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141.
公开(公告)号:WO2004016350A1
公开(公告)日:2004-02-26
申请号:PCT/US2003/025554
申请日:2003-08-15
Applicant: ARCHER-DANIELS-MIDLAND COMPANY , SLEETER, Ronald, T.
Inventor: SLEETER, Ronald, T.
IPC: B01J23/46
CPC classification number: C11C3/14 , B01J23/462 , B01J27/13
Abstract: A process for conjugating organic compounds containing methylene interrupted carbon-carbon double bonds comprising (a) contacting ruthenium trichloride hydrate and an organic solvent or carboxylic acid to form a first mixture, the organic solvent or carboxylic acid being present in an amount sufficient to solubilize the ruthenium trichloride hydrate, and (b) contacting the first mixture with an organic compound containing methylene interrupted carbon-carbon double bonds at a sufficient temperature and for a sufficient time to conjugate the organic compound containing methylene interrupted carbon-carbon double bonds; wherein the ruthenium in the ruthenium trichloride hydrate in (b) is present in an amount of about 5 ppm to about 100 ppm based on the weight of the organic compound containing methylene interrupted carbon-carbon double bonds.
Abstract translation: 一种含有亚甲基间断碳 - 碳双键的有机化合物的共轭方法,包括(a)使三氯化钌水合物与有机溶剂或羧酸接触以形成第一混合物,有机溶剂或羧酸的存在量足以溶解 三氯化钌水合物,和(b)在足够的温度下使第一混合物与含有亚甲基中断的碳 - 碳双键的有机化合物接触足够的时间以使含有亚甲基中断的碳 - 碳双键的有机化合物结合; 其中(b)中三氯化钌水合物中的钌以含有亚甲基中断碳 - 碳双键的有机化合物的重量计约5ppm至约100ppm的量存在。
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公开(公告)号:WO2003037884A2
公开(公告)日:2003-05-08
申请号:PCT/US2002/029599
申请日:2002-09-19
Applicant: ARCHER-DANIELS-MIDLAND COMPANY
Inventor: ARCHER-DANIELS-MIDLAND COMPANY , SHUKLA, Rishi , BARTOK, Laslow, F. , HILALY, Ahmad , SCHUETTE, Christine, M.
IPC: C07D311/72
CPC classification number: C07D311/72
Abstract: A process for separation of specific tocopherols from a mixture of tocopherols is disclosed. The process includes methods of separation of the tocopherols from residues of vegetable oil refining and other various food sources by dissolving in organic solvents and eluting over non-ionic adsorbent resins.
Abstract translation: 公开了从生育酚混合物分离特定生育酚的方法。 该方法包括通过溶解在有机溶剂中并通过非离子吸附树脂洗脱,将生育酚与植物油精炼和其它各种食物来源的残留物分离的方法。
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公开(公告)号:WO2002031158A3
公开(公告)日:2002-04-18
申请号:PCT/US2001/031893
申请日:2001-10-12
Applicant: ARCHER-DANIELS-MIDLAND COMPANY
Inventor: HANKE, Paul, D.
IPC: C12N15/52
Abstract: The present invention relates to a mutated pyruvate carboxylase gene from Corynebacterium . The mutant pyruvate carboxylase gene encodes a pyruvate carboxylase enzyme which is resistant to feedback inhibition from aspartic acid. The present invention also relates to a method of replacing the wild-type pyruvate carboxylase gene in Corynebacterium with this feedback-resistant pyruvate carboxylase gene. The present invention further relates to methods of the production of amino acids, preferably lysine, comprising the use of this mutant pyruvate carboxylase enzyme in microorganisms.
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公开(公告)号:WO2022173704A2
公开(公告)日:2022-08-18
申请号:PCT/US2022/015514
申请日:2022-02-07
Applicant: ARCHER-DANIELS-MIDLAND COMPANY
Inventor: VENKITASUBRAMANIAN, Padmesh , GARNER, Ashley , ISLAM, S M Mahfuzul , SUBEDI, Bishnu , WELCH, Mark , GOVINDARAJAN, Sridhar
Abstract: This disclosure provides maltotriose amylase enzymes useful for commercial scale production of reduced sugar glucose syrups (RSGS) from a starch. Useful enzymes ("amylase variants" or "enzyme variants") may be variants of a Bacillus subtilis amylase or enzymes with at least 90 % sequence identity thereto engineered with mutations that improve thermal tolerance and activity at a temperature above 50⁰C as compared with the parent enzymes.
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公开(公告)号:WO2021257948A1
公开(公告)日:2021-12-23
申请号:PCT/US2021/038021
申请日:2021-06-18
Applicant: ARCHER DANIELS MIDLAND COMPANY
Inventor: AYOUB, Ali , GHOTRA, Baljit , SANBORN, Alexandra , CHENAULT, Darrell, V.
Abstract: A method of preparing a non-wood fiber paper strengthening product is disclosed. The method comprises placing an additive in an aqueous alkaline medium, wherein the additive comprises a hydroxycarboxylic acid, and mixing a non-wood fiber material with the placed additive in the aqueous alkaline medium to form a mixture, wherein the non-wood fiber material comprises starch, protein and fiber, wherein the additive, starch, protein, and fiber of the non-wood fiber material, and metal ions of the alkaline medium become physically crosslinked resulting in a non-wood fiber paper strengthening product. In an aspect, the non-wood fiber paper strengthening product is used in making a paper product wherein the paper product has greater strength than the same paper product made with native starch or chemically modified starch instead of the non-wood fiber paper strengthening product.
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公开(公告)号:WO2021231556A1
公开(公告)日:2021-11-18
申请号:PCT/US2021/031969
申请日:2021-05-12
Applicant: ARCHER DANIELS MIDLAND COMPANY
Inventor: INGRAM, Andrew , HAGBERG, Erik , MA, Chi-Cheng , MCCLURG, Jessica , STENSRUD, Kenneth
IPC: C07D307/68 , C07D307/46 , C07C51/16 , C07C55/02
Abstract: Processes for the oxidation of carbohydrate dehydration products, such as furanics that can be oxidized to the bio-based monomer 2,5-furandicarboxylic acid (FDCA), are disclosed, according to which certain co-feeds, having been discovered to impart a beneficial reaction stabilizing effect, are oxidized together with the carbohydrate dehydration products. This can advantageously counteract, in whole or in part, detrimental effects of humin impurities present in oxidation feed, with such impurities having been generated as byproducts of the upstream dehydrating step. An important co-feed is para-xylene that can be co-oxidized to form the petroleum-based monomer terephthalic acid (TPA), such that co-processing can beneficially yield two valuable monomers, while improving performance, particularly in terms of reaction stability, over comparable processes in which only the first monomer is produced. Related aspects involve opportunities for retrofitting existing monomer production facilities to enable co-processing of carbohydrate dehydration products that can lead to the above-noted advantages.
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公开(公告)号:WO2021195001A1
公开(公告)日:2021-09-30
申请号:PCT/US2021/023542
申请日:2021-03-22
Applicant: ARCHER DANIELS MIDLAND COMPANY
Inventor: MA, Chi-Cheng , BRAZDIL, James
IPC: C07C303/02 , C07C309/14
Abstract: A process for producing taurine, comprising mixing aminoethanol sulfate ester (AES) and a carbonate or bicarbonate, or combination thereof, thus producing a reaction mixture, and heating the reaction mixture in the presence of a sulfite or a bisulfite, or combination thereof, such that taurine is formed.
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148.
公开(公告)号:WO2020086916A9
公开(公告)日:2020-04-30
申请号:PCT/US2019/057967
申请日:2019-10-24
Applicant: ARCHER DANIELS MIDLAND COMPANY
Inventor: GHOTRA, Baljit , HALALIPOUR, Ali , MARION, Eric , SANBORN, Alexandra , ZHU, Lijia
Abstract: Disclosed herein are processing methods for producing a physically modified starch and for producing a physically modified flour and/or starch flour mixture. The starch process comprises adding at least one salt or additive to a starch, adjusting the pH of the starch to alkaline, and dewatering the starch using a filter to obtain filtered solids. The process further comprises drying the filtered solids, spreading a layer of dried filtered solids on a surface, and heating the dried filtered solids while on the surface to a temperature of about 100° C to 190° C to obtain the physically modified starch. In an embodiment, the flour and/or starch/flour mixture process comprises preparing a thermally inhibited flours and/or starch/flour mixtures starting with or without additives, pH adjustment, followed by heat treating the flour and/or starch/flour mixtures directly to obtain the physically modified flour and/or starch flour mixture.
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149.
公开(公告)号:WO2020086916A1
公开(公告)日:2020-04-30
申请号:PCT/US2019/057967
申请日:2019-10-24
Applicant: ARCHER DANIELS MIDLAND COMPANY
Inventor: GHOTRA, Baljit , HALALIPOUR, Ali , MARION, Eric , SANBORN, Alexandra , ZHU, Lijia
Abstract: Disclosed herein are processing methods for producing a physically modified starch and for producing a physically modified flour and/or starch flour mixture. The starch process comprises adding at least one salt or additive to a starch, adjusting the pH of the starch to alkaline, and dewatering the starch using a filter to obtain filtered solids. The process further comprises drying the filtered solids, spreading a layer of dried filtered solids on a surface, and heating the dried filtered solids while on the surface to a temperature of about 100° C to 190° C to obtain the physically modified starch. In an embodiment, the flour and/or starch/flour mixture process comprises preparing a thermally inhibited flours and/or starch/flour mixtures starting with or without additives, pH adjustment, followed by heat treating the flour and/or starch/flour mixtures directly to obtain the physically modified flour and/or starch flour mixture.
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公开(公告)号:WO2020069396A1
公开(公告)日:2020-04-02
申请号:PCT/US2019/053582
申请日:2019-09-27
Applicant: ARCHER DANIELS MIDLAND COMPANY
Inventor: BAO, Wu-li , SOLHEIM, Leif , VENKITASUBRAMANIAN, Padmesh
Abstract: Methods are disclosed for the production of soluble dietary fiber from a starch, including, e.g., corn and wheat starch. The methods comprise adding an acid to a soluble starch, mixing and heating the starch to form a starch substrate, and placing the starch substrate in contact with a glycosyl-transferase, thus producing a soluble dietary fiber composition having a higher a higher soluble dietary content than a composition without the addition of the glycosyl-transferase.
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