公开(公告)号：US6004725A

公开(公告)日：1999-12-21

申请号：US118626

申请日：1998-07-17

申请人： Robert Barr ,  Daniel E. Lundy ,  Eiji Kosaka ,  Shigeru Murakami

发明人： Robert Barr ,  Daniel E. Lundy ,  Eiji Kosaka ,  Shigeru Murakami

IPC分类号： G03F7/027 ,  G03F7/029 ,  G03F7/033 ,  G03F7/031 ,  G03F0/033

CPC分类号： G03F7/033 ,  G03F7/027 ,  G03F7/029 ,  Y10S430/111 ,  Y10S430/113

摘要： A negative acting photoimageable composition comprisesA) between about 30 and about 70 wt %, based on total weight of A) plus B), of a organic binder polymers having sufficient acid functionality to render said photoimageable composition developable in alkaline aqueous solution,A) comprising between about 3 and about 65 wt % relative to total of A) plus B) a binder polymer A') having a weight average molecular weight between about 5000 and about 40,000 and a T.sub.g of between about 40 and about 100, and 5 to 67 wt % relative to total of A) plus B) a binder polymer A") having a weight average molecular weight between about 41,000 and about 200,000 and a T.sub.g of between about 40 and about 100,B) between about 30 and about 60 wt %, based on total weight of A) plus B), of .alpha.,.beta.-ethylenically unsaturated compounds, said component B) comprisingB') an isocyanate trimer having tri-.alpha.,.beta.-ethylenically unsaturated functionality, said trimer B') being present at between about 2 to about 30 wt % based on total weight of A) plus B), andB") 0 to about 5 wt % based on total weight of A) plus B) of other .alpha.,.beta.-ethylenically unsaturated compounds, at least about 50 mole percent of the .alpha.,.beta.-ethylenically unsaturated functionality of B' and B" being methacrylate functionality andC) between about 0.5 and about 15 wt %, based on total weight of A) plus B) of an organic, radiation-sensitive free-radical generating system, said photoinitiator chemical system C) comprising between about 0.005 and about 3 wt % relative to total weight of A) plus B) of triphenyphosphine and between about 0.005 and about 2 wt % relative to total weight of A) plus B) of n-phenylglycine.

摘要翻译： 一种负性作用的可光成像组合物包含A）基于A）+ B）总重量的约30至约70重量％的具有足够的酸官能团以使所述可光成像组合物在碱性水溶液中显影的有机粘合剂聚合物，A） 包含约3至约65重量％，相对于A）的总量加上B）粘合剂聚合物A'），其重均分子量在约5000至约40,000之间，Tg约为40至约100，和5至 67重量％，相对于A）的总量加B）粘合剂聚合物A“），其重均分子量为约41,000至约200,000，Tg为约40至约100，B为约30至约60 所述组分B）包含B'）具有三-α，β-烯键式不饱和官能度的异氰酸酯三聚体，所述三聚体B'）的重量百分数，基于A）加B），α，β-烯属不饱和化合物的总重量， 存在于约2至 基于A）加B）和B“）的总重量的约30重量％，基于A）加B）的其它α，β-烯键式不饱和化合物的总重量为0至约5重量％，至少约50 B'和B“的α，β-烯键式不饱和官能团的摩尔百分比是甲基丙烯酸酯官能度，C）约0.5至约15重量％，基于A）+ B）有机辐射敏感的总重量 自由基产生系统，所述光引发剂化学体系C）相对于A）加B）三苯膦的总重量为约0.005至约3重量％，相对于A）加上的总重量为约0.005至约2重量％ B）的n-苯基甘氨酸。