Copolyether composition and processes therefor and therewith
    2.
    发明授权
    Copolyether composition and processes therefor and therewith 失效
    共聚醚组合物及其工艺及其

    公开(公告)号:US06316586B1

    公开(公告)日:2001-11-13

    申请号:US09638356

    申请日:2000-08-15

    IPC分类号: C08G6366

    CPC分类号: C08G63/6886 C08G63/672

    摘要: A copolyether composition that can be used to produce a dyeable polyester is provided. The composition can comprise repeat units derived from a first diol such as, for example, 1,3-propanediol and a sulfonated dicarboxylic acid such as, for example, 5-sulfo-isophthalic acid. The dyeable polyester composition can comprise repeat units derived from the copolyether composition, an acid such as, for example, terephthalic acid, and a second diol such as, for example, 1,3-propanediol. Also disclosed is a process that can be used for producing the copolyether composition. The process comprises contacting the first diol with the sulfonated dicarboxylic acid. Further disclosed is a process that can be used for producing the dyeable composition in which the process comprises (1) contacting, in the presence of a catalyst, the copolyether composition with a diol such as, for example, 1,3-propanediol, and a dicarboxylic ester such as, for example, dimethylterephthalate or (2) contacting an acid such as for example, terephthalic acid and a diol such as, for example, 1,3-propanediol to produce an intermediate and thereafter contacting the intermediate with the copolyether.

    摘要翻译: 提供了可用于生产可染色聚酯的共聚醚组合物。 组合物可以包含衍生自第一二醇的重复单元,例如1,3-丙二醇和磺化二羧酸,例如5-磺基间苯二甲酸。 可染性聚酯组合物可以包含衍生自共聚醚组合物的重复单元,酸例如对苯二甲酸,和第二二醇,例如1,3-丙二醇。 还公开了可用于制备共聚醚组合物的方法。 该方法包括使第一二醇与磺化二羧酸接触。 进一步公开的是可用于生产可染组合物的方法,其中该方法包括(1)在催化剂存在下使共聚醚组合物与二醇例如1,3-丙二醇接触,和 二羧酸酯,例如对苯二甲酸二甲酯或(2)使酸例如对苯二甲酸与二醇例如1,3-丙二醇接触以制备中间体,然后使中间体与共聚醚接触 。

    Resin composite, method for producing the same and articles consisting of the same
    3.
    发明授权
    Resin composite, method for producing the same and articles consisting of the same 失效
    树脂复合材料,其制造方法和由其组成的制品

    公开(公告)号:US06828402B2

    公开(公告)日:2004-12-07

    申请号:US09976103

    申请日:2001-10-15

    申请人: Yoshihiko Kikuchi

    发明人: Yoshihiko Kikuchi

    IPC分类号: C08G6366

    摘要: A resin composite characterized in that it includes: a polymer compound which is an alternating copolymer of a saccharic compound and an aliphatic compound and has a three-dimensional network; and a plasticizer contained in the gap in the three-dimensional network of the above polymer compound, the production of the resin composite contributing to making good use of waste vegetable resources, such as used paper and waste molasses, as raw materials, the resin composite having elasticity and flexibility just as does rubber.

    摘要翻译: 一种树脂复合材料,其特征在于它包括:高分子化合物,其是糖化合物和脂族化合物的交替共聚物并具有三维网络; 和上述高分子化合物的三维网格间隙中含有的增塑剂,生产有助于利用废旧植物资源的废旧植物资源的树脂复合材料如废纸和废糖蜜作为原料,树脂复合物 具有弹性和弹性,就像橡胶一样。

    Water-soluble fiber and a method for manufacture thereof
    5.
    发明授权
    Water-soluble fiber and a method for manufacture thereof 失效
    水溶性纤维及其制造方法

    公开(公告)号:US06566485B1

    公开(公告)日:2003-05-20

    申请号:US09596668

    申请日:2000-06-19

    IPC分类号: C08G6366

    摘要: This invention relates to a water-soluble fiber and a method of manufacturing the fiber. The water-soluble fiber of the invention is composed of a high molecular compound with a weight average molecular weight of not less than 10,000, which high molecular compound is obtainable by reacting a polyalkylene oxide compound, which is obtainable by addition polymerization of an ethylene oxide-containing alkylene oxide and an organic compound containing two active hydrogen atoms, with a polycarboxylic acid, an anhydride thereof, a lower alkyl ester thereof, or a diisocyanate and is manufactured by spinning the same high molecular compound. The water-soluble fiber of the invention is not only high in elongation and tensile strength but is readily soluble in water.

    摘要翻译: 本发明涉及一种水溶性纤维及其制造方法。 本发明的水溶性纤维由重均分子量不小于10,000的高分子化合物构成,该高分子化合物可以通过使环氧乙烷的加成聚合得到的聚环氧烷化合物 含有两个活性氢原子的有机化合物与多元羧酸,其酸酐,低级烷基酯或二异氰酸酯反应,并通过纺丝相同的高分子化合物制备。 本发明的水溶性纤维不但伸长率高,拉伸强度高,而且易溶于水。

    Process for making pre-gels for a cross-linked branched polyester
    6.
    发明授权
    Process for making pre-gels for a cross-linked branched polyester 失效
    用于制备交联支化聚酯的预凝胶的方法

    公开(公告)号:US06444782B1

    公开(公告)日:2002-09-03

    申请号:US09563536

    申请日:2000-04-26

    申请人: Michael D. Hamlin

    发明人: Michael D. Hamlin

    IPC分类号: C08G6366

    摘要: The invention relates to a process for making a high molecular weight pre-gel for a cross-linked branched polyester comprising: a) reacting polyester precursor repeat units via condensation polymerization in a continuous or semi-continuous, or batch reactor stage to form a low molecular weight pre-gel; and b) further reacting the low molecular weight pre-gel via condensation polymerization in a continuous thin-film reactive vacuum processing stage to form a high molecular weight pre-gel.

    摘要翻译: 本发明涉及一种制备用于交联支链聚酯的高分子量预凝胶的方法,包括:a)通过缩聚在连续或半连续或间歇反应器阶段使聚酯前体重复单元反应以形成低 分子量预凝胶; 和b)在连续薄膜反应性真空处理阶段中通过缩聚进一步使低分子量预凝胶反应以形成高分子量预凝胶。

    Method of preparing modified polyester bottle resins
    7.
    发明授权
    Method of preparing modified polyester bottle resins 失效
    改性聚酯瓶树脂的制备方法

    公开(公告)号:US06335422B2

    公开(公告)日:2002-01-01

    申请号:US09851240

    申请日:2001-05-08

    IPC分类号: C08G6366

    摘要: The present invention is a method of preparing a high molecular weight copolyester bottle resin that has excellent melt processing characteristics. The method includes the steps of reacting a diacid or diester component and a diol component to form modified polyethylene terephthalate, wherein diol component is present in excess of stoichiometric proportions. Together, the diacid or diester component and the diol component must include at least 7 percent comonomer. The remainder of the diacid component is terephthalic acid or dimethyl terephthalate and the remainder of the diol component is ethylene glycol. The modified polyethylene terephthalate is copolymerized in the melt phase to an intrinsic viscosity of between about 0.25 dl/g and 0.40 dl/g to thereby form a copolyester prepolymer. Thereafter the copolyester prepolymer is polymerized in the solid phase to form a high molecular weight bottle resin that has an intrinsic viscosity of at least about 0.70 dl/g, and a solid phase density of less than 1.413 g/cc.

    摘要翻译: 本发明是制备具有优异的熔融加工特性的高分子量共聚酯瓶树脂的方法。 该方法包括使二酸或二酯组分和二醇组分反应形成改性聚对苯二甲酸乙二醇酯的步骤,其中二醇组分以超过化学计量比的量存在。 一起,二酸或二酯组分和二醇组分必须包含至少7%的共聚单体。 二酸组分的其余部分是对苯二甲酸或对苯二甲酸二甲酯,剩余的二醇组分是乙二醇。 改性聚对苯二甲酸乙二醇酯在熔融相中共聚至约0.25dl / g至0.40dl / g之间的特性粘度,从而形成共聚酯预聚物。 此后,共聚酯预聚物在固相中聚合以形成特性粘度为至少约0.70dl / g,固相密度小于1.413g / cc的高分子量瓶型树脂。

    Polyether polyol and a method for the manufacture of mouldable polyester containing said polyether polyol
    8.
    发明授权
    Polyether polyol and a method for the manufacture of mouldable polyester containing said polyether polyol 失效
    聚醚多元醇和制造含有所述聚醚多元醇的可成型聚酯的方法

    公开(公告)号:US06252037B1

    公开(公告)日:2001-06-26

    申请号:US09242935

    申请日:1999-02-26

    IPC分类号: C08G6366

    摘要: Polyether polyol having the following chemical formula (1): HO—(AO)mZO—(BO)n—H, which is suitable for the manufacture of polyester, polyurethane elastomer and polyurethane paint showing an excellent hydrolysis resistance is disclosed. In this formula, Z is a dimer diol residue; A and B are the same or different alkylene groups having 2-4 carbon atoms; and m and n are the same or different integers of 0 or more where 2≦(m+n)≦40. Also disclosed is a method for the manufacture of mouldable polyester containing the above-mentioned polyether polyol as one of the constituting units.

    摘要翻译: 公开了具有以下化学式(1)的聚醚多元醇:适用于制造具有优异耐水解性的聚酯,聚氨酯弹性体和聚氨酯涂料的HO-(AO)mZO-(BO)n -H。 在该式中,Z是二聚二醇残基; A和B是具有2-4个碳原子的相同或不同的亚烷基; 并且m和n是0或更大的相同或不同的整数,其中2 <=(m + n)<= 40。 还公开了制造含有上述聚醚多元醇作为构成单元之一的可成型聚酯的方法。