公开(公告)号：WO2021262495A1

公开(公告)日：2021-12-30

申请号：PCT/US2021/037541

申请日：2021-06-16

Applicant: DOW SILICONES CORPORATION ,  DOW GLOBAL TECHNOLOGIES LLC

Inventor： COURTEMANCHE, Marc-andre ,  BEDARD, Anne-catherine ,  SPINNEY, Heather ,  WILSON, David ,  RAGHURAMAN, Arjun ,  MUKHOPADHYAY, Sukrit ,  SUNDERLAND, Travis

IPC: C08G77/08 ,  C08G77/12 ,  C08G77/18

Abstract: A composition and method can be used in the preparation of various siloxanes. The composition and method employ a fluorinated triarylborane Lewis acid, a hydrocarbonoxy-functional organosilicon compound, and a silyl hydride. The fluorinated triarylborane Lewis acid catalyzes reaction of a hydrocarbonoxy moiety (from the organosilicon compound) and a silicon-bonded hydrogen atom (from the silyl hydride) to form a siloxane bond.

公开(公告)号：WO2021262494A1

公开(公告)日：2021-12-30

申请号：PCT/US2021/037540

申请日：2021-06-16

Applicant: DOW SILICONES CORPORATION ,  DOW GLOBAL TECHNOLOGIES LLC

Inventor： COURTEMANCHE, Marc-Andre ,  BEDARD, Anne-Catherine ,  SPINNEY, Heather ,  WILSON, David ,  RAGHURAMAN, Arjun ,  MUKHOPADHYAY, Sukrit ,  SUNDERLAND, Travis

IPC: C08G77/08 ,  C08G77/16

Abstract: A polyfunctional organohydrogensiloxane is prepared using a fluorinated triarylborane Lewis acid as catalyst. The polyfunctional organohydrogensiloxane may be formulated into release coating compositions. Alternatively, the polyfunctional organohydrogensiloxane may be further functionalized with a curable group to form a clustered functional organosiloxane. The clustered functional organosiloxane may be formulated into thermal radical cure adhesive compositions.

公开(公告)号：WO2021126516A1

公开(公告)日：2021-06-24

申请号：PCT/US2020/062694

申请日：2020-12-01

Applicant: DOW SILICONES CORPORATION ,  DOW GLOBAL TECHNOLOGIES LLC

Inventor： SUNDERLAND, Travis ,  BAUMGARTNER, Ryan ,  BEKEMEIER, Thomas D. ,  LIU, Nanguo ,  JOFFRE, Eric ,  KENNAN, John ,  PETROFF, Lenin ,  DEETH, Brian ,  FERRITTO, Michael S. ,  SCHMIDT, Alix

IPC: C08G77/12 ,  C08G77/20 ,  C08G77/38 ,  C08G77/46 ,  C08K5/06 ,  C08L83/12 ,  C08G77/34

Abstract: A reaction composition contains: (a) an allyl polyether having the following formula: CH2=CHCH2O-Aa-B where, (i) subscript a is 2 to 170; (ii) A is selected from: –CH2CH2O-; -CH2CH(CH3)O-; -CH(CH3)CH2O-, CH2CH(CH2CH3)O-; -CH(CH2CH3)CH2O-, -CH2CF(CF3)O-, -CF(CF3)CF2O- and -CF2CF(CF3)O-; and (iii) B is selected from –H, -CH3, -CH2CH3, -CH2CH2CH3, -CH2CH2CH2CH3, –C(O)CH3, and -CF2CF2CF3; (b) A silyl hydride functional siloxane comprising the following siloxane units: [R2HSiO1/2]m[R2SiO2/2]d[RSiO3/2]t[SiO4/2]q where d+t+q is one or more and wherein: (i) R is selected from hydrocarbyl groups having from one to 8 carbon atoms; (ii) subscript m is 2 or more; (iii) subscript d is zero to 20; (iv) subscript t is zero to 2; (v) subscript q is zero to 2; and (c) a platinum-based hydrosilylation catalyst; where there are at least 4 molar equivalents of silyl hydride functionalities relative to allyl functionalities in the reaction composition.

公开(公告)号：WO2021262940A1

公开(公告)日：2021-12-30

申请号：PCT/US2021/038831

申请日：2021-06-24

Applicant: DOW SILICONES CORPORATION ,  DOW GLOBAL TECHNOLOGIES LLC

Inventor： ZHANG, Fang ,  LIU, Nanguo ,  BOELTER, Scott ,  SUNDERLAND, Travis ,  TULLOCH, Weston ,  TOTH, Simon ,  NIU, Zhenbin ,  GOYAL, Sachit ,  OGUNNIYI, Adebola ,  CHENG, Yang

IPC: C08G18/48 ,  C08G18/50 ,  C08G18/61 ,  C08G65/336 ,  C08G77/46 ,  C08L83/06 ,  C08G18/163 ,  C08G18/1808 ,  C08G18/225 ,  C08G18/283 ,  C08G18/4804 ,  C08G18/485 ,  C08G18/5096 ,  C08G18/7664 ,  C08G2101/00

Abstract: A composition is disclosed, which comprises (A) an organohydrogensiloxane having cyclic siloxane moieties including silicon-bonded hydrogen atoms. The composition further comprises (B) a polyether compound having an aliphatically unsaturated group. Finally, the composition comprises (C) a hydrosilylation catalyst. A silicone polyether surfactant prepared by reacting components (A) and (B) in the presence of component (C) is also disclosed. In addition, an isocyanate-reactive component comprising a polyol and the silicone polyether surfactant is disclosed. A composition comprising the isocyanate-reactive component, an isocyanate component comprising a polyisocyanate, and a catalyst is further disclosed. Finally, a method of preparing an article comprising a polyurethane and/or polyisocyanurate foam, and an article formed from the composition and/or the method, are disclosed.

公开(公告)号：WO2021113317A1

公开(公告)日：2021-06-10

申请号：PCT/US2020/062827

申请日：2020-12-02

Applicant: DOW SILICONES CORPORATION

Inventor： NIU, Zhenbin ,  LIU, Nanguo ,  SUNDERLAND, Travis ,  RICH, David ,  CHEVALIER, Pierre ,  NG, Sze-Sze ,  KNOTT, Alex

IPC: C08G77/12 ,  C08L83/04 ,  C09D183/04

Abstract: A method of preparing a composition for forming a release coating is disclosed. The method comprises preparing a reaction product comprising a polyorganohydrogensiloxane compound having cyclic SiH-functional branching groups interconnected by linear polydiorganosiloxane segments (the "branched cyclic polyorganohydrogensiloxane compound"), by combining together (A) a hydroxyl terminated polydiorganosiloxane and (B) a cyclic polyorganohydrogensiloxane, in the presence of (C) a boron containing Lewis acid and a solvent. A release coating composition including the reaction product comprising the branched cyclic polyorganohydrogensiloxane is also disclosed. The reaction product may be combined with or prepared in the presence of a polyorganohydrogensiloxane diluent and stripped of solvent to prepare the composition as a blend of the branched cyclic polyorganohydrogensiloxane and the polyorganohydrogensiloxane diluent for use in solventless-curable compositions.

公开(公告)号：WO2023086692A1

公开(公告)日：2023-05-19

申请号：PCT/US2022/075435

申请日：2022-08-25

Applicant: DOW SILICONES CORPORATION

Inventor： SUNDERLAND, Travis ,  JELETIC, Matthew ,  HASSO, Douglas

IPC: D06M15/263 ,  D06M15/273 ,  D06M15/356 ,  C08L83/10

Abstract: An emulsion formulation includes a silicone – (meth)acrylate copolymer and a silicone additive. The emulsion formulation can be coated on textiles and dried to impart both durable water repellency and softness to the textiles.

公开(公告)号：WO2019118019A1

公开(公告)日：2019-06-20

申请号：PCT/US2018/049314

申请日：2018-09-04

Applicant: DOW SILICONES CORPORATION

Inventor： CHANG, Noel Mower ,  HWANG, Byung K. ,  REKKEN, Brian D. ,  SHAMAMIAN, Vasgen ,  SUNDERLAND, Travis ,  TELGENHOFF, Michael D. ,  ZHOU, Xiaobing

IPC: C23C16/455 ,  C23C16/30 ,  C23C16/40

Abstract: A method of depositing a silicon-containing film on a substrate, the method comprising: A) contacting an organo(halo)siloxane precursor, wherein the organo(halo)siloxane precursor comprises a siloxane bond, a silicon-bonded halogen atom, and a silicon-bonded unsaturated hydrocarbyl group having from 1-10 carbon atoms with a substrate in a reactor at conditions sufficient to deposit the silicon-containing film on the substrate.

公开(公告)号：WO2019005571A1

公开(公告)日：2019-01-03

申请号：PCT/US2018/038711

申请日：2018-06-21

Applicant: DOW SILICONES CORPORATION

Inventor： MILLWARD, Andrew ,  REKKEN, Brian, D. ,  SUNDERLAND, Travis ,  YOUNG, Jeanette, K. ,  ZHOU, Xiaobing

IPC: C07F7/02 ,  C01B33/107 ,  C30B21/02

Abstract: A method of making a trihalodisilane, the method comprising: combining a reductive effective amount of an alkylaluminum hydride, a halodisilane comprising at least 4 halogen atoms, and a solvent at a temperature