprinted polymers 失效
    使用分子印迹聚合物从水中除去汽油添加剂MTBE的方法

    公开(公告)号:US06783686B2

    公开(公告)日:2004-08-31

    申请号:US09888968

    申请日:2001-06-25

    IPC分类号: B01D1504

    摘要: A method and product for removing at MTBE molecules from a solution, such as a contaminated aquifer, includes exposing the solution to a plurality of molecularly imprinted polymer beads (MIPS) that have receptor sites on the surfaces thereof that include imprints that match the physical shape of at least a portion of an MTBE molecule. A quantity of the MTBE molecules align with and adhere to some of the receptor sites and, accordingly, they are removed from the solution producing a remediated solution. According to one embodiment, the MIPS are contained in an enclosure having a plurality of openings large enough to permit the solution to pass through and small enough so as to prevent the MIPS from passing through. According to a preferred embodiment the MIPS are applied (i.e., coated) to the inside surface of a conduit and the solution is forced or allowed to flow through the conduit thereby removing some of the MTBE molecules therefrom.

    摘要翻译: 用于从溶液(例如污染含水层)中除去MTBE分子的方法和产物包括将溶液暴露于多个分子印迹聚合物珠粒(MIPS),其在其表面上具有受体位点,其包括与物理形状相匹配的印记 的至少一部分MTBE分子。 一定量的MTBE分子与一些受体位点配对并粘附,因此从溶液中除去它们,产生修复的溶液。 根据一个实施例,MIPS包含在具有足够大的许多开口的外壳中,以允许溶液通过并且足够小以防止MIPS通过。 根据优选实施例,将MIPS施加(即涂覆)到导管的内表面,并且迫使溶液流过导管,从而从其中除去一些MTBE分子。