Alpha-halogeno-lauroyl peroxides, solutions thereof, and methods of preparing them
    1.
    发明授权
    Alpha-halogeno-lauroyl peroxides, solutions thereof, and methods of preparing them 失效
    ALPHA-HALOGENO-LAUROYL过氧化物及其制备方法及其制备方法

    公开(公告)号:US3728401A

    公开(公告)日:1973-04-17

    申请号:US3728401D

    申请日:1966-12-29

    发明人: VAN GAVER G

    IPC分类号: C07C409/34 C07C73/02

    CPC分类号: C07C409/34

    摘要: New alpha-halogeno-lauroyl peroxides are described with novel processes of making them and with some reference to their uses. In general, they are prepared by mixing an alpha-halogeno-lauroyl halide diluted in a solvent inert to the constituents of the reaction medium with hydrogen peroxide in the presence of caustic soda under conditions of temperature, pressure, agitation favorable to their reaction.

    摘要翻译: 新的α-卤代 - 月桂酰基过氧化物用新的制备方法描述,并参考其用途。 通常,它们通过在苛性钠的存在下,在有利于其反应的温度,压力,搅拌条件下,将在与反应介质成分惰性的溶剂中稀释的α-卤代 - 月桂酰卤与过氧化氢混合来制备。

    Novel diacyl peroxides
    2.
    发明授权
    Novel diacyl peroxides 失效
    新型二氧化碳过氧化物

    公开(公告)号:US3855315A

    公开(公告)日:1974-12-17

    申请号:US30303972

    申请日:1972-11-02

    摘要: 3-Alkoxy acyl peroxides having the formula:

    IN WHICH R is alkyl containing from 1 to 14 carbon atoms, and X is hydrogen or methyl are new compounds which resemble common diacyl peroxides in manner of decomposition, but exhibit important differences in chemical and physical properties. The new peroxides are liquids at ambient temperatures and possess a higher degree of thermal stability than the commonly used aliphatic acyl peroxides of similar structure and molecular weight. The new compounds, and especially the 3-alkoxyisobutyryl peroxides, are suitable for use as initiators for the polymerization or copolymerization of ethylenic monomers and for the crosslinking of unsaturated polyesters.

    摘要翻译: 具有下式的3-烷氧基酰基过氧化物

    Diacyl peroxides
    3.
    发明授权
    Diacyl peroxides 失效
    二氧化碳过氧化物

    公开(公告)号:US3728402A

    公开(公告)日:1973-04-17

    申请号:US3728402D

    申请日:1968-05-15

    申请人: TEKNOR APEX CO

    摘要: 3-Alkoxy acyl peroxides having the formula:

    IN WHICH R is alkyl containing from one to 14 carbon atoms, and X is hydrogen or methyl are new compounds which resemble common diacyl peroxides in manner of decomposition, but exhibit important differences in chemical and physical properties. The new peroxides are liquids at ambient temperatures and possess a higher degree of thermal stability than the commonly used aliphatic acyl peroxides of similar structure and molecular weight. The new compounds, and especially the 3-alkoxyisobutyryl peroxides, are suitable for use as initiators for the polymerization or copolymerization of ethylenic monomers and for the cross-linking of unsaturated polyesters.

    摘要翻译: 具有下式的3-烷氧基酰基过氧化物

    Method for the continuous preparation of alkylperoxydicarbonates
    6.
    发明授权
    Method for the continuous preparation of alkylperoxydicarbonates 失效
    连续制备烷基二氧化二碳酸酯的方法

    公开(公告)号:US3849468A

    公开(公告)日:1974-11-19

    申请号:US30535172

    申请日:1972-11-10

    申请人: RHONE PROGIL

    发明人: BUSSERET R

    摘要: 1. A PROCESS FOR THE CONTINUOUS PREPARATION OF ALKYLPEROXYDICARBONATES IN SOLUTION FROM SODIUM PEROXIDE AND ALKYLCHLOROFORMATES COMPRISING CONGINUOUSLY CIRCULATING IN A REACTION CHAMBER AN AQUEOUS LIQUID MAINTAINED AT A TEMPERATURE OF AT LEAST -10* C., CONTINUOUSLY INTRODUCING INTO SAID AQUEOUS LIQUID HYDROXIDE, HYDROGEN PEROXIDE IN A STOICHIOMETIC EXCESS OF 10-20%, ALKYLCHLOROFORMATE AND A SOLVENT FOR SAID ALKYLPEROXYDICARBONATE, AT FLOW RATES SUCH THAT THE PJ OF THE AQUEOUS LIQUID IS CONSTANTLY MAINTAINED AT A VALUE WITHIN THE RANGE OF 3 TO 10, WHEREBY THE AMOUNT OF SODIUM HYDROXIDE FORMED IS IN EXCESS OF 10-20% BY WEIGHT OF THE ALKYLFORMATE SODIUM PEROXIDE CHIOMETRIC RATIO OF THE ALKYLFORMATE/SODIUM PEROXIDE, CONTINUOUSLY SEPARATING THE OBTAINED SOLUTION OF ALKYLPEROXYDICARBONATE FROM THE AQUEOUS LIQUID, WASHING SAID SOLUTION WITH WATER, AND SEPARATING THE WASHED SOLUTION OF ALKYLPEROXYDICARBONATE FROM THE WASH WATER.