摘要:
A solution composition, particularly useful for the manufacture of flexible polyether urethane foam, is provided comprising water, a hydrolytically stable siloxane-oxyalkylene block copolymer, an amine polyurethane-foaming catalyst and a water soluble, silicon-free organic surfactant which is capable of raising the cloud point of the solution. Suitable organic surfactants include those having the general formula, C9H19C6H4(OC2H4)eOH, wherein e represents any number from about 9 to about 20 inclusive. The compositions may also contain water soluble organic solvents. The presence of the organic surfactant serves to protect the solution from physical separation when subjected to adverse temperature conditions which may be encountered during shipment or storage. A process for the manufacture of polyurethane foam is also provided in which the foam-forming reaction mixture comprises a polyether polyol, a polyisocyanate and the aforesaid solution composition.
摘要翻译:提供特别可用于制造柔性聚醚聚氨酯泡沫的溶液组合物,其包含水,水解稳定的硅氧烷 - 氧化烯嵌段共聚物,胺聚氨酯发泡催化剂和能够提高的水溶性无硅有机表面活性剂 云点的解决方案。 合适的有机表面活性剂包括具有通式C 9 H 19 C 6 H 4(OC 2 H 4)e OH的那些,其中e表示约9至约20的数值。 组合物还可以含有水溶性有机溶剂。 有机表面活性剂的存在用于在经受在运输或储存期间可能遇到的不利温度条件时保护溶液免于物理分离。 还提供了制造聚氨酯泡沫的方法,其中泡沫形成反应混合物包含聚醚多元醇,多异氰酸酯和上述溶液组合物。
摘要:
A MODIFIED POLYESTER RESIN COATING FOR MAGNET WIRE OR THE LIKE MADE BY REACTING (A) TEREPHTHALIC, ISOPHTHALIC ACID OR DIMETHYL ESTERS THEREOF, (B) A POLYHYDRIC ALCOHOL, AND (C) A SILANE OR A LOW MOLECULAR WEIGHT, PARTIALLY CONDENSED, PHENYL, METHYL, METHYL ALKYL OR PHENYLMETHYL POLYSILOXANE CONTAINING AT LEAST ONE REACTIVE OH GROUP BONDED TO THE SILICON ATOM. THE SILICON CONTAINING COMPOUNDS REACTS WITH THE (A) COMPONENT, OR IF IT CONTAINS A REACTIVE COOH GROUP, WITH THE (B) COMPONENT. THESE POLYESTER RESINS ARE CHARACTERIZED BY A REMARKABLY LOW COEFFICIENTS OF FRICTION AND MAY BE USED AS A WIRE "ENAMEL" WITH OR WITHOUT AN OVERCOAT.
摘要:
HYDROXYLATED COPOLYMERS OF (C6H5)2SIO UNITS AND CH3SIO1.5 UNITS ARE DISCLOSED. THE DIPHENYLSILOXANE UNITS ARE PRESENT IN AN AMOUNT OF 20 TO 50 MOL PERCENT AND ARE BONDED TO MONOMETHYLSILOXANE UNITS WHICH CONTAIN THE HYDROXYL GROUPS. ALSO DISCLOSED ARE THE ABOVE HYDROXYLATED COPOLYMERS MODIFIED BY LINKING SEGMENTS OF
-O-SI(-R2)-(O-SI(-R2))X-O-SI(-R2)-O-
WHERE X IS AT LEAST 2 AND R IS METHYL, PHENL OF 3,3,3TRIFLUOROPROPYL AND THE SEGMENTS ARE PRESENT IN AMOUNTS OF 1 TO 50 WEIGHT PERCENT. THE HYDROXYLATED COPOLYMERS AND THE MODIFIED HYDROXYLATED COPOLYMERS ARE RESINS USEFUL IN PROTECTIVE COATINGS, LAMINATES, RELEASE COATINGS AND MOLDING RESINS.
摘要:
Acetoxymonomethylsiloxane-diphenylsiloxane copolymers of CH3SiO1.5 units, (C6H5)2SiO units and WHERE THE (C6H5)2SiO units are bonded to CH3SiO1.5 units or 15 TO 46 WEIGHT PERCENT OF THE COPOLYMER IS AND 20 TO 50 MOL PERCENT OF THE SILOXANE UNITS ARE (C6H5)2SiO units is disclosed. Also disclosed are modified acetoxymonomethylsiloxane-diphenylsiloxane copolymers wherein molecules of the copolymer are linked together by segments of the formula WHEREIN X IS AT LEAST 2 AND R is methyl, phenyl or 3,3,3trifluoropropyl and the segments being present in amounts of 1 to 50 weight percent. The copolymers and modified copolymers are useful as cross-linkers, intermediates and laminating resins.
摘要:
A composition useful as a coupling agent for promoting the adhesion of a cured organopolysiloxane release agent to a cellulosic substrate is the reaction product of WHERE R is a divalent or trivalent radical of carbon and hydrogen, R'' is a lower alkyl, n is 1 to 2 and R'''' is a monovalent hydrocarbon radical. An example is a reaction product of AND VINYLTRIACETOXYSILANE.
摘要:
AROMATIC SILICON-CONTAINING POLYOXADIAZOLES THAT ARE SOLUBLE IN ORGANIC SOLVENTS AND ARE OXIDATION RESISTANT AND GENERALLY STABLE UP TO ABOUT 400*C. THE POLYOXADIAZOLE POLY(1,4-PHENYLENE(DIPHENYLSILYL)-1,4-PHENYLENE-2,5(1,3,4-OXADIAZOLE)) PREPARED BY THERMAL CYCLODEHYDRATION OF THE POLYHYDRAZIDE OBTAINED BY COPOLYMERIZATION OF BIS(P-CHLOROCARBONYLPHENYL)DIPHENYLSILANE OR BIS(P-CARBOPENTACHLOROPHENOXYPHENYL)DIPHENYLSILANE WITH EITHER HYDRAZINE OR BIS(P-CARBONHYDRAZIDOPHENYL)DIPHENYLSILANE. OTHER POLYHDRAZIDE PREPOLYMERS ARE OBTAINED BY COPOLYMERIZATION OF BIS(P-CARBOHYDRAZIDOPHENYL)DIPHENYLSILANE WITH DIPENTACHLOROPHENYL TEREPHTHALATE OR DIPENTACHLOROPHENYL ISOPHTHALATE WHICH YIELD POLY(N-(P-DIPHENYLSILYLBENZOYL)-N,N"-(TEREPHTHALOYL)-N''"-(P-BENZOYL) DIHYDRAZIDE) AND POLY(N-(P-DIPHENYLSILYLBENZOYL)-N,N"(ISOPHTHALOYL)-N''"-(P -BENZOYL)DIHYDRAZIDE), RESPECTIVELY. THESE POLYHDRAZIDE PREPOLYMES CONVERT BY THERMAL CYCLODEHYDRATION INTO THE POLYOXADIAZOLES POLY(1,4-PHENYLENE(DIPHENYLSILYL)-1,4-PHENYLENE-(1,3,4-OXADIAZOLE2,5-DIYL) -1,4-PHENYLENE-2,5-(1,3,4-OXADIAZOLE)) AND POLY(1,4-PHENYLENE(DIPHENYLSILYL)-1,4-PHENYLENE(1,3,4-OXADIAZOLE-2,5-DIYL) -1,3-PHENYLENE-2,5(1,3,4-OXADIAZOLE)), RESPECTIVELY. THE PREVIOUSLY RECITED POLYOXADIAZOLE POLY(1,4-PHENYLENE(DIPHENYLSILYL)1,4-
PHENYLENE-2,5-(1,3,4-OXADIAZOLE)) IS SOMEWHAT MORE HEAT RESISTANT THAN THE OTHER OXADIAZOLES.