公开(公告)号：USRE39744E1

公开(公告)日：2007-07-24

申请号：US10830494

申请日：1998-03-05

Applicant: Yasutaka Ishii ,  Tatsuya Nakano ,  Naruhisa Hirai

Inventor： Yasutaka Ishii ,  Tatsuya Nakano ,  Naruhisa Hirai

IPC: C07C35/22 ,  C07C61/12 ,  C07C211/00 ,  C07D207/40 ,  C07D207/444 ,  C07D204/24 ,  B01J31/00

CPC classification number: C07C29/50 ,  C07C35/37 ,  C07C62/06 ,  C07C62/24 ,  C07C67/05 ,  C07C67/08 ,  C07C67/29 ,  C07C67/31 ,  C07C68/02 ,  C07C69/757 ,  C07C69/96 ,  C07C205/18 ,  C07C205/41 ,  C07C205/55 ,  C07C219/24 ,  C07C233/23 ,  C07C233/32 ,  C07C233/74 ,  C07C235/40 ,  C07C265/10 ,  C07C271/34 ,  C07C2603/74 ,  C07C69/753 ,  C07C69/157

Abstract: In the presence of an imide compound (e.g., N-hydroxyphthalimide) shown by the formula (2): wherein R1 and R2 independently represents a hydrogen atom, a halogen atom, an alkyl group, an aryl group, a cycloalkyl group; or R1 and R2 may bond together to form a double bond or an aromatic or non-aromatic ring; Y is O or OH and n=1 to 3; or the imide compound and a co-catalyst (e.g., a transition metal compound), an adamantane derivative having a functional group such as a nitro group, an amino group, a hydroxyl group, a carboxyl group, a hydroxymethyl group and an isocyanato group is oxidized with oxygen. According to the above method, an adamantane derivative having a hydroxyl group together with a functional group such as a nitro group, an amino group, a hydroxyl group, a carboxyl group, a hydroxymethyl group and an isocyanato group is efficiently obtained.

Abstract translation: 在式（2）所示的酰亚胺化合物（例如，N-羟基邻苯二甲酰亚胺）存在下，其中R 1和R 2独立地表示氢原子，卤素 原子，烷基，芳基，环烷基; 或R 1和R 2可以键合在一起形成双键或芳族或非芳族环; Y为O或OH且n = 1至3; 或酰亚胺化合物和助催化剂（例如过渡金属化合物），具有硝基，氨基，羟基，羧基，羟甲基和异氰酸基的官能团的金刚烷衍生物 被氧气氧化。 根据上述方法，有效地获得具有羟基的金刚烷衍生物与硝基，氨基，羟基，羧基，羟甲基和异氰酸基等官能团。