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公开(公告)号：US20230015387A1
公开(公告)日：2023-01-19
申请号：US17859115
申请日：2022-07-07
发明人： Dustin Slack , James A. Mennell , Daren Daugaard
摘要： Some variations provide a process for producing biocarbon pellets, comprising: pyrolyzing a biomass-containing feedstock in a first pyrolysis reactor to generate a first biogenic reagent and a pyrolysis vapor; introducing the pyrolysis vapor to a separation unit, to generate a pyrolysis precipitate in liquid or solid form; contacting the first biogenic reagent with the pyrolysis precipitate, thereby generating an intermediate material; pelletizing the intermediate material, to generate intermediate pellets; optionally, drying the intermediate pellets; separately pyrolyzing the intermediate pellets in a second pyrolysis reactor to generate a second biogenic reagent and a pyrolysis off-gas; and recovering the second biogenic reagent as biocarbon pellets. Some variations provide a similar process that utilizes a carbon-containing condensed-matter material, which is not necessarily a pyrolysis precipitate. The disclosure provides improved processes for producing biocarbon compositions, especially with respect to carbon yield and biocarbon properties, such as reactivity.
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公开(公告)号：US20210139789A1
公开(公告)日：2021-05-13
申请号：US17041015
申请日：2019-04-09
发明人： Kevin B. Daly , Federico Barrai
摘要： Reverse flow reactor (RFR) apparatuses exhibiting asymmetric feed profiles and improved purge mode efficiency, and methods of using same to transform a hydrocarbon feed into a pyrolysed hydrocarbon product are disclosed. The RFR apparatus includes an RFR body with a reaction zone having at least one bed. The RFR body has a central vertical axis and flanked by first and second void spaces. The method utilizes at least two oxygen-containing feeds, a combustion fuel feed, a purge feed, and a hydrocarbon pyrolysis feed. The RFR apparatus can cycle between an exothermic heating mode (heated to ≥700° C. while maintaining a pressure drop across the reaction zone of ≤100 kPag), a purge mode (purging oxygen using
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公开(公告)号：US20210139788A1
公开(公告)日：2021-05-13
申请号：US17041012
申请日：2019-04-09
发明人： Kevin B. Daly , Federico Barrai
摘要： Reverse flow reactor (RFR) apparatuses exhibiting asymmetric feed profiles and improved flow distribution during heating mode and/or pyrolysis mode operation, and methods of using same to transform a hydrocarbon feed into a pyrolysed hydrocarbon product are disclosed. The RFR apparatus includes an RFR body with a reaction zone having at least one bed. The RFR body has a central vertical axis and is flanked by first and second void spaces. The method utilizes at least two oxygen-containing feeds, a combustion fuel feed, a purge feed, and a hydrocarbon pyrolysis feed. The RFR apparatus can cycle between an exothermic heating mode (heated to ≥700° C. while maintaining a pressure drop across the reaction zone of ≤100 kPag), a purge mode (purging oxygen using
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公开(公告)号：US20190031961A1
公开(公告)日：2019-01-31
申请号：US16072283
申请日：2017-01-30
申请人： SGL CFL CE GmbH
发明人： Oswin ÖTTINGER , Heribert WALTER , Martin CHRIST , Johann DAIMER , Wilhelm FROHS , Frank HILTMANN , Rainer SCHMITT
IPC分类号： C10B57/06 , C10B55/02 , C04B35/52 , C04B35/528
摘要： Coke including additives that are accumulated at the yield points or in the regions surrounded by the yield points. For homogeneous distribution, the additives are continuously dosed into the delayed coker during the filling time. The dosing can be carried out by powdery blowing with an inert gas (nitrogen) or also distributed in a slurry consisting of the reaction components and a partial flow of the coker feed (vacuum resid, pytar, decant oil or coal-tar distillates). According to an advantageous form of embodiment, the additives may optionally have a diameter of between 0.05 mm and 5 mm, preferably between 1 mm and 3 mm. Advantageously, the additives can be selected from at least one of acetylene coke, fluid coke, flexi coke, shot coke, carbon black, non-graphitisable carbons (chars), non-graphitic anthracite, silicon carbide, titanium carbide, titanium diboride or mixtures thereof.
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公开(公告)号：US09969937B2
公开(公告)日：2018-05-15
申请号：US14030219
申请日：2013-09-18
发明人： Ahmad Faegh
摘要： A process for producing coke that may include: heating a coker feedstock to a coking temperature to produce a heated coker feedstock; feeding the heated coker feedstock to a coking drum; feeding a coking additive, such as at least one hydroconversion or hydrocracking catalyst, to the coking drum; and subjecting the heated coker feedstock to thermal cracking in the coking drum to crack a portion of the coker feedstock to produce a cracked vapor product and produce a coke product.
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公开(公告)号：US09739283B2
公开(公告)日：2017-08-22
申请号：US15254726
申请日：2016-09-01
发明人： Craig T Barker
IPC分类号： C10B55/02 , C10B57/06 , F04D29/047 , B01D19/04 , C10B55/00 , C10B57/12 , C10G9/00 , C10G33/04 , F04D13/08
CPC分类号： F04D29/047 , B01D19/04 , B01D19/0404 , C10B55/00 , C10B55/02 , C10B57/06 , C10B57/12 , C10G9/005 , C10G33/04 , C10G2300/80 , F04D13/08
摘要： Methods for defoaming in hydrocarbon processes include the steps of providing a defoaming agent, and introducing the agent into a hydrocarbon process to inhibit or control foaming in the hydrocarbon process. These methods may be particularly useful in coking processes, especially as to foaming in coke drums. In certain embodiments, defoaming agents may comprise a plurality of carbon nanoparticles. In some embodiments, drag reducing agents may comprise high-molecular weight alkanes. Advantages include, but are not limited to, more efficient and effective foam inhibition, reduced or eliminated product contamination, reduced or eliminated catalyst poisoning, increased refinery production rate, debottlenecking the coker, and reduced cost and consequences of applying too much antifoam.
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公开(公告)号：US09206810B2
公开(公告)日：2015-12-08
申请号：US14370463
申请日：2012-02-09
申请人： Craig T Barker
发明人： Craig T Barker
IPC分类号： C10B55/02 , C10B57/06 , F04D29/047 , B01D19/04 , C10B55/00 , C10B57/12 , C10G9/00 , C10G33/04 , F04D13/08
CPC分类号： F04D29/047 , B01D19/04 , B01D19/0404 , C10B55/00 , C10B55/02 , C10B57/06 , C10B57/12 , C10G9/005 , C10G33/04 , C10G2300/80 , F04D13/08
摘要： Methods for defoaming in hydrocarbon processes include the steps of providing a defoaming agent, and introducing the agent into a hydrocarbon process to inhibit or control foaming in the hydrocarbon process. These methods may be particularly useful in coking processes, especially as to foaming in coke drums. In certain embodiments, defoaming agents may comprise a plurality of carbon nanoparticles. In some embodiments, drag reducing agents may comprise high-molecular weight alkanes. Advantages include, but are not limited to, more efficient and effective foam inhibition, reduced or eliminated product contamination, reduced or eliminated catalyst poisoning, increased refinery production rate, debottlenecking the coker, and reduced cost and consequences of applying too much antifoam.
摘要翻译： 在烃工艺中消泡的方法包括提供消泡剂并将试剂引入烃工艺中以抑制或控制烃工艺中的起泡的步骤。 这些方法在焦化方法中特别有用，特别是在焦炭鼓中起泡。 在某些实施方案中，消泡剂可以包含多个碳纳米颗粒。 在一些实施方案中，减阻剂可以包含高分子量烷烃。 优点包括但不限于更有效和有效的泡沫抑制，减少或消除产品污染，减少或消除催化剂中毒，提高炼油厂生产率，克服焦化器，并降低应用太多消泡剂的成本和后果。
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公开(公告)号：US20150184080A1
公开(公告)日：2015-07-02
申请号：US14657385
申请日：2015-03-13
发明人： Craig T. Barker
IPC分类号： C10B55/02
CPC分类号： F04D29/047 , B01D19/04 , B01D19/0404 , C10B55/00 , C10B55/02 , C10B57/06 , C10B57/12 , C10G9/005 , C10G33/04 , C10G2300/80 , F04D13/08
摘要： Methods for defoaming in hydrocarbon processes include the steps of providing a defoaming agent, and introducing the agent into a hydrocarbon process to inhibit or control foaming in the hydrocarbon process. These methods may be particularly useful in coking processes, especially as to foaming in coke drums. In certain embodiments, defoaming agents may comprise a plurality of carbon nanoparticles. In some embodiments, drag reducing agents may comprise high-molecular weight alkanes. Advantages include, but are not limited to, more efficient and effective foam inhibition, reduced or eliminated product contamination, reduced or eliminated catalyst poisoning, increased refinery production rate, debottlenecking the coker, and reduced cost and consequences of applying too much antifoam.
摘要翻译： 在烃工艺中消泡的方法包括提供消泡剂并将试剂引入烃工艺中以抑制或控制烃工艺中的起泡的步骤。 这些方法在焦化方法中特别有用，特别是在焦炭鼓中起泡。 在某些实施方案中，消泡剂可以包含多个碳纳米颗粒。 在一些实施方案中，减阻剂可以包含高分子量烷烃。 优点包括但不限于更有效和有效的泡沫抑制，减少或消除产品污染，减少或消除催化剂中毒，提高炼油厂生产率，克服焦化器，并降低应用太多消泡剂的成本和后果。
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公开(公告)号：US5340464A
公开(公告)日：1994-08-23
申请号：US941499
申请日：1992-09-08
申请人： Anthony Mickas
发明人： Anthony Mickas
摘要： A process for disposing of filter media is provided, which process comprises (a) mixing a filter media with a hydrocarbonaceous mixing stream to form a media-hydrocarbon mixture and (b) feeding said media-hydrocarbon mixture to a coking vessel. Preferred coking vessels include delayed cokers, fluidized cokers, and coke calciners. An apparatus for disposing of filter media is provided, which apparatus comprises (a) a coking vessel; (b) a mixer to mix the filter media with a hydrocarbonaeous mixing fluid to form a media- hydrocarbonaeous fluid mixture; and, (c) a feed means to feed the media-hydrocarbonaeous fluid mixture to the coking vessel. Preferably, the apparatus comprises a size reduction means to reduce the size of the filter media to form a media staple comprising fiber clusters having a desired shape and size.
摘要翻译： 提供了一种处理过滤介质的方法，该方法包括（a）将过滤介质与烃类混合流混合以形成介质 - 烃混合物，和（b）将所述介质 - 烃混合物供入焦化容器。 优选的焦化容器包括延迟焦化器，流化焦化器和焦炭煅烧器。 提供了一种处理过滤介质的设备，该装置包括（a）焦化容器; （b）混合器以将过滤介质与烃混合流体混合以形成介质 - 烃类流体混合物; 和（c）将介质 - 烃类流体混合物供入焦化容器的进料装置。 优选地，该装置包括尺寸减小装置，以减小过滤介质的尺寸以形成包含具有期望形状和尺寸的纤维簇的介质订书钉。
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公开(公告)号：US5174891A
公开(公告)日：1992-12-29
申请号：US785444
申请日：1991-10-29
申请人： Lloyd G. Becraft
发明人： Lloyd G. Becraft
IPC分类号： C10B55/02
CPC分类号： C10B55/02
摘要： A nonair-blown low sulfur petroleum residual oil is combined with super finely divided particles of calcined premium coke, and the combination is subjected to delayed coking to produce isotropic coke containing reduced sulfur and having a low CTE ratio.
摘要翻译： 将非吹制的低硫石油残油与超细煅烧优质焦炭颗粒结合，并将该组合进行延迟焦化，以产生含有还原硫并具有低CTE比的各向同性焦炭。
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