公开(公告)号：WO2010060670A1

公开(公告)日：2010-06-03

申请号：PCT/EP2009/062763

申请日：2009-10-01

Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION ,  IBM UNITED KINGDOM LIMITED ,  SEKARIC, Lidija ,  AFZALI-ARDAKANI, Ali

Inventor： SEKARIC, Lidija ,  AFZALI-ARDAKANI, Ali

IPC: H01L51/42

CPC classification number: H01L51/428 ,  B82Y10/00 ,  H01L29/0673 ,  H01L51/0049 ,  H01L51/0077 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/0086 ,  H01L51/4213 ,  Y02E10/549 ,  Y10S977/762 ,  Y10T428/292

Abstract: A semiconductor nanowire is coated with a chemical coating layer that slectively attaches to the semiconductor material and which forms a dye in a chemical reaction. The dye layer comprises a material that absorbs electromagnetic radiation. A portion of the absorbed energy induces electronic excitation in the chemical coating layer from which additional free charge carriers are temporarily donated into the semiconductor nanowire. Thus, the conductivity of the semiconductor nanowire increases upon illumination on the dye layer. The semiconductor nanowire, and the resulting dye layer collective operate as a detector for electromagnetic radiation.

Abstract translation: 半导体纳米线涂覆有选择性地附着到半导体材料上并在化学反应中形成染料的化学涂层。 染料层包括吸收电磁辐射的材料。 吸收的能量的一部分在化学涂层中引起电子激发，其中额外的自由电荷载体从其中暂时捐赠到半导体纳米线中。 因此，在染料层上照射时，半导体纳米线的导电性增加。 半导体纳米线和所得到的染料层集合起来用作电磁辐射的检测器。

公开(公告)号：WO2008011623A8

公开(公告)日：2008-06-26

申请号：PCT/US2007074118

申请日：2007-07-23

Applicant: IBM ,  AFZALI-ARDAKANI ALI ,  KAGAN CHERIE R ,  TROMP RUDOLF

Inventor： AFZALI-ARDAKANI ALI ,  KAGAN CHERIE R ,  TROMP RUDOLF

CPC classification number: B82Y40/00 ,  B82Y30/00 ,  C01B32/152 ,  C01B32/174 ,  C01B2202/28 ,  C01B2202/36 ,  Y10S977/84 ,  Y10S977/842 ,  Y10S977/845 ,  Y10S977/847 ,  Y10S977/877 ,  Y10S977/895 ,  Y10S977/896

Abstract: Separation of carbon nanotubes or fullerenes according to diameter through non- covalent pi-pi interaction with molecular clips is provided. Molecular clips are prepared by Diels- Alder reaction of polyacenes with a variety of dienophiles. The pi-pi complexes of carbon nanotrubes with molecular clips are also used for selective placement of carbon nanotubes and fullerenes on substrates.

Abstract translation: 提供了根据直径通过非共价π-π相互作用与分子剪辑分离碳纳米管或富勒烯。 分子剪辑通过多并苯与各种亲二烯体的狄尔斯 - 阿尔德反应来制备。 具有分子夹的碳纳米管的pi-pi复合物也用于在基底上选择性放置碳纳米管和富勒烯。

公开(公告)号：WO2008060678A2

公开(公告)日：2008-05-22

申请号：PCT/US2007/068154

申请日：2007-05-03

Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION ,  AFZALI-ARDAKANI, Ali ,  KAGAN, Cherie, R. ,  KOSBAR, Laura, L.

Inventor： AFZALI-ARDAKANI, Ali ,  KAGAN, Cherie, R. ,  KOSBAR, Laura, L.

IPC: H01L21/336

CPC classification number: H01L29/0665 ,  B82Y10/00 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/162 ,  C30B25/00 ,  C30B29/02 ,  C30B29/60 ,  H01L29/0673 ,  H01L29/0676 ,  H01L29/78681 ,  H01L29/78684 ,  Y10S977/762 ,  Y10S977/84 ,  Y10S977/89 ,  Y10S977/932 ,  Y10S977/936 ,  Y10S977/938

Abstract: The invention is directed to a method of forming carbon nanomaterials or semiconductor nanomaterials. The method comprises providing a substrate and attaching a molecular precursor to the substrate. The molecular precursor includes a surface binding group for attachment to the substrate and a binding group for attachment of metal-containing species. The metal-containing species is selected from a metal cation, metal compound, or metal or metal-oxide nanoparticle to form a metallized molecular precursor. The metallized molecular precursor is then subjected to a heat treatment to provide a catalytic site from which the carbon nanomaterials or semiconductor nanomaterials form. The heating of the metallized molecular precursor is conducted under conditions suitable for chemical vapor deposition of the carbon nanomaterials or semiconductor nanomaterials.

Abstract translation: 本发明涉及一种形成碳纳米材料或半导体纳米材料的方法。 该方法包括提供基材并将分子前体附着至基材。 分子前体包括用于附着于基质的表面结合基团和用于附着含金属物质的结合基团。 含金属物质选自金属阳离子，金属化合物或金属或金属氧化物纳米粒子以形成金属化分子前体。 然后对金属化分子前体进行热处理以提供形成碳纳米材料或半导体纳米材料的催化位点。 金属化分子前体的加热在适合于碳纳米材料或半导体纳米材料的化学气相沉积的条件下进行。

公开(公告)号：WO2006081040A2

公开(公告)日：2006-08-03

申请号：PCT/US2006/000266

申请日：2006-01-05

Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION ,  AFZALI-ARDAKANI, Ali ,  HANNON, James Bowler

Inventor： AFZALI-ARDAKANI, Ali ,  HANNON, James Bowler

IPC: B05D5/00

CPC classification number: B82Y30/00 ,  B05D1/283 ,  B82Y40/00

Abstract: The present invention provides a method for the selective placement of carbon nanotubes on a particular surface. In particular, the present invention provides a method in which self-assembled monolayers formed on an unpatterned or patterned metal oxide surface are used to attract or repel carbon nanotubes from a dispersion containing the same. In accordance with the present invention, the carbon nanotubes can be attracted to the self-assembled monolayers so as to be attached to the metal oxide surface, or they can be repelled by the self-assembled monolayers bonding to a predetermined surface other than the metal oxide surface containing the self-assembled monolayers.

Abstract translation: 本发明提供了一种在特定表面上选择性地放置碳纳米管的方法。 特别地，本发明提供了一种方法，其中形成在未图案化或图案化的金属氧化物表面上的自组装单层被用于从含有该碳纳米管的分散体吸引或排斥碳纳米管。 根据本发明，碳纳米管可以被吸引到自组装单层上以便附着到金属氧化物表面，或者它们可以被结合到除了金属之外的预定表面的自组装单层排斥 含有自组装单层的氧化物表面。

公开(公告)号：WO2013022903A1

公开(公告)日：2013-02-14

申请号：PCT/US2012/049878

申请日：2012-08-07

Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION ,  AFZALI-ARDAKANI, Ali ,  WAGGONER, Philip, S.

Inventor： AFZALI-ARDAKANI, Ali ,  WAGGONER, Philip, S.

IPC: G01N27/26

CPC classification number: G01N33/48721 ,  B01L3/502746 ,  B01L3/502761 ,  B01L2300/0867

Abstract: Biological and chemical sensors based on surface charge changes in a pore or channel, such as a nanopore or nanochannel, are employed to detect targeted analytes in an electrolyte solution having a low ion concentration. Receptors within the pore or channel capture a targeted analyte, causing a change in surface charge that affects ionic conductance. The change in ionic conductance is detected, evidencing the presence of the targeted analyte. A secondary tag may be introduced to the pore or channel for binding with a captured analyte in certain circumstances for causing a change in the surface charge.

Abstract translation: 使用基于孔或通道（如纳米孔或纳米通道）中的表面电荷变化的生物和化学传感器来检测具有低离子浓度的电解质溶液中的目标分析物。 孔或通道内的受体捕获目标分析物，导致影响离​​子电导的表面电荷的变化。 检测离子电导的变化，证明目标分析物的存在。 在某些情况下，可以将二级标签引入孔或通道中与捕获的分析物结合以引起表面电荷的改变。

公开(公告)号：WO2012022513A1

公开(公告)日：2012-02-23

申请号：PCT/EP2011/059413

申请日：2011-06-07

Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION ,  BOL, Ageeth, Anke ,  AFZALI-ARDAKANI, Ali ,  TULEVSKI, George, Stojan

Inventor： BOL, Ageeth, Anke ,  AFZALI-ARDAKANI, Ali ,  TULEVSKI, George, Stojan

IPC: H01B1/04 ,  H01L51/00 ,  H01L51/44 ,  C01B31/04

CPC classification number: H01B1/04 ,  B82Y10/00 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/194 ,  C01B2204/22 ,  H01L51/0045 ,  H01L51/442 ,  Y02E10/549

Abstract: Techniques for increasing conductivity of graphene films by chemical doping are provided. In one aspect, a method for increasing conductivity of a graphene film includes the following steps. The graphene film is formed from one or more graphene sheets. The graphene sheets are exposed to a solution having a one-electron oxidant configured to dope the graphene sheets to increase a conductivity thereof, thereby increasing the overall conductivity of the film. The graphene film can be formed prior to the graphene sheets being exposed to the one-electron oxidant solution. Alternatively, the graphene sheets can be exposed to the one-electron oxidant solution prior to the graphene film being formed. A method of fabricating a transparent electrode on a photovoltaic device from a graphene film is also provided.

Abstract translation: 提供了通过化学掺杂增加石墨烯膜的导电性的技术。 一方面，提高石墨烯膜的导电性的方法包括以下步骤。 石墨烯膜由一个或多个石墨烯片形成。 将石墨烯片暴露于具有被配置为掺杂石墨烯片的单电子氧化物的溶液以增加其导电性，从而增加膜的总导电性。 在石墨烯片暴露于单电子氧化剂溶液之前，可以形成石墨烯膜。 或者，石墨烯片可以在形成石墨烯膜之前暴露于单电子氧化剂溶液。 还提供了一种从石墨烯膜制造光电器件上的透明电极的方法。

公开(公告)号：WO2011023498A1

公开(公告)日：2011-03-03

申请号：PCT/EP2010/061293

申请日：2010-08-03

Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION ,  IBM UNITED KINGDOM LIMITED ,  TULEVSKI, George, Stojan ,  AFZALI-ARDAKANI, Ali

Inventor： TULEVSKI, George, Stojan ,  AFZALI-ARDAKANI, Ali

IPC: H01L51/00 ,  H01L51/44

CPC classification number: H01L51/444 ,  H01L51/0003 ,  H01L51/002 ,  Y02E10/549 ,  Y02P70/521

Abstract: Techniques for increasing conductivity of carbon nanotube films are provided. In one aspect, a method for increasing conductivity of a carbon nanotube film includes the following steps. The carbon nanotube film is formed from a mixture of metallic and semiconducting carbon nanotubes. The carbon nanotubes are exposed to a solution comprising a one-electron oxidant configured to dope thesemiconducting carbon nanotubes to increase a conductivity thereof, thereby increasing the overall conductivity of the film. The step of forming the carbon nanotube film can be performed prior to the step of exposing the carbon nanotubes to the one-electron oxidant solution. Alternatively, the step of exposing the carbon nanotubes to the one-electron oxidant solution can be performed prior to the step of forming the carbon nanotube film. A method of fabricating a transparent electrode on a photovoltaic device from a carbon nanotube film is also provided.

Abstract translation: 提供了增加碳纳米管膜导电性的技术。 一方面，提高碳纳米管膜的导电性的方法包括以下步骤。 碳纳米管膜由金属和半导体碳纳米管的混合物形成。 将碳纳米管暴露于包含配置为掺杂导电性碳纳米管的单电子氧化物以增加其导电性的溶液的溶液，从而增加膜的总导电性。 形成碳纳米管膜的步骤可以在将碳纳米管暴露于单电子氧化剂溶液的步骤之前进行。 或者，可以在形成碳纳米管膜的步骤之前进行将碳纳米管暴露于单电子氧化剂溶液的步骤。 还提供了从碳纳米管膜在光电器件上制造透明电极的方法。

公开(公告)号：WO2008011623A2

公开(公告)日：2008-01-24

申请号：PCT/US2007/074118

申请日：2007-07-23

Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION ,  AFZALI-ARDAKANI, Ali ,  KAGAN, Cherie, R. ,  TROMP, Rudolf

Inventor： AFZALI-ARDAKANI, Ali ,  KAGAN, Cherie, R. ,  TROMP, Rudolf

CPC classification number: B82Y40/00 ,  B82Y30/00 ,  C01B32/152 ,  C01B32/174 ,  C01B2202/28 ,  C01B2202/36 ,  Y10S977/84 ,  Y10S977/842 ,  Y10S977/845 ,  Y10S977/847 ,  Y10S977/877 ,  Y10S977/895 ,  Y10S977/896

Abstract: Separation of carbon nanotubes or fullerenes according to diameter through non- covalent pi-pi interaction with molecular clips is provided. Molecular clips are prepared by Diels- Alder reaction of polyacenes with a variety of dienophiles. The pi-pi complexes of carbon nanotrubes with molecular clips are also used for selective placement of carbon nanotubes and fullerenes on substrates.

Abstract translation: 提供根据直径通过与分子夹的非共价π-π相互作用分离碳纳米管或富勒烯。 分子夹是由多烯与Dienophiles的Diels-Alder反应制备的。 具有分子夹的碳纳米管的π-π络合物也用于将碳纳米管和富勒烯选择性地放置在基底上。

公开(公告)号：WO2006081040A3

公开(公告)日：2007-10-11

申请号：PCT/US2006000266

申请日：2006-01-05

Applicant: IBM ,  AFZALI-ARDAKANI ALI ,  HANNON JAMES BOWLER

Inventor： AFZALI-ARDAKANI ALI ,  HANNON JAMES BOWLER

IPC: B05D5/00 ,  B82B3/00

CPC classification number: B82Y30/00 ,  B05D1/283 ,  B82Y40/00

Abstract: The present invention provides a method for the selective placement of carbon nanotubes on a particular surface. In particular, the present invention provides a method in which self-assembled monolayers formed on an unpatterned or patterned metal oxide surface are used to attract or repel carbon nanotubes from a dispersion containing the same. In accordance with the present invention, the carbon nanotubes can be attracted to the self-assembled monolayers so as to be attached to the metal oxide surface, or they can be repelled by the self-assembled monolayers bonding to a predetermined surface other than the metal oxide surface containing the self-assembled monolayers.

Abstract translation: 本发明提供了一种在特定表面上选择性地放置碳纳米管的方法。 特别地，本发明提供了一种方法，其中形成在未图案化或图案化的金属氧化物表面上的自组装单层被用于从含有该碳纳米管的分散体吸引或排斥碳纳米管。 根据本发明，碳纳米管可以被吸引到自组装单层上，以便附着到金属氧化物表面，或者它们可以被结合到除金属之外的预定表面的自组装单层排斥 含有自组装单层的氧化物表面。

公开(公告)号：WO2007077078A1

公开(公告)日：2007-07-12

申请号：PCT/EP2006/069341

申请日：2006-12-05

Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION ,  IBM UNITED KINGDOM LIMITED ,  AFZALI-ARDAKANI, Ali ,  KLINKE, Christian ,  HANNON, James ,  AVOURIS, Phaedon

Inventor： AFZALI-ARDAKANI, Ali ,  KLINKE, Christian ,  HANNON, James ,  AVOURIS, Phaedon

IPC: C01B31/02 ,  H01B1/00

CPC classification number: B82Y30/00 ,  B82Y40/00 ,  C01B32/174 ,  C01B2202/28 ,  H01B1/04 ,  Y10S977/742 ,  Y10S977/847

Abstract: The present invention provides a method for selectively placing carbon nanotubes on a substrate surface by using functionalized carbon nanotubes having an organic compound that is covalently bonded to such carbon nanotubes. The organic compound comprises at least two functional groups, the first of which is capable of forming covalent bonds with carbon nanotubes, and the second of which is capable of selectively bonding metal oxides. Such functionalized carbon nanotubes are contacted with a substrate surface that has at least one portion containing a metal oxide. The second functional group of the organic compound selectively bonds to the metal oxide, so as to selectively place the functionalized carbon nanotubes on the at least one portion of the substrate surface that comprises the metal oxide.

Abstract translation: 本发明提供了一种通过使用具有共价键合到这种碳纳米管上的有机化合物的官能化碳纳米管来选择性地将碳纳米管置于基材表面上的方法。 有机化合物包括至少两个官能团，其中第一个能够与碳纳米管形成共价键，其中第二个能够选择性地键合金属氧化物。 这样的官能化碳纳米管与具有至少一部分含有金属氧化物的基材表面接触。 有机化合物的第二官能团选择性地键合到金属氧化物上，以便将官能化的碳纳米管选择性地置于包含金属氧化物的衬底表面的至少一部分上。