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    Peroxy carboxylic amino-derivatives
    5.
    发明授权
    Peroxy carboxylic amino-derivatives 失效
    过氧羧基氨基衍生物

    公开(公告)号：US5423998A

    公开(公告)日：1995-06-13

    申请号：US45166

    申请日：1993-04-13

    Applicant: Carlo Venturello ,  Claudio Cavallotti

    Inventor： Carlo Venturello ,  Claudio Cavallotti

    IPC: C07C409/40 ,  C07D211/34 ,  C11D3/39 ,  C07D211/20 ,  C07D207/04 ,  C07D211/36 ,  C11D7/54

    CPC classification number: C07C409/40 ,  C07D211/34 ,  C11D3/3945

    Abstract: Amino-derivative (poly)peroxycarboxylic acids which have the formula: ##STR1## wherein the symbols have the following meanings: R, R.sub.1, and R.sub.2, which may be equal to or different from one another, represent hydrogen atoms, alkyl groups or groups selected from R, R.sub.1 and R.sub.2, which taken together with the nitrogen atom to which they are linked, give rise to an aliphatic heterocyclic group, all of them being optionally substituted;A represents a (cyclo)alkylene group, an arylene group which may also be condensed with cycloaliphatic groups, a cycloalkylene-alkylene or an alkylene-cycloalkylene group, an arylene-alkylene or an alkylene-arylene group, which may be condensed with cyclo-aliphatic groups, wherein said alkylene group may also be interrupted by --CONR.sub.3 groups, wherein R.sub.3 represents a hydrogen atom or an alkyl or aryl group;X.sup.- represents HSO.sub.4.sup.- or CH.sub.3 SO.sub.3.sup.- ; a process for their preparation; and their use as bleaching agents.

    Abstract translation: 具有下式的氨基衍生物（聚）过氧羧酸：其中符号具有以下含义：R，R 1和R 2可以相同或不同，表示氢原子，烷基 与它们所连接的氮原子一起选自R，R 1和R 2的基团或基团产生脂族杂环基团，它们全部被任选取代; A表示（环）亚烷基，也可以与脂环族基团缩合的亚芳基，亚环烷基亚烷基或亚烷基 - 亚环烷基，亚芳基 - 亚烷基或亚烷基 - 亚芳基，其可以与环 - 脂族基团，其中所述亚烷基也可以被-CONR 3基团中断，其中R 3表示氢原子或烷基或芳基; X-表示HSO4-或CH3SO3-; 其准备过程; 并将其用作漂白剂。

    Diacylated dipercarboxylic acid as bleaching agent
    6.
    发明授权
    Diacylated dipercarboxylic acid as bleaching agent 失效
    二酰基二过羧酸作为漂白剂

    公开(公告)号：US5415668A

    公开(公告)日：1995-05-16

    申请号：US946343

    申请日：1992-11-06

    Applicant: Hans Lagnemo ,  Annbritt Forsstrom

    Inventor： Hans Lagnemo ,  Annbritt Forsstrom

    IPC: C07C291/04 ,  C07C409/30 ,  C07C409/34 ,  C07C409/40 ,  C07C409/42 ,  C11D3/39 ,  C11D3/395 ,  D06L3/02

    CPC classification number: C07C291/04 ,  C07C409/34 ,  C07C409/40 ,  C07C409/42 ,  C11D3/3945

    Abstract: ##STR1## The invention concerns diacylated dipercarboxylic acids according to general formula (I), in which R
    1 and R
    2 are hydrocarbon groups having from 1 to 15 carbon atoms, and X is electron attracting by being an optionally substituted phenyl group, an optionally substituted heterocycle in which the hetero atom is positioned so that from 2 to 4 carbon atoms are present between the hetero atom and each one of the carbonyl carbons of the diperacid, or by comprising at least one electron attracting functional group positioned so that a carbon chain having from 2 to 4 carbon atoms is present between said electron attracting group and each one of the carbonyl carbons of the diperacid, wherein the electron attracting group contains oxygen, sulfur, nitrogen, phosphorus, halogen, optionally substituted phenyl, or at least two conjugated double bonds, R
    1 and R
    2 are hydrocarbon groups having from 1 to 15 carbon atoms, except compounds in which X consists of a phenyl group having the carbonyl carbons in 1,4 position and both of R
    1 and R
    2 are acetyl or both of R
    1 and R
    2 are nonyl. The invention also concerns a method of their preparation, a composition useful for bleaching and a method of bleaching.

    Abstract translation: PCT No.PCT / SE91 / 00291 Sec。 371日期：1992年11月6日 102（e）日期1992年11月6日PCT 1991年4月24日PCT PCT。 第WO91 / 17143号公报 （I）本发明涉及根据通式（I）的二酰化二元羧酸，其中R 1和R 2是具有1至15个碳原子的烃基，X是通过 任选取代的苯基，任选取代的杂环，其中所述杂原子被定位使得2至4个碳原子存在于所述杂原子和所述二酸的每个羰基碳之间，或通过包含至少一个吸电子 官能团定位使得具有2至4个碳原子的碳链存在于所述吸电子基团和二酸的每个羰基碳之间，其中电子吸引基团含有氧，硫，氮，磷，卤素，任选地 取代的苯基或至少两个共轭双键，R 1和R 2是具有1至15个碳原子的烃基，除了其中X由苯基 具有1,4位的羰基碳原子，R1和R2两者都是乙酰基，R1和R2都是壬基。 本发明还涉及它们的制备方法，可用于漂白的组合物和漂白方法。

    Diperisophthalic acids
    9.
    发明授权
    Diperisophthalic acids 失效
    间苯二甲酸

    公开(公告)号：US3880914A

    公开(公告)日：1975-04-29

    申请号：US16877771

    申请日：1971-08-03

    Applicant: PPG INDUSTRIES INC

    Inventor： NIELSEN DONALD R

    IPC: C07C409/30 ,  C07C73/10

    CPC classification number: C07C407/00 ,  C07B2200/13 ,  C07C409/40

    Abstract: Diperphthalic acids are prepared from hydrogen peroxide and the phthalic acid in an alkanesulfonic acid reaction medium by using finely subdivided phthalic acid with a particle dimension below 0.1 millimeter, more notably in the range of from 0.001 to 0.1 millimeter. A unique crystal form of diperisophthalic acid is obtained, for example, by reaction of isophthalic acid of less than 0.044 millimeter (less than 325 mesh).

    Abstract translation: 通过使用粒度小于0.1毫微米的细分的邻苯二甲酸，更特别地在0.001至0.1毫米的范围内，通过在链烷磺酸反应介质中由过氧化氢和邻苯二甲酸制备邻苯二甲酸。 通过例如小于0.044毫米（小于325目）的间苯二甲酸的反应获得独立的二间二邻苯二甲酸酯晶体。

    Substituted nitroalkyl nitrate and peroxynitrate
    10.
    发明授权
    Substituted nitroalkyl nitrate and peroxynitrate 失效
    取代的硝酸甘油和过氧化物

    公开(公告)号：US3853944A

    公开(公告)日：1974-12-10

    申请号：US31199372

    申请日：1972-12-04

    Applicant: TEXACO INC

    Inventor： CUMMINGS W

    IPC: C07C205/40 ,  C07C409/40 ,  C10L1/23 ,  C07C121/16

    CPC classification number: C10L1/231 ,  C07C205/40 ,  C07C409/40 ,  C10M1/08 ,  C10M2215/16 ,  C10M2215/202

    Abstract: WHERE R, R1 and X are as heretofore defined and second contacting said peroxynitrate with a reducing agent to form said substituted nitroalkyl nitrate, the first and second contacting being conducted in the presence of inert liquid. The nitroalkyl final products of the invention are useful as fuel additives to increase power output of petroleum distillates such as gasoline and kerosene. Further, they are useful as intermediates in the preparation of surfactants, fuel and lubricant additives, insecticides, fungicides (e.g. controlling early blight in bean plants), pharmaceuticals and polymers.

    WHERE R, R1 and X are as heretofore defined with a mixture of dinitrogen tetroxide and oxygen to form substituted nitroalkyl peroxynitrate of the formula:

    where R2 is alkyl of from 1 to 10 carbons of phenyl and R3 is hydrogen, phenyl or alkyl of from 1 to 10 carbons, and where Y is -OONO2 or -ONO2, said nitroalkyl nitrates being prepared by first contacting a substituted alkene of the formula:

    WHERE R and R1 are hydrogen or alkyl of from 1 to 10 carbons, where X is R2O-,-CN, Cl, phenyl, -ONO2,

    Nitroalkyl nitrate and peroxynitrates characterized by the formula:

    Abstract translation: 硝酸硝基硝酸盐和过氧硝酸盐，其特征在于下式：

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