公开(公告)号：US06552157B2

公开(公告)日：2003-04-22

申请号：US09730080

申请日：2000-12-05

申请人： Charles A. Gambino ,  Karen M. Henderson ,  Patricia B. Jacobs ,  Sze-Ming Lee ,  Robert A. Sylvester

发明人： Charles A. Gambino ,  Karen M. Henderson ,  Patricia B. Jacobs ,  Sze-Ming Lee ,  Robert A. Sylvester

IPC分类号： C08G1832

CPC分类号： C08G18/3825 ,  C09D175/12 ,  Y10T428/31551

摘要： The present invention relates to polyurethanes containing secondary amide groups in the backbones of the polyurethanes, wherein the secondary amide groups (calculated as NH—CO—, MW 43) are present in an amount of 1 to 14% by weight, based on the weight of the polyurethanes, and correspond to the formula —X1—R1—NH—C(O)—R2—X2—  (I) wherein X1 and X2 are the same or different and represent the groups obtained by removing a hydrogen atom from a hydroxy group or a primary or secondary amino group and R1 and R2 are the same or different and represent linear or branched hydrocarbon groups that are optionally substituted by groups that do not contain isocyanate-reactive hydrogen atoms. The present invention also relates to one-component, thermoset compositions containing the polyurethanes with secondary amide groups in the backbone and a cross-linking component that is reactive with amide groups. Finally, the present invention relates to coatings, sealants and adhesives prepared from these one-component, thermoset compositions.

摘要翻译： 本发明涉及在聚氨酯的主链中含有仲酰胺基团的聚氨酯，其中仲酰胺基团（以NH-CO-，MW 43计算）的存在量为基于重量的1至14重量％ 的氨基甲酸酯，并且对应于肟基X 1和X 2相同或不同，表示通过从羟基或伯或仲氨基除去氢原子获得的基团，R 1和R 2相同或不同，表示直链或支链 任选被不含有异氰酸酯反应性氢原子的基团取代的烃基。本发明还涉及含有在主链中具有仲酰胺基团的聚氨酯和含有异氰酸酯反应性氢原子的反应性的交联组分的单组分热固性组合物 酰胺基。 最后，本发明涉及由这些单组分热固性组合物制备的涂料，密封剂和粘合剂。

公开(公告)号：US06455605B1

公开(公告)日：2002-09-24

申请号：US09841382

申请日：2001-04-24

申请人： Albert M. Giorgini ,  James A. Hagquist

发明人： Albert M. Giorgini ,  James A. Hagquist

IPC分类号： C08G1832

CPC分类号： C08G18/36 ,  C08G2101/005 ,  Y10S521/902

摘要： The invention relates to a foamable composition comprising at least two parts. The first part comprises a polyol, a thixotropic gelling agent, a blowing agent, a urethane reaction catalyst and a isocyanurate reaction catalyst. The second part comprises at least one isocyanate. A foam mass can be prepared by combining the first part polyol component with the second part isocyanate component. The composition is foamable under water and exhibits, upon foaming under water, substantially the same wet foam density and dry foam density. The invention also relates to a method of repairing or reinforcing structural members having defects such as spike holes left after spike removal from railroad ties during road bed maintenance or repair by means of the foamable composition.

摘要翻译： 本发明涉及包含至少两个部分的可发泡组合物。 第一部分包括多元醇，触变胶凝剂，发泡剂，氨基甲酸酯反应催化剂和异氰脲酸酯反应催化剂。 第二部分包含至少一种异氰酸酯。 可以通过将第一部分多元醇组分与第二部分异氰酸酯组分组合来制备泡沫体。 组合物在水下可发泡，并且在水下发泡时表现出基本相同的湿泡沫密度和干泡沫密度。 本发明还涉及一种修复或加强具有缺陷的结构构件的方法，例如在通过可发泡组合物的道路床维护或修复过程中从铁路连接件上取出尖钉之后留下的钉孔。

公开(公告)号：US06365697B1

公开(公告)日：2002-04-02

申请号：US09068009

申请日：1998-04-29

申请人： Son Nguyen Kim ,  Karin Sperling

发明人： Son Nguyen Kim ,  Karin Sperling

IPC分类号： C08G1832

CPC分类号： C08G18/61 ,  A61K8/87 ,  A61K47/34 ,  A61Q5/06 ,  C08G18/0819 ,  C08G18/12 ,  C08L75/04 ,  C08G18/285 ,  C08G18/288 ,  C08L83/00

摘要： The present invention relates to water-soluble or water-dispersible polyurethanes of a water-dispersible polyurethane prepolymer having terminal isocyanate groups and a primary or secondary amine having at least one ionogenic or ionic group, and to the salts thereof. The novel polyurethanes can be used as auxiliaries in cosmetology and pharmacy and, in particular, as hair lacquers having enhanced ease of washoff.

摘要翻译： 本发明涉及具有末端异氰酸酯基团的水分散性聚氨酯预聚物和具有至少一种离子基团或离子基团的伯胺或仲胺的水溶性或水分散性聚氨酯及其盐。 新型聚氨酯可用作美容和药学的辅助材料，特别是作为具有增强的易洗涤性的发胶。

公开(公告)号：US06245876B1

公开(公告)日：2001-06-12

申请号：US09380280

申请日：1999-08-27

申请人： Hiroyuki Hanahata ,  Yoshihiko Shimaya

发明人： Hiroyuki Hanahata ,  Yoshihiko Shimaya

IPC分类号： C08G1832

CPC分类号： C08J5/18 ,  C08J2375/02 ,  D01F6/70

摘要： The present invention relates to a continuous shaped article such as a polyurethaneurea fiber and a polyurethaneurea film having a birefringence index (&Dgr;n) of from at least 1.0×10−4 to 8.0×10−4 in a nontensile state, a crosslinking density at an elongation of 100% (N100) of at least 5.0×1026/m3, a crosslinking point density at an elongation of 400% (N400) of from 4.0×1026 to 3.0×1027/m3, and a crosslinking point density at the time of breakage (Nt) of at least 1.6×1027/m3, wherein the ratio of the crosslinking density at an elongation of 400% to that at an elongation of 100% (N400/N100) is from 0.9 to 1.3, and a process for producing the same. The present invention has made the continuous shaped article show an initial stress, a strength at break and an elongation at break which are sufficiently high, and a small rise in the stress in the medium elongation range.

摘要翻译： 本发明涉及连续成型制品如聚氨酯脲纤维和聚氨酯脲膜，其双折射指数（DELTAn）为非拉伸状态下至少为1.0×10 -4至8.0×10 -4，伸长时的交联密度为 100％（N100）为至少5.0×1026 / m3，伸长率为400％（N400）的交联点密度为4.0×1026〜3.0×1027 / m3，断裂时的交联点密度（Nt）为 至少1.6×10 27 / m 3，其中伸长率为400％时的交联密度与伸长率100％（N400 / N100）的交联密度的比为0.9〜1.3，以及其制造方法。 本发明使得连续成形制品显示足够高的初始应力，断裂强度和断裂伸长率，以及介质伸长范围内的应力的小的上升。

公开(公告)号：US06462162B2

公开(公告)日：2002-10-08

申请号：US09123930

申请日：1998-07-28

申请人： William Peter Van Antwerp ,  Christian C. Decker ,  John J. Mastrototoro

发明人： William Peter Van Antwerp ,  Christian C. Decker ,  John J. Mastrototoro

IPC分类号： C08G1832

CPC分类号： A61B5/14865 ,  A61B5/14532 ,  A61B5/411 ,  C08G18/4833 ,  C08G18/61 ,  C08G18/6674 ,  C08G77/458 ,  C08J5/2287 ,  C08J2323/06 ,  C12Q1/002 ,  C12Q1/006 ,  Y10T428/31551

摘要： Methods for reducing the electrode impedance of implantable biosensors by coating the surface of the biosensor with a uniform hydrogel which allows unimpeded water movement around the sensor are provided. The surface coatings are compositions which are biocompatible and are capable of water uptake of at least 120% of their weight, more preferably at least 200% of their weight. Upon the uptake of water, the hydrogels used in the present invention will also swell and provide a layer of water around the electrodes to which the hydrogels are attached. The hydrogels can be prepared from (a) a diisocyanate, (b) a hydrophilic polymer which is a hydrophilic diol, a hydrophilic diamine, or a combination thereof, and optionally, (c) a chain extender.

摘要翻译： 提供了通过用均匀的水凝胶涂覆生物传感器的表面来减少植入式生物传感器的电极阻抗的方法，其允许围绕传感器的不受阻碍的水移动。 表面涂层是生物相容性并且能够吸收其重量的至少120％，更优选至少其重量的200％的组合物。 在吸收水时，本发明中使用的水凝胶也将溶胀并在水凝胶附着的电极周围提供一层水。 水凝胶可以由（a）二异氰酸酯，（b）亲水性聚合物，亲水性二醇，亲水二胺或其组合，和任选的（c）扩链剂制备。

公开(公告)号：US06458866B1

公开(公告)日：2002-10-01

申请号：US09051351

申请日：1998-05-15

申请人： Wilhelm Oppermann ,  Frank Hermanutz ,  Peter Hirt ,  Michael Schweizer ,  Oliver Oess

发明人： Wilhelm Oppermann ,  Frank Hermanutz ,  Peter Hirt ,  Michael Schweizer ,  Oliver Oess

IPC分类号： C08G1832

CPC分类号： D01F6/70 ,  C08G18/675 ,  C08G18/676 ,  C08G18/678 ,  C08G18/679 ,  Y10S528/906

摘要： The invention concerns a polyurethane elastomer containing structural units of type (a), in which: the group —O—R1—O—is a macrodiol group with a molecular weight of approximately 500 to 10000, R2 is a bivalent aliphatic, cycloaliphatic and/or aliphatic-cycloaliphatic group; and X is a short-chain olefinically unsaturated group, Y is NH or O, n is an integer from 1 to 10 and m is an integer of at least 4. The invention also concerns a method of preparing this polyurethane elastomer which can be melt-spun to form fibres or melt-extruded to form foils. The fibres or foils can be exposed to energy-rich radiation such that crosslinking of the polyurethane occurs. Fibres according to the invention display superior properties in terms of textile-mechanical properties, in particular good tensile strength, elongation at tear, residual elongation and heat distortion temperature.

摘要翻译： 本发明涉及含有（a）型结构单元的聚氨酯弹性体，其中：-O-R 1 -O-为分子量约500〜10000的大二醇基，R2为二价脂族，脂环族和/ 或脂肪族 - 脂环族基团; X为短链烯属不饱和基团，Y为NH或O，n为1〜10的整数，m为4以上的整数。本发明还涉及制备该聚氨酯弹性体的方法，该聚氨酯弹性体可熔融 - 纺成纤维或熔融挤出以形成箔。 纤维或箔可以暴露于能量丰富的辐射，从而发生聚氨酯的交联。 根据本发明的纤维在纺织 - 机械性能，特别是良好的拉伸强度，撕裂伸长率，残余伸长率和热变形温度方面表现出优异的性能。

公开(公告)号：US06451931B1

公开(公告)日：2002-09-17

申请号：US09750129

申请日：2000-12-29

申请人： Akio Ogawa ,  Manabu Abe

发明人： Akio Ogawa ,  Manabu Abe

IPC分类号： C08G1832

CPC分类号： C08G59/4057 ,  C08G18/3225 ,  C08G59/184 ,  C08G59/4014

摘要： A curing agent composition for an epoxy resin which comprises (B) a reaction product obtained from (a) an amine compound represented by formula (I): wherein R1 and R2 each represent an alkyl group having 1 to 8 carbon atoms, of R1 and R2 are connected together to form an alkylene group which may contain an oxygen atom or a nitrogen atom; and n represents 1 to 6, (b) a polyamine compound comprising a dicarboxylic acid dihydrazide, (c) an organic polyisocyanate, and, optionally; (d) an epoxy compound.

摘要翻译： 一种用于环氧树脂的固化剂组合物，其包含（B）由（a）由式（I）表示的胺化合物获得的反应产物：其中R 1和R 2各自表示具有1至8个碳原子的烷基，R 1和 R2连接在一起形成可以含有氧原子或氮原子的亚烷基; n表示1〜6，（b）含有二羧酸二酰肼的多胺化合物，（c）有机多异氰酸酯， （d）环氧化合物。

公开(公告)号：US06403752B1

公开(公告)日：2002-06-11

申请号：US09617766

申请日：2000-07-17

申请人： David W. House ,  Ray V. Scott, Jr.

发明人： David W. House ,  Ray V. Scott, Jr.

IPC分类号： C08G1832

CPC分类号： C09D175/02 ,  C08G18/10 ,  C08G18/3234 ,  C08G18/482 ,  C08G18/5024 ,  C08G18/6685

摘要： Certain secondary aliphatic diamines are excellent chain extenders in the formation of polyurethanes, polyurea-polyurethane hybrids, and polyurea polymers, both elastomers and coatings, from both monomeric polyisocyanates and isocyanate-terminated prepolymers using the high-pressure impingement mixing reaction technique. These diamines include 1,4-di(alkylamino)cyclohexanes, 1-methyl-2,4-di(alkylamino)-3,5-dialkylcyclohexanes, N,N′-dialkyl isophoronediamine, 1,3-di(1′methyl-1′-alkylaminoethyl)benzene, and 1,6-di(alkylamino)hexane. These chain extenders may be used alone or in combination with other polyamines and with polyols. A broad spectrum of polymeric materials can be formed with a range of diverse properties.

摘要翻译： 某些仲脂族二胺是使用高压冲击混合反应技术从单体多异氰酸酯和异氰酸酯封端的预聚物形成聚氨酯，聚脲 - 聚氨酯混合物和聚脲聚合物，弹性体和涂层的优异的增链剂。 这些二胺包括1,4-二（烷基氨基）环己烷，1-甲基-2,4-二（烷基氨基）-3,5-二烷基环己烷，N，N'-二烷基异佛尔酮二胺，1,3-二（1' 1'-烷基氨基乙基）苯和1,6-二（烷基氨基）己烷。 这些扩链剂可以单独使用或与其它多胺和多元醇组合使用。 可以形成广泛的聚合物材料，具有多种不同的性质。

公开(公告)号：US06258918B1

公开(公告)日：2001-07-10

申请号：US09064490

申请日：1998-04-22

申请人： Chia-Tie Ho ,  Clarence Fullbright, Jr.

发明人： Chia-Tie Ho ,  Clarence Fullbright, Jr.

IPC分类号： C08G1832

CPC分类号： B32B27/40 ,  B32B7/12 ,  C08G18/32 ,  C08G18/4202 ,  C09D175/06 ,  Y10T428/31551

摘要： The present invention provides a flexible two component polyurethane and method for producing the polyurethane. The cured polyurethane is flexible, durable and weather resistant. The polyurethane is suitable for use as a protective layer on various substrates. The flexible polyurethane is the reaction product of solvent-free reaction components. The first component includes one or more polyols, optionally, one or more diols, and a catalyst. The second component includes a primary aliphatic isocyante crosslinker.

摘要翻译： 本发明提供了柔性双组分聚氨酯和聚氨酯的制造方法。 固化的聚氨酯具有柔韧性，耐用性和耐候性。 聚氨酯适用于各种基材上的保护层。 柔性聚氨酯是无溶剂反应组分的反应产物。 第一组分包括一种或多种多元醇，任选的一种或多种二醇和催化剂。 第二组分包括伯脂肪族异氰酸酯交联剂。

公开(公告)号：US06180745B2

公开(公告)日：2001-01-30

申请号：US09436328

申请日：1999-11-08

申请人： Richard R. Roesler

发明人： Richard R. Roesler

IPC分类号： C08G1832

CPC分类号： C08G18/7837 ,  C08G18/307 ,  C08G18/3821 ,  C08G18/792 ,  C09K3/10

摘要： The present invention relates to moisture-curable compositions which have a) a content of (cyclo)aliphatically-bound isocyanate groups (calculated as NCO, MW 42) of 0.2 to 22% by weight and b) a content of succinyl urea groups (calculated as —NH—CO—N—, MW 57) of 0.1 to 14% by weight, and c) an equivalent ratio of (cyclo)aliphatically-bound isocyanate groups to succinyl urea groups of 4:1 to 1:1, wherein the preceding percentages are based on resin solids content of the moisture-curable compositions. The present invention also relates to coating, adhesive or sealing compositions containing these moisture-curable compounds as the binder.

摘要翻译： 本发明涉及可湿固化的组合物，其具有（a）含量（环）脂族结合的异氰酸酯基团（以NCO计，MW 42计）为0.2至22重量％，和b）琥珀酰脲基团的含量（以 - NH-CO-N-，MW 57）为0.1〜14重量％，c）（环）脂族连接的异氰酸酯基团与琥珀酰脲基团的当量比为4:1至1:1，其中前述百分比为 基于水分可固化组合物的树脂固体含量。本发明还涉及包含这些可湿气固化的化合物作为粘合剂的涂料，粘合剂或密封组合物。