公开(公告)号：US11987760B2

公开(公告)日：2024-05-21

申请号：US17609561

申请日：2020-05-08

Applicant: Arq IP Limited

Inventor： John Unsworth ,  Stephen Paspek

IPC: C10G9/00 ,  C10B53/04 ,  C10B55/10 ,  C10B57/04

CPC classification number: C10G9/005 ,  C10B53/04 ,  C10B55/10 ,  C10B57/045 ,  C10G2300/1077 ,  C10G2300/202 ,  C10G2300/205 ,  C10G2300/206 ,  C10G2300/302 ,  C10G2300/304 ,  C10G2300/308

Abstract: Processes for the production of coke, and one or more volatile products comprise the steps of: (i) providing a purified coal product (PCP), wherein the PCP is in particulate form, and wherein at least about 90% v of the particles are no greater than about 100 μm in diameter; wherein the PCP has an ash content of less than about 10% m and a water content of less than around 5% m; (ii) combining the PCP with a liquid residue oil to create a combined solid-liquid blend, wherein the solid-liquid blend comprises at least around 0.1% m and at most around 30% m PCP; (iii) subjecting the solid-liquid blend to a temperature in excess of 375° C. for a time period sufficient to induce cracking of at least 1% of the PCP particles to generate the one or more volatile products, and (iv) producing coke from the product of step (iii).

公开(公告)号：US11959031B2

公开(公告)日：2024-04-16

申请号：US17947744

申请日：2022-09-19

Applicant: Saudi Arabian Oil Company

Inventor： Aaron Chi Akah ,  Essa Alnaimi ,  Qi Xu ,  Musaed Salem Al-Ghrami

IPC: C10G67/04 ,  C07C2/76 ,  C07C4/04 ,  C07C5/32 ,  C10G9/00

CPC classification number: C10G67/049 ,  C07C2/76 ,  C07C4/04 ,  C07C5/321 ,  C10G9/005 ,  C10G2300/1033 ,  C10G2300/206 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2400/20 ,  C10G2400/30

Abstract: An integrated process and associated system for conversion of crude oil to value added petrochemicals. The process includes separating crude oil into light and heavy crude fractions and processing the heavy fraction in a solvent deasphalting unit and a delayed coker unit, and then providing the light fraction and selected effluents of the solvent deasphalting unit and the delayed coker unit to a hydrotreater. The process further includes separating the effluent of the hydrotreater to generate a C1 fraction passed to a methane cracker, a C2 fraction passed to an ethane steam cracker, a C3-C4 fraction passed to a dehydrogenation reactor, a hydrotreated light fraction passed to an aromatization unit, and a hydrotreated heavy fraction passed to a steam enhanced catalytic cracking unit. The process further includes separating effluents of the various unit operations into product streams including a BTX stream and a light olefin stream.

公开(公告)号：US11905470B1

公开(公告)日：2024-02-20

申请号：US18194974

申请日：2023-04-03

Applicant: Saudi Arabian Oil Company

Inventor： Ki-Hyouk R. Choi ,  Joo-Hyeong R. Lee ,  Abdullah Tariq AlAbdulhadi

IPC: C10G31/08 ,  C10G9/00

CPC classification number: C10G31/08 ,  C10G9/005 ,  C10G2300/1033 ,  C10G2300/206 ,  C10G2300/4081 ,  C10G2300/708 ,  C10G2300/805

Abstract: A process for reducing coke and coke precursor formation in supercritical water may include producing a supercritical water stream by heating and pressurizing a feed water, mixing the supercritical water stream with heated pressurized feed oil in a mixing device, to create a combined feed stream, feeding the combined feed stream into a supercritical water reactor to produce an upgraded product producing a cooled depressurized upgraded product, separating the cool depressurized product in a fractionator into a liquid hydrocarbon stream and a hydrocarbon vapor stream, condensing the hydrocarbon vapor stream with a cooling device to produce a light hydrocarbon water mixture and a separate gas product, recycling the light hydrocarbon mixture to mix with the feed water upstream of the supercritical reactor.

公开(公告)号：US20230220285A1

公开(公告)日：2023-07-13

申请号：US17792389

申请日：2022-01-13

Applicant: KELLOGG BROWN & ROOT LLC

Inventor： Samir Saxena ,  Yellaiahnaidu Mekala

IPC: C10G9/00 ,  C10B55/00 ,  C10B57/04 ,  C10G21/00 ,  C10G55/04 ,  C10G7/00

CPC classification number: C10G9/005 ,  C10B55/00 ,  C10B57/045 ,  C10G21/003 ,  C10G55/04 ,  C10G7/00 ,  C10G2300/1077 ,  C10G2300/4056 ,  C10G2400/06 ,  C10G2400/08 ,  C10G2400/26

Abstract: The present invention relates to debottleneck solution for delayed Coker unit. More particularly, this invention relates to bottoms of vacuum residuum routed to Coker unit through de-asphalting unit to avoid revamp of existing Coker for the processing of heavier feed stock when there is a change in crude slate. Another object of the invention, in particular, relates to improved delayed coking products, a process used in petroleum refineries to crack petroleum residue, thus converting it into gaseous and liquid product streams and leaving behind solid, carbonaceous petroleum coke.

公开(公告)号：US11661556B2

公开(公告)日：2023-05-30

申请号：US17809211

申请日：2022-06-27

Applicant: Indian Oil Corporation Limited

Inventor： Shivam Ashok Dixit ,  Ponoly Ramachandran Pradeep ,  Jitumoni Brahma ,  Terapalli Hari Venkata Devi Prasad ,  Satyen Kumar Das ,  Madhusudan Sau ,  Gurpreet Singh Kapur ,  Sankara Sri Venkata Ramakumar

IPC: C10G53/08 ,  C10G9/00 ,  C10G25/00 ,  C10G31/06

CPC classification number: C10G53/08 ,  C10G9/005 ,  C10G9/007 ,  C10G25/003 ,  C10G31/06 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/203 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4031 ,  C10G2300/701

Abstract: The present invention relates to a sequential thermo-chemical treatment along with adsorption-based pre-treatment process for residual oils having a very high naphthenic acid content. First stage of the process is a thermal pre-treatment step which results into generation of hydrocarbon stream with a reduced naphthenic acid content due to high temperature. In second stage of pre-treatment, generated hydrocarbon stream from stage-1 is subjected to esterification reaction with alcohol, such as methanol, to further reduce the TAN of hydrocarbon stream. After recovery of alcohol from the reaction mixture, depending on TAN reduction required reaction mixture may be subjected to an adsorption stage, third stage pre-treatment, where an adsorbent mixture comprising of FCC spent catalyst is used to adsorb the TAN of feed hydrocarbon stream. The treated hydrocarbon stream is then co-processed with DCU feed stock for producing lighter hydrocarbons.

公开(公告)号：US20230145975A1

公开(公告)日：2023-05-11

申请号：US17422714

申请日：2021-07-02

Applicant: Dorf Ketal Chemicals (India) Private Limited

Inventor： Mahesh SUBRAMANIYAM ,  Shivank MENON ,  Prasanta BARUA ,  Suhas A. CHAVAN

IPC: C10B57/06 ,  C10B43/14 ,  C10B53/07 ,  C10B57/04 ,  C10B55/00 ,  C10G1/10 ,  C10G9/00

CPC classification number: C10B57/06 ,  C10B43/14 ,  C10B53/07 ,  C10B57/045 ,  C10B55/00 ,  C10G1/10 ,  C10G9/005 ,  C10G2300/1003 ,  C10G2300/4075 ,  C10G2300/206 ,  C10G2300/1077

Abstract: The present invention relates to a coke reducing additive composition capable of simultaneously (a) reducing coke formation and (b) increasing distillate yield during pyrolysis of a feedstock in the presence of a plastic material, wherein the feedstock is a vacuum residue (VR), plastic material is a waste plastic material or an olefin polymer (OP) material, or a mixture thereof, and the coke reducing additive composition comprises a naphthenate, preferably a calcium naphthenate, or sodium naphthenate, or a mixture thereof, and to a method of employing the coke reducing additive composition, and to a method of use of the coke reducing additive composition of the present invention.
Particularly, in another embodiment, the present invention relates to a coke reducing additive composition capable of simultaneously (a) reducing formation of coke deposits on walls of the processing unit; and (b) reducing fouling caused due to deposits of coke products on walls of the processing unit during pyrolysis of a feedstock in the presence of a plastic material, wherein the feedstock is a vacuum residue (VR), plastic material is a waste plastic material or an olefin polymer (OP) material, or a mixture thereof, and the coke reducing additive composition comprises a naphthenate, preferably a calcium naphthenate, or sodium naphthenate, or a mixture thereof, and to a method of employing the coke reducing additive composition, and to a method of use of the coke reducing additive composition of the present invention.
Particularly, in yet another embodiment, the present invention relates to a method to convert a waste plastic into useful chemical commodity.

公开(公告)号：US10000705B2

公开(公告)日：2018-06-19

申请号：US14744462

申请日：2015-06-19

Applicant: Catalytic Distillation Technologies

Inventor： Ahmad Faegh ,  John E. Collins ,  Virendra Manral ,  Gary Reisen

IPC: C01G9/00 ,  C10B41/08 ,  C10B27/06 ,  C10G9/00 ,  C10B41/00 ,  C10B55/00 ,  C10B57/04 ,  C10B39/06 ,  C10L5/04

CPC classification number: C10G9/005 ,  C10B27/06 ,  C10B39/06 ,  C10B41/00 ,  C10B41/08 ,  C10B55/00 ,  C10B57/045 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/4006 ,  C10G2300/4081 ,  C10G2400/06 ,  C10L5/04 ,  C10L2290/02 ,  C10L2290/06 ,  C10L2290/58

Abstract: A process and apparatus for improving the production of coke having a high volatile combustible material content are disclosed. The process may include, for example: heating a coker feedstock to a coking temperature to produce a heated coker feedstock; contacting the heated coker feedstock with a quench medium to reduce a temperature of the heated coker feedstock and produce a quenched feedstock; feeding the quenched feedstock to a coking drum; subjecting the quenched feedstock to thermal cracking in the coking drum to (a) crack a portion of the quenched feedstock to produce a cracked vapor product, and (b) produce a coke product having a volatile combustible material (VCM) concentration in the range from about 13% to about 50% by weight, as measured by ASTM D3175.

公开(公告)号：US09994780B2

公开(公告)日：2018-06-12

申请号：US15220896

申请日：2016-07-27

Applicant: Saudi Arabian Oil Company

Inventor： Omer Refa Koseoglu

IPC: C10G25/06 ,  C10G25/12 ,  C10G55/04 ,  C10B55/00 ,  C10B57/08 ,  C10G25/00 ,  C10G29/20 ,  C10G53/08 ,  C10G9/00

CPC classification number: C10G55/04 ,  C10B55/00 ,  C10B57/08 ,  C10G9/005 ,  C10G25/00 ,  C10G25/12 ,  C10G29/20 ,  C10G53/08 ,  C10G2300/202 ,  C10G2300/206

Abstract: An integrated process is provided for producing deasphalted oil, high quality petroleum green coke and liquid coker products. An enhanced solvent deasphalting process is used to treat the feedstock to reduce the level of asphaltenes, N, S and metal contaminants and produce a deasphalted oil with reduced contaminants. A coking process is integrated to produce liquid and gas coking unit products, and petroleum green coke.

公开(公告)号：US09969937B2

公开(公告)日：2018-05-15

申请号：US14030219

申请日：2013-09-18

Applicant: Lummus Technology Inc.

Inventor： Ahmad Faegh

IPC: C10B55/00 ,  C10B55/02 ,  C10B57/06 ,  C10B1/04 ,  C10G9/00 ,  C10G11/18

CPC classification number: C10B55/02 ,  C10B1/04 ,  C10B55/00 ,  C10B57/06 ,  C10G9/005 ,  C10G11/18

Abstract: A process for producing coke that may include: heating a coker feedstock to a coking temperature to produce a heated coker feedstock; feeding the heated coker feedstock to a coking drum; feeding a coking additive, such as at least one hydroconversion or hydrocracking catalyst, to the coking drum; and subjecting the heated coker feedstock to thermal cracking in the coking drum to crack a portion of the coker feedstock to produce a cracked vapor product and produce a coke product.

公开(公告)号：US09920263B2

公开(公告)日：2018-03-20

申请号：US13447957

申请日：2012-04-16

Applicant: Benjamin Klein ,  Odette Eng

Inventor： Benjamin Klein ,  Odette Eng

IPC: C10G55/04 ,  C10G7/00 ,  C10G7/06 ,  C10G7/12 ,  C10G9/00 ,  C10G7/02

CPC classification number: C10G55/04 ,  C10G7/00 ,  C10G7/02 ,  C10G7/06 ,  C10G7/12 ,  C10G9/005 ,  C10G2300/1033 ,  C10G2300/1077 ,  C10G2300/301 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/06 ,  C10G2400/08

Abstract: Systems and methods for refining conventional crude and heavy, corrosive, contaminant-laden carbonaceous crude (Opportunity Crude) in partially or totally separated streams or trains.