摘要:
A method for handling and stabilizing a (2-alkyl)-acryloyl isocyanate represented by the formula (1) ##STR1## is disclosed, which comprises the steps of: reacting an azomethine compound represented by formula (2) ##STR2## with the (2-alkyl)-acryloyl isocyanate of formula (1) to obtain the reaction product of formula (3) ##STR3## and dissolving said reaction product into a solvent to regenerate the (2-alkyl)-acryloyl isocyanate of formula (1); the identity of said solvent and R-groups being defined herein.
摘要:
A method for producing a (2-alkyl)acryloyl isocyanate of the formula ICH.sub.2 .dbd.C(R.sup.1)--C(O)--NCO (I)wherein R.sup.1 is defined herein, from the dissociation of a compound of formula III ##STR1## wherein R.sup.5, R.sup.6, R.sup.7 and R.sup.8 are defined herein and wherein the dissociation of the compound of formula III produces the compound of formula I and a compound of formula II(R.sup.3) (R.sup.4)C.dbd.N--R.sup.2 (II)wherein R.sup.3, R.sup.4 and R.sup.2 are defined herein.
IN WHICH X REPRESENTS A CHLORINE OR BROMINE ATOM, R1, R2, R3 AND R4 REPRESENT HYDROGEN ATOMS OR SATURATD OR UNSATURATED ALIPHATIC. CYCLOALIPHATIC ARALIPHATIC, AROMATIC OR HETEROCYCLIC RADIACAL ARE PREPARED BY RECTING A LACTAM OF THE FORMULA
1-X,2-R1,2-R2,3-R3,3-R4,4-(O=)AZETIDINE
IN WHICH X, R1, R2, R3 AND R4 ARE DEFINED ABOVE, IN THE PRESENCE OF AN OLEFINE AND/OR AN ACETYLENE WITH A RADICAL-FORMING CATALYST. THE REACTION PRODUCTS ARE INTERMEDIATES FOR THE MANUFACTURES OF COMPOUNDS USED IN THE FIELD OF PLANT PROTECTION, SYNTHELIC MATERIALS AND TEXILE FINISHING.
摘要:
Curable compositions based on polyuretidiones, polythiols and photoactivable bases are disclosed. Also a process for generating isocyanate groups by exposing uretidiones to radiation in the range of 100-315 nm is disclosed. The process can be used in a dual curing system for curing compositions that comprise groups that under go photoinduced polymerizations and active hydrogen groups that react with the generated isocyanates.
摘要:
A solvent system employed in the preparation of phenylene diisocyanates in high yields and purity from phenylene di(nitrile sulfites) wherein the nitrile sulfite groups are either meta or para to each other, is disclosed. The solvents employed are paraffinic hydrocarbons often having about 4 to 16 carbon atoms. Solvent recycle is advantageously employed in the decomposition of, for instance, benzene-1,4-di(nitrile) sulfite) to improve product yield without decreasing purity.
摘要:
The invention relates to a method for preparing polyhydroxy-urethanes without using a compound having an isocyanate function, and from amino compounds and compounds carrying carbonate functions, in particular cyclic carbonate functions. The invention also relates to a method for preparing aqueous or hydro-organic formulations containing polyhydroxy-urethanes, and to the use of said polyhydroxy-urethanes and of said aqueous or hydro-organic formulations.
摘要:
Process for preparing isocyanic acid by bringing cyanuric acid into contact with an aluminum catalyst at temperatures of from 300.degree. to 600.degree. C. and isolating the isocyanic acid formed or directly using it for further reaction.
摘要:
A process for the production of isocyanate by thermal decomposition of a dialiphatic substituted furoxan. Preferably the furoxan is derived from a cyclic olefin and the product is an aliphatic diisocyanate.