摘要:
The present invention provides a reactive dyestuff with an alkylthio group and a β-sulfatoethylsulfone group, which is represented by formula (I), wherein D, R, R1, R2, R3, R4, Q, x, and y are defined the same as the specification. The reactive dyestuffs of the present invention not only have characteristics of high solubility, high alkali solubility, and easily being washed off for dyeing cellulose fiber, but also are suitably applied in cold-pad-batch dyeing, continuous-dyeing, printing, and digital printing.
摘要:
An anionic coloring agent according to the following formula: CA—RSA. CA comprises at least a chromophore and RSA is a spacer-arm with the chemical structure: —X—R-Z. X is a chemical bond, —S(O)n, or —NR1, wherein R1 is hydrogen or a C1-C10 alkyl group; R is a C1-C10 alkylene group; Z is —NR2R3, wherein R2 and R3 are, independently hydrogen or a C1-C10 alkyl group. Alternatively, Z is —NR4—(CH2)m—W, wherein R4 is hydrogen, a hydroxy C1-C10 alkyl group, or C1-C10 alkyl group; m is an integer from 1 to 10; and W is —COOR5, wherein R5 is hydrogen, a C1-C10 alkyl group; or —CONR6R7. R6 and R7 are, independently, a hydrogen atom, a C1-C10 alkyl group, —SO3H; —S—SO3H; —CN: or SO3R8 wherein, R8 is hydrogen, a C1-C10 alkyl group, or —S—SO3R9 group, wherein, R9 is hydrogen atom, or a C1-C10 alkyl group; provided that when X is —NR1, and Z is —NR2R3, then R1, R2 and R3 cannot be simultaneously a hydrogen atom. The inclusion of spacer-arms in anionic coloring agents improves dye properties such as strength, tone and affinity.
摘要:
This invention relates to novel fibre-reactive formazan dyes of the formula (I): where the symbols are each as defined in claim 1, their preparation, their use for dyeing and printing hydroxyl-containing or nitrogenous organic substrates and substrates dyed or printed with these compounds.
摘要:
The invention concerns the use as direct dyeing agent of at least one tetraazapentamethine compound, a dyeing composition comprising at least such a compound, as well as a method for dyeing keratinous fibers, in particular human keratinous fibers and more particularly hair, which consists in applying at least one composition comprising such a compound. The composition also concerns tetra-azapentamethine compounds of formula (I). The invention further concerns a method for bleaching such compounds, as well as bleaching keratinous fibers previously dyed therewith.
摘要:
A family of 1:2 Fe-complexed formazan dyes is described. The dyes unexpectedly afford reddish-violet, violet, blue and black shades on natural and synthetic substrates. Methods for synthesizing the dyes and for dyeing a substrate are described. The dyes represent environmentally friendly alternatives to conventional Cr- and Co-based azo and formazan dyes.
摘要:
An ink comprising at least one water-soluble dye, free from cellulose-reactive groups, of the formula: ##STR1## wherein, R.sup.1 is --(C.sub.a H.sub.2a O).sub.m (C.sub.b H.sub.2b O).sub.n H,R.sup.2 is H or --(C.sub.a H.sub.2a O).sub.m (C.sub.b H.sub.2b O).sub.n H, orR.sup.1 and R.sup.2 together with the nitrogen atom form a morpholine ring;a and b are different and from 2 to 8m is from 1 to 10; n is from 0 to 9;M is H, ammonium or sodium, potassium or lithium;X is (i) NR.sup.1 R.sup.2, (ii) NR.sup.3 R.sup.4, in which R.sup.3 and R.sup.4 are each independently selected from H, alkyl and aryl, or (iii) a mono- or dis-azo chromophore consisting of benzene, naphthalene or mono- or bi-cyclic heteroaryl diazo and coupling components linked to the triazine nucleus through an amino linking group, NR.sup.9, in which R.sup.9 is H, C.sub.1-4 -alkyl or phenyl;R.sup.5 and R.sup.6 are selected from SO.sub.3 M and H provided at least one is SO.sub.3 M;R.sup.7 is H, halogen, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, SO.sub.3 M or COOM; and R.sup.8 is H or SO.sub.3 M.The ink is particularly suited for ink jet printing having improved solution stability, excellent recording properties, ejection stability, ejection responsiveness and continuous recording workability.
摘要:
A water-soluble dye, free from cellulose-reactive groups, of the formula: ##STR1## wherein R.sup.1 is --(C.sub.a H.sub.2a O).sub.m (C.sub.b H.sub.2b O).sub.n H,R.sup.2 is H or --(C.sub.a H.sub.2a O).sub.m (C.sub.b H.sub.2b O).sub.n H, orR.sup.1 & R.sup.2 together with the nitrogen atom form a morpholine ring;a & b are different and from 1 to 8m is from 1 to 10; n is from 0 to 9;M is H, ammonium or a monovalent metal;X is (i) NR.sup.1 R.sup.2, (ii) NR.sup.3 R.sup.4, in which R.sup.3 and R.sup.4 are each independently selected from H, alkyl and aryl, or (ii) a mono- or dis-azo chromophore comprising benzene, naphthalene or mono - or bi-cyclic heteroaryl diazo and coupling components linked to the triazine nucleus through an amino linking group;R.sup.5 & R.sup.6 are selected from SO.sub.3 M and H provided at least one is SO.sub.3 M;R.sup.7 is H, halogen, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, SO.sub.3 M or COOM;and R.sup.8 is H or SO.sub.3 M,a printing ink containing the dye and a method of printing.
摘要翻译:没有纤维素反应性基团的水溶性染料,其具有下式:其中R 1是 - (CaH 2 H)m(C b H b B)n H,R 2是H或 - (CaH 2 H)m(C b H b B)n H或R 1 &R2与氮原子一起形成吗啉环; a&b是不同的,1到8 m是1到10; n为0〜9; M是H,铵或一价金属; X是(i)NR 1 R 2,(ii)NR 3 R 4,其中R 3和R 4各自独立地选自H,烷基和芳基,或(ⅱ)单或二偶氮发色团,包括苯,萘或单 - 或双 - 环状杂芳基重氮和通过氨基连接基团与三嗪核连接的偶联组分; R5和R6选自SO3M和H,至少一个是SO 3 M; R 7为H,卤素,C 1-4烷基,C 1-4烷氧基,SO 3 M或COOM; R8是H或SO3M,含有染料的印刷油墨和印刷方法。