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    Bis-phosphonium salt and process for producing the same
    2.
    发明授权
    Bis-phosphonium salt and process for producing the same 失效
    双鏻盐及其制备方法

    公开(公告)号：US06774265B2

    公开(公告)日：2004-08-10

    申请号：US10743728

    申请日：2003-12-24

    申请人： Sha Yaowu

    发明人： Sha Yaowu

    IPC分类号： C07F954

    CPC分类号： C07F9/65688 ,  C07F9/5449

    摘要： A bis-phosphonium salt represented by the following formula (1) is provided: wherein R1, R2, R3, and R4 each represent a linear or branched alkyl group, a cycloalkyl group, an aryl group, or an aralkyl group; A represents an alkylene group; Y represents an anion; R1 and R2 may form a ring; R3 and R4 may form a ring; and R1, R2, R3, and R4 may be the same or different. A process for producing such a bis-phosphonium salt includes a step of allowing a first secondary phosphine and second secondary phosphine to react with a compound in an alcohol solvent selected from a secondary alcohol and tertiary alcohol. The compound is represented by the following formula (5): Y—A—Y  (5)

    摘要翻译： 提供由下式（1）表示的双鏻盐：其中R 1，R 2，R 3和R 4各自表示直链或支链烷基，环烷基， 芳基或芳烷基; A表示亚烷基; Y表示阴离子; R 1和R 2可以形成环; R 3和R 4可以形成环; 并且R 1，R 2，R 3和R 4可以相同或不同。 制备这种双鏻盐的方法包括使第一仲膦和第二仲膦与选自仲醇和叔醇的醇溶剂中的化合物反应的步骤。 该化合物由下式（5）表示：

    Solvent-free mechanochemical preparation of phosphonium salts, phosphorus ylides, and olefins
    4.
    发明授权
    Solvent-free mechanochemical preparation of phosphonium salts, phosphorus ylides, and olefins 失效

    公开(公告)号：US06730812B2

    公开(公告)日：2004-05-04

    申请号：US10358552

    申请日：2003-02-05

    申请人： Vitalij K. Pecharsky ,  Viktor P. Balema ,  Jerzy W. Wiench ,  Marek Pruski

    发明人： Vitalij K. Pecharsky ,  Viktor P. Balema ,  Jerzy W. Wiench ,  Marek Pruski

    IPC分类号： C07F954

    CPC分类号： C07C17/2635 ,  C07C1/34 ,  C07F9/5352 ,  C07F9/54 ,  C07C25/24

    摘要： The present invention provides a method of preparing a phosphonium salt of the formula [R1R2R3P—CR4R5R6]X, comprising ball-milling a phosphine of the formula R1R2R3P with a compound of the formula XCR4R5R6; a method of preparing a phosphorus ylide of the formula R1R2R3P═CR4R5, comprising ball-milling a phosphonium salt of the formula [R1R2R3P—HCR4R5]X in the presence of a base; and a method of preparing an olefin of the formula R4R5C═CR7H or R4R5C═CR7R8, comprising ball-milling a phosphorus ylide of the formula R1R2R3P═CR4R5 with a compound of the formula R7C(O)H or R7C(O)R8. The inventive method produces phosphonium salts and phosphorus ylides by mechanical processing solid reagents under solvent-free conditions. The advantages of the present invention over conventional solution methods, include: (1) extremely high selectivity; (2) high yields; (3) low processing temperatures; (4) simple and scalable reactions using commercially available equipment; and (5) the complete elimination of solvents from the reaction.

    Method for producing phosphonium phenolates
    5.
    发明授权
    Method for producing phosphonium phenolates 有权
    苯酚酚盐生产方法

    公开(公告)号：US06476273B2

    公开(公告)日：2002-11-05

    申请号：US09446475

    申请日：1999-12-21

    申请人： Annett König ,  Lothar Bunzel ,  Uwe Hucks

    发明人： Annett König ,  Lothar Bunzel ,  Uwe Hucks

    IPC分类号： C07F954

    CPC分类号： C07F9/54 ,  C07C37/00 ,  C07C39/04

    摘要： A process for preparing phosphonium phenolate is disclosed. The process entails a reaction of phosphonium halide with phenol in an aqueous alkaline solution at a temperature of 0 to 55° C. The molar ratio of phenol to phosphonium halide is between 2:1 to 10:1 and the pH of the solution is 9.5 to 11. An optional embodiment entails carrying out the reaction in the further presence of alcohol.

    摘要翻译： 公开了一种制备酚酞的方法。 该方法需要在0至55℃的温度下在碱性水溶液中将卤化鏻与酚反应。苯酚与卤化鏻的摩尔比为2:1至10:1，溶液的pH为9.5 任选的实施方案需要在醇的进一步存在下进行反应。

    Process for the purification of phosphonium salts
    6.
    发明授权
    Process for the purification of phosphonium salts 失效

    公开(公告)号：US06630605B2

    公开(公告)日：2003-10-07

    申请号：US10161682

    申请日：2002-06-05

    申请人： Christoph Wegner ,  Daniela Klein

    发明人： Christoph Wegner ,  Daniela Klein

    IPC分类号： C07F954

    CPC分类号： C07F9/5428 ,  C07F9/025 ,  C07F9/5435

    摘要： The invention relates to a process for the purification of phosphonium salts in which a solution of the crude phosphonium salt is passed over a bed of a cation exchange resin in salt form or of an adsorber resin, the resin is washed with a polar protic solvent in the case of the cation exchange resin and with an electrolyte solution and a nonpolar solvent in the case of the adsorber resin, and the phosphonium salt is eluted from the cation exchange resin with an electrolyte solution or from the adsorber resin with a polar solvent.

    Process for preparing phosphonium salts
    9.
    发明授权
    Process for preparing phosphonium salts 失效
    鏻盐的制备方法

    公开(公告)号：US06423873B1

    公开(公告)日：2002-07-23

    申请号：US09791574

    申请日：2001-02-26

    申请人： Christoph Wegner ,  Michael John

    发明人： Christoph Wegner ,  Michael John

    IPC分类号： C07F954

    CPC分类号： C07F9/5428

    摘要： A process for preparing phosphonium salts of the general formula I in which the substituents have the following meanings, independently of one another: R aryl; X anion of an organic or inorganic acid selected from the group consisting of hydrohalic acids, sulfuric acid, sulfonic acids, phosphoric acid and C1-C6-alkanoic acids, by reacting 3,7,11-trimethyldodeca-1,4,6,10-tetraen-3-ol of the formula II with triarylphosphane and organic or inorganic acids selected from the abovementioned group, wherein in a two-stage process a) initially a tertiary phosphonium salt of the formula III  in which the radicals R and X have the abovementioned meanings, is prepared at temperatures in the range from −20 to 40° C., and b) the tertiary phosphonium salt of the formula III which is formed is rearranged to the primary phosphonium salt of the formula I at temperatures in the range from 40 to 100° C.

    摘要翻译： 一种制备通式Iin的鏻盐的方法，其中取代基具有以下含义：R芳基;选自以下的有机或无机酸的X阴离子：氢卤酸，硫酸，磺酸， 磷酸和C 1 -C 6链烷酸，通过使式II的3,7,11-三甲基十二碳-1,4,6,10-四烯-3-醇与三芳基膦和选自上述基团的有机或无机酸反应，其中 在两步法中）最初在-20至40℃的温度范围内制备其中基团R和X具有上述含义的式III的叔鏻盐，和b）叔鏻盐 所形成的式III的化合物在40至100℃的温度下重排成式I的主要鏻盐。

    Mordants for ink-jet receptors and the like
    10.
    发明授权
    Mordants for ink-jet receptors and the like 失效
    用于喷墨受体的媒染剂等

    公开(公告)号：US06211304B1

    公开(公告)日：2001-04-03

    申请号：US08521545

    申请日：1995-08-30

    申请人： Omar Farooq

    发明人： Omar Farooq

    IPC分类号： C07F954

    CPC分类号： G03C8/56 ,  B41M5/5245 ,  C08G65/33306 ,  C08G65/335 ,  G03C1/835

    摘要： Novel mordants based upon a poly(alkylene oxide) backbone and either pendant phosphonium or quaternized-nitrogen compounds are disclosed. The mordants find use in stopping or controlling ink-bleeding in ink-jet receptors and photographic films.

    摘要翻译： 公开了基于聚（环氧烷）骨架和侧鏻或季铵化合物的新型媒染剂。 媒染剂用于停止或控制喷墨受体和摄影胶片中的墨水渗出。