Gas diffusion electrode for electrochemical oxygen reduction
    2.
    发明授权
    Gas diffusion electrode for electrochemical oxygen reduction 有权
    用于电化学氧还原的气体扩散电极

    公开(公告)号:US07820339B2

    公开(公告)日:2010-10-26

    申请号:US11837032

    申请日:2007-08-10

    IPC分类号: H01M4/08 H01M4/90

    摘要: An improved gas diffusion electrode composed of a perovskite-type oxide dispersed in a mixture of carbon black and a hydrophobic binder polymer. An improved catalyst for use in the electrochemical reduction of oxygen comprising a perovskite-type compound having alpha and beta sites, and having a greater molar ratio of cations at the beta site. A particularly good reduction catalyst is a neodymium calcium manganite. An improved method of dispersing the catalysts with carbon in a reaction layer of the electrode improves performance of the electrode and the oxygen reduction process. This is provided by adding carbon black to an aqueous solution of metal salts before it is heated to a gel and then to a char and then calcined. Optionally, a quantity of the desired oxide catalyst can be premixed with a portion the carbon before adding the carbon to an aqueous solution of the metal salts to be heated. The amount of premixed metal oxide is chosen in conjunction with the amount of metal salts to provide the desired molar ratio after heating and calcining of the aqueous solution.

    摘要翻译: 改进的气体扩散电极,其由分散在炭黑和疏水性粘合剂聚合物的混合物中的钙钛矿型氧化物组成。 用于电化学还原氧的改进的催化剂包括具有α和β位点的钙钛矿型化合物,并且在β位具有更大的阳离子摩尔比。 特别好的还原催化剂是钕钙锰矿。 将电催化剂用碳分散在电极的反应层中的改进方法提高了电极的性能和氧还原过程。 这是通过在金属盐的水溶液加热至凝胶然后加入炭然后煅烧之前将炭黑加入到水溶液中而提供的。 任选地,一定量的所需氧化物催化剂可以在将碳添加到待加热的金属盐的水溶液中之前与碳的一部分预混合。 联合金属盐的量选择预混合金属氧化物的量,以便在加热和煅烧水溶液之后提供所需的摩尔比。

    Method of diffusing a catalyst for electrochemical oxygen reduction
    3.
    发明授权
    Method of diffusing a catalyst for electrochemical oxygen reduction 失效
    扩散电化学氧还原催化剂的方法

    公开(公告)号:US07666812B2

    公开(公告)日:2010-02-23

    申请号:US11837008

    申请日:2007-08-10

    摘要: An improved gas diffusion electrode composed of a perovskite-type oxide dispersed in a mixture of carbon black and a hydrophobic binder polymer. An improved catalyst for use in the electrochemical reduction of oxygen comprising a perovskite-type compound having alpha and beta sites, and having a greater molar ratio of cations at the beta site. A particularly good reduction catalyst is a neodymium calcium manganite. An improved method of dispersing the catalysts with carbon in a reaction layer of the electrode improves performance of the electrode and the oxygen reduction process. This is provided by adding carbon black to an aqueous solution of metal salts before it is heated to a gel and then to a char and then calcined. Optionally, a quantity of the desired oxide catalyst can be premixed with a portion the carbon before adding the carbon to an aqueous solution of the metal salts to be heated. The amount of premixed metal oxide is chosen in conjunction with the amount of metal salts to provide the desired molar ratio after heating and calcining of the aqueous solution.

    摘要翻译: 改进的气体扩散电极,其由分散在炭黑和疏水性粘合剂聚合物的混合物中的钙钛矿型氧化物组成。 用于电化学还原氧的改进的催化剂包括具有α和β位点的钙钛矿型化合物,并且在β位具有更大的阳离子摩尔比。 特别好的还原催化剂是钕钙锰矿。 将电催化剂用碳分散在电极的反应层中的改进方法提高了电极的性能和氧还原过程。 这是通过在金属盐的水溶液加热至凝胶然后加入炭然后煅烧之前将炭黑加入到水溶液中而提供的。 任选地,一定量的所需氧化物催化剂可以在将碳添加到待加热的金属盐的水溶液中之前与碳的一部分预混合。 联合金属盐的量选择预混合金属氧化物的量,以便在加热和煅烧水溶液之后提供所需的摩尔比。

    Gas Diffusion Electrode For Electrochemical Oxygen Reduction
    7.
    发明申请
    Gas Diffusion Electrode For Electrochemical Oxygen Reduction 有权
    用于电化学氧还原的气体扩散电极

    公开(公告)号:US20080057379A1

    公开(公告)日:2008-03-06

    申请号:US11837032

    申请日:2007-08-10

    IPC分类号: H01M4/90 C25B11/06

    摘要: An improved gas diffusion electrode composed of a perovskite-type oxide dispersed in a mixture of carbon black and a hydrophobic binder polymer. An improved catalyst for use in the electrochemical reduction of oxygen comprising a perovskite-type compound having alpha and beta sites, and having a greater molar ratio of cations at the beta site. A particularly good reduction catalyst is a neodymium calcium manganite. An improved method of dispersing the catalysts with carbon in a reaction layer of the electrode improves performance of the electrode and the oxygen reduction process. This is provided by adding carbon black to an aqueous solution of metal salts before it is heated to a gel and then to a char and then calcined. Optionally, a quantity of the desired oxide catalyst can be premixed with a portion the carbon before adding the carbon to an aqueous solution of the metal salts to be heated. The amount of premixed metal oxide is chosen in conjunction with the amount of metal salts to provide the desired molar ratio after heating and calcining of the aqueous solution.

    摘要翻译: 改进的气体扩散电极,其由分散在炭黑和疏水性粘合剂聚合物的混合物中的钙钛矿型氧化物组成。 用于电化学还原氧的改进的催化剂包括具有α和β位点的钙钛矿型化合物,并且在β位具有更大的阳离子摩尔比。 特别好的还原催化剂是钕钙锰矿。 将电催化剂用碳分散在电极的反应层中的改进方法提高了电极的性能和氧还原过程。 这是通过在金属盐的水溶液加热至凝胶然后加入炭然后煅烧之前将炭黑加入到水溶液中而提供的。 任选地,一定量的所需氧化物催化剂可以在将碳添加到待加热的金属盐的水溶液中之前与碳的一部分预混合。 联合金属盐的量选择预混合金属氧化物的量,以便在加热和煅烧水溶液之后提供所需的摩尔比。

    Process and apparatus for producing powders of metal compound containing oxygen, and the powders produced by the process
    9.
    发明申请
    Process and apparatus for producing powders of metal compound containing oxygen, and the powders produced by the process 失效
    用于生产含氧的金属化合物的粉末的方法和设备,以及通过该方法生产的粉末

    公开(公告)号:US20050204514A1

    公开(公告)日:2005-09-22

    申请号:US11076948

    申请日:2005-03-11

    摘要: An apparatus for producing powders of metal compound containing oxygen comprising a liquid flow controller, a vaporizer and a reactor, which consists essentially of: means for feeding a gas containing a material and oxygen; means for heating the gas from the side surface of the feeding means; means for cooling the gas positioned at the downstream side of the feeding means; and means for receiving the product generated by the reaction. A process and products for producing powders of metal compound containing oxygen comprising the steps of: feeding at least one material selected from a liquid material and a solution material obtained by dissolving solid ingredient in organic solvent via a liquid flow controller into a vaporizer; vaporizing the materials in the vaporizer; adding oxygen; heating; cooling; and crystallizing. The process and the apparatus enable easily mass-producing fine powders of metal compound containing oxygen used as materials for optical crystals, nonlinear crystals or magneto-optical crystals with reasonable production cost.

    摘要翻译: 一种用于生产包含氧的金属化合物的粉末的装置,包括液体流量控制器,蒸发器和反应器,其基本上由以下部件组成:用于供给包含材料和氧气的气体的装置; 用于从进料装置的侧表面加热气体的装置; 用于冷却位于所述进给装置的下游侧的气体的装置; 以及用于接收由反应产生的产物的装置。 一种用于生产含氧的金属化合物粉末的方法和产品,包括以下步骤:将通过液体流量控制器将固体成分溶解在有机溶剂中而获得的液体材料和溶液中的至少一种材料进料到蒸发器中; 蒸发蒸发器中的物质; 加氧; 加热; 冷却; 并结晶。 该方法和装置能够以合理的生产成本容易地批量生产含有氧的金属化合物的细粉末作为光学晶体的材料,非线性晶体或磁光晶体。