Method for preparing SiOC-linked polyether siloxanes branched in the siloxane part

    公开(公告)号:US11725017B2

    公开(公告)日:2023-08-15

    申请号:US16759413

    申请日:2018-08-15

    CPC classification number: C07F7/1892 C07F7/20 C08G77/06 C08G77/46 C08G77/08

    Abstract: Described is a process for producing SiOC-bonded polyether siloxanes branched in the siloxane portion from cyclic branched siloxanes of the D/T type, wherein said process comprises in a first step reacting the mixtures of cyclic branched siloxanes of the D/T type with acetic anhydride optionally in admixture with simple siloxane cycles under acid catalysis to afford acetoxy-bearing branched siloxanes, in a second step performing the equilibration of the acetoxy-modified branched siloxane with trifluoromethanesulfonic acid, preferably with addition of acetic acid, and in a third step reacting the trifluoromethanesulfonic acid-treated acetoxysiloxane with polyetherols optionally in the presence of bases and optionally in the presence of an inert solvent.

    Method for preparing aminopropylsilanes

    公开(公告)号:US11440926B2

    公开(公告)日:2022-09-13

    申请号:US16603329

    申请日:2018-02-06

    Abstract: Aminopropylalkoxysilanes of the formula H2N—CR2R3—CHR1—CH2—SiR4R5(OR6)  I, are synthesized by hydrosilylating silazanes of the formulae and mixtures thereof, in the presence of a catalyst containing rhodium and/or iridium compounds, and then reacted with alcohol to form an aminopropylalkoxysilane.

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