Use of crosslinked copolymers of monoethylenically unsaturated carboxylic acids as stabilizer in oil-in-water emulsions
    1.
    发明授权
    Use of crosslinked copolymers of monoethylenically unsaturated carboxylic acids as stabilizer in oil-in-water emulsions 失效
    在水包油乳液中使用单烯属不饱和羧酸的交联共聚物作为稳定剂

    公开(公告)号:US06528575B1

    公开(公告)日:2003-03-04

    申请号:US08578706

    申请日:1995-12-28

    Abstract: The use of crosslinked copolymers obtainable by precipitation polymerization of monomer mixtures comprising (a) monoethylenically unsaturated C3-C8-carboxylic acids, their anhydrides or mixtures of said carboxylic acids and anhydrides, (b) compounds with at least 2 non-conjugated ethylenic double bonds in the molecule as crosslinkers and, where appropriate, (c) other monoethylenically unsaturated monomers which are copolymerizable with monomers (a) and (b), in the presence of free-radical polymerization initiators and from 0.1 to 20% by weight, based on the monomers used, of saturated, nonionic surface-active compounds, as stabilizer in oil-in-water emulsions in amounts of from 0.01 to 5% of the weight of the emulsions, and cosmetic and pharmaceutical formulations based on oil-in-water emulsions which contain said precipitation polymers.

    Abstract translation: 使用可通过单体混合物的沉淀聚合获得的交联共聚物,其包含(a)单烯属不饱和C 3 -C 8 - 羧酸,其酸酐或所述羧酸和酸酐的混合物,(b)具有至少2个非共轭烯键双键的化合物 在分子中作为交联剂,并且在适当的情况下,(c)可以在自由基聚合引发剂存在下与单体(a)和(b)共聚的其它单烯属不饱和单体和基于 饱和的非离子表面活性化合物所使用的单体作为水包油乳液中稳定剂的量为乳剂重量的0.01至5%,以及基于水包油乳液的化妆品和药物制剂 其含有所述沉淀聚合物。

    Cosmetic compositions comprising sulfonate groups containing polyamides
    4.
    发明授权
    Cosmetic compositions comprising sulfonate groups containing polyamides 失效
    包含含有聚酰胺的磺酸酯基的化妆品组合物

    公开(公告)号:US6036962A

    公开(公告)日:2000-03-14

    申请号:US790734

    申请日:1997-01-27

    CPC classification number: A61Q5/06 A61K8/88 A61Q19/00 A61Q3/02

    Abstract: The present invention relates to the use of polyamides in cosmetics which carry sulfonate groups and are obtainable fromA.sub.1) from 0 to 19.9 mol-% of at least one monoaminocarboxylic acid having 2 to 12 carbon atoms, its lactam, or monoaminocarboxylic acid/lactam mixtures,A.sub.2) from 40.05 to 50 mol-% of at least one diamine having 2 to 18 carbon atoms,A.sub.3) from 0.5 to 49.5 mol-% of at least one dicarboxylic acid having 4 to 12 carbon atoms which carries sulfonate groups, andA.sub.4) from 0.5 to 49.5 mol-% of at least one further dicarboxylic acid having 2 to 16 carbon atoms, and cosmetic compositions containing said polyamides.

    Abstract translation: 本发明涉及在具有磺酸盐基团的化妆品中使用聚酰胺,并且可从A1至0.9.9摩尔%的至少一种具有2至12个碳原子的单氨基羧酸,其内酰胺或单氨基羧酸/内酰胺混合物 ,A2)从40.05至50mol%的至少一个具有2至18个碳原子的二胺,A3)0.5至49.5mol%的至少一种带有磺酸根基团的具有4至12个碳原子的二羧酸,以及A4 )0.5至49.5mol%的至少一种其它具有2至16个碳原子的二羧酸,以及含有所述聚酰胺的化妆品组合物。

    Copolymers of carboxylic acids and multiply olefinically unsaturated
carboxylic acid derivatives and their use as thickeners and dispergents
    5.
    发明授权
    Copolymers of carboxylic acids and multiply olefinically unsaturated carboxylic acid derivatives and their use as thickeners and dispergents 失效
    羧酸和多烯属不饱和羧酸衍生物的共聚物及其作为增稠剂和分散剂的用途

    公开(公告)号:US6015551A

    公开(公告)日:2000-01-18

    申请号:US77598

    申请日:1998-06-02

    CPC classification number: A61K8/8152 A61Q19/00 B01F17/00 C08F220/04 C08F222/00

    Abstract: The disclosure relates to a copolymer obtainable by radically initiated polymerization of the following: A) 70-99.9 wt. % an olefinically unsaturated C.sub.3 -C.sub.5 monocarboxylic acid, an olefinically unsaturated C.sub.4 -C.sub.8 dicarboxylic acid or its anhydride, or a mixture of such carboxylic acids; with B) 0.1-30 wt. % one or more multiply olefinically unsaturated carboxylic acid derivatives of formula (I)Z--Y--(CHR.sup.3 --CH.sub.2 --X).sub.n --R.sup.4 (I)in which Z is a vinyl or allyl group or structure (a), ##STR1## R.sup.1, R.sup.2 are hydrogen or methyl, R.sup.3 is hydrogen, methyl or ethyl, R.sup.4 is a singly or multiply olefinically unsaturated alkenyl or cycloalkenyl group or a singly or doubly olefinically unsaturated arylalkylene group, X is oxygen or NH, Y is oxygen, NH or N-alkyl, n is a number between 0 and 50; and C) 0-29.9 wt. % other copolymerizable monomers. The proposed copolymer can be used as a thickener or dispergent for aqueous systems.

    Abstract translation: PCT No.PCT / EP96 / 05522 Sec。 371日期1998年6月2日 102(e)1998年6月2日PCT 1996年12月11日PCT PCT。 出版物WO97 / 21744 日期:1997年6月19日本公开内容涉及通过以下方式的自由基引发聚合获得的共聚物:A)70-99.9wt。 %烯属不饱和C3-C5一元羧酸,烯属不饱和C4-C8二羧酸或其酸酐,或这些羧酸的混合物; B)0.1-30wt。 %的一种或多种式(I)ZY-(CHR 3 -CH 2 -X)n -R 4(I)的多烯属不饱和羧酸衍生物,其中Z是乙烯基或烯丙基或结构(a),R 1,R 2是氢 或甲基,R3是氢,甲基或乙基,R4是单或多烯属不饱和烯基或环烯基或单或双烯属不饱和芳基亚烷基,X是氧或NH,Y是氧,NH或N-烷基,n 是0到50之间的数字; 和C)0-29.9wt。 %其他可共聚单体。 所提出的共聚物可用作水性体系的增稠剂或分散体。

    Hair setting composition
    6.
    发明授权
    Hair setting composition 失效
    头发定型组成

    公开(公告)号:US5306484A

    公开(公告)日:1994-04-26

    申请号:US874203

    申请日:1992-04-27

    CPC classification number: A61K8/046 A61K8/8152 A61Q5/06

    Abstract: Hair setting composition containing as film formers copolymers based on tert-butyl acrylate and/or tert-butyl methacrylate, having a K value of from 10 to 50 and obtainable by free radical polymerization ofA) from 75 to 99% by weight of tert-butyl acrylate and/or tert-butyl methacrylate,B) from 1 to 25% by weight of acrylic acid and/or methacrylic acid andC) from 0 to 10% by weight of a further free radical copolymerizable monomer,the carboxyl groups of the copolymers having been partly or wholly neutralized by amines.

    Abstract translation: 含有作为成膜剂的基于丙烯酸叔丁酯和/或甲基丙烯酸叔丁酯的共聚物的固化组合物,其K值为10至50,可通过A)的75至99重量%的叔 - 丙烯酸丁酯和/或甲基丙烯酸叔丁酯,B)1至25重量%的丙烯酸和/或甲基丙烯酸,和C)0至10重量%的另外的自由基可共聚单体, 已经被胺部分或全部中和的共聚物。

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