USE OF SUBSTITUTED DIBENZOTHIEPINE DERIVATIVES AS INSECTICIDAL, ACARICIDAL AND NEMATICIDAL AGENTS
    11.
    发明申请
    USE OF SUBSTITUTED DIBENZOTHIEPINE DERIVATIVES AS INSECTICIDAL, ACARICIDAL AND NEMATICIDAL AGENTS 审中-公开
    用作杀虫剂,杀虫剂和神经毒剂的替代二苯并噻吩衍生物的使用

    公开(公告)号:WO2003039255A1

    公开(公告)日:2003-05-15

    申请号:PCT/EP2002/012228

    申请日:2002-11-02

    Abstract: A composition comprising a) compounds of formula (I):, wherein A-B denotes C-C or C=C; x is S, O, SO, SO 2 , NR a , or CR b R c ; R 1 , R 2 are H, halogen, OH, SH, NH 2 , CN, NO 2 , alkyl, alkoxy, alky­lamino, dialkylamino, alkylthio, alkenyl, alkenyloxy, alkeny­lamino, alkenylthio, alkynyl, alkynyloxy, alkynylamino, alkynylthio, alkylsulfonyl, alkylsulfoxyl, alkenylsulfonyl, alkynylsulfoxyl, formyl, alkylcarbonyl, hydroxycarbonyl,alkoxy­carbonyl, carbonyloxy, alkylcarbonyloxy, phenyloxy, C(O)NR d R e , (S0 2 )nNR d R e , or C(=NOR f )-Γ p -R f' , a mono- or bicyclic 5- to 10-membered aromatic ringsystem, a 5- to 10-membered heteroaromatic ring system, or cycloalkyl, each optionally substituted, which is unfused or fused to the aromatic group to which it is bonded and which, when unfused, is bonded directly or through an O, S, alkyl, or alkoxy linkage; R 3 , R 4 are each independently H, alkyl, haloalkyl, alkylamine, al­koxy, cycloalkyl, wherein the carbon atoms in these aliphatic groups may be substituted, or R 3 and R 4 together with the nitrogen atom to which they are attached form a saturated or partially saturated mono-or bi­cyclic 5- to 10-membered ringsystem or a 5-membered hetaryl, wherein the rings are optionally substituted and are bonded directly or via an O, S, or alkyl linkage, and cycloalkenyl, wherein the carbon atoms in these aliphatic groups can be substituted, and wherein the group NR 3 R 4 can be present as [N + -O-]R 3 R 4 (amino­xide) if R 3 and R 4 are bonded through a single bond to the ni­trogen atom; and R a , R b , R c , R d , R e , R f' , R f , Γ, and p are as defined in the description; m is 0, 1 ,2 ,3, or 4; n is 0, 1, 2, 3, or 4; or the enantiomers or diastereomers, salts or esters thereof, and b) an agronomically acceptable carrier, methods for protecting crops from attack by insects, arachnids and nematodes by contacting the crop or the target species with a pesticidally effective amount of the compound of formula (I), compounds of formula I, and a process for their preparation.

    Abstract translation: 包含式I化合物的组合物,其中AB表示C C或C = C x为S,O,SO,SO 2,NR a或CR b R c R 1,R 2为H,卤素,OH,SH,NH 2,CN,NO 2, 烷基氨基,烷基氨基,二烷基氨基,烷硫基,烯基,烯氧基,烯基氨基,烯基硫基,炔基,炔氧基,炔基氨基,炔基硫代,烷基磺酰基,烷基亚砜基,链烯基磺酰基,炔基磺酰基,甲酰基,烷基羰基,羟基羰基,烷氧基羰基,羰基氧基,烷基羰氧基,苯氧基,CONRdRe, S02nNRdRe或C = NORf-GAMMAp-Rf',单环或双环5至10元芳族环系统,5至10元杂芳族环系统或环烷基,各自任选取代,其未融合或稠合至 其键合的芳族基团,当未被取代时,其直接键合或通过O,S,烷基或烷氧基键R 3键合,R 4各自独立地为H,烷基,卤代烷基,烷基胺,烷氧基,环烷基,其中碳 这些脂族基团中的原子可以被取代,或者R3和R4 与其连接的氮原子一起形成饱和或部分饱和的单环或双环5-至10-元环系或5元杂芳基,其中所述环任选被取代并直接键合或经由O,S 或烷基键,和环烯基,其中这些脂族基团中的碳原子可以被取代,并且其中如果R3和R4通过单键与氮键合,则基团NR 3 R 4可以[N + -O-] R 3 R 4氨基氧化物存在 原子和R a,R b,R c,R d,R f,R f',R f,GAMMA和p如说明书中所定义,m为0,1,2,3或4,n为0,1,2,3或 4或其对映异构体或非对映异构体,其盐或酯,以及b农艺学上可接受的载体,通过使作物或目标物种与农药有效量的式I化合物接触来保护作物免受昆虫,蜘蛛和线虫袭击的方法 ,式I化合物及其制备方法。

    INSECTICIDAL AND ACARICIDAL 3-SUBSTITUTED PYRAZOLES
    12.
    发明申请
    INSECTICIDAL AND ACARICIDAL 3-SUBSTITUTED PYRAZOLES 审中-公开
    杀虫剂和杀虫剂3-取代的吡唑

    公开(公告)号:WO2003029222A1

    公开(公告)日:2003-04-10

    申请号:PCT/EP2002/010719

    申请日:2002-09-25

    Abstract: Compounds of formula (I), wherein the variables and the index have the following meanings: R 1 H, halogen, alkyl, haloalkyl, alkenyl, haloalkenyl, alkylthio, alkoxyalkyl, alkylthioalkyl, or optionally substituted phenyl; R 2 H, halogen, alkyl, haloalkyl, alkenyl, haloalkenyl or optionally substituted phenyl; A H, OH, CN, NO 2 , halogen, SCN, alkoxy, haloalkoxy, alkenyloxy, alkylthio, haloalkylthio, alkylsulfinyl, alkylsulfonyl, aminothiocarbonyl, hydroxycarbonyl, alkoxycarbonyl, or aminocarbonyl; B H, OH, NH 2 , CN, NO 2 , halogen, optionally substituted alkyl, optionally substituted alkoxy, optionally substituted alkenyl, alkenyloxy, alkylthio, haloalkylthio, alkoxythiocarbonylthio, alkoxycarbonylalkoxy, alkoxycarbonylalkylthio, alkylsulfinyl, alkylsulfonyl, aminothiocarbonyl, NR 3 R 4 , N=CHOR 5 , or N=CHNR 5 ; R 3 , R 4 H, alkyl, alkoxycarbonylalkyl, [(alkoxycarbonyl)(alkenyl)]alkyl, alkoxycarbonylalkenyl, alkylcarbonyl, cycloalkylcarbonyl, alkylaminocarbonyl, diaminocarbonyl, alkoxycarbonyl, alkoxyaminosulfonyl, or di(alkoxy)aminosulfonyl; R 5 alkyl, haloalkyl, or phenylalkyl; Q H, NO 2 , halogen, haloalkyl, alkylamino, dialkylamino, alkoxy, haloalkoxy, or alkenyloxy; X H, halogen, haloalkyl, alkoxy or haloalkoxy; Y H, halogen, haloalkyl, alkoxy or haloalkoxy; Z H, halogen, haloalkyl, alkoxy or haloalkoxy; M N or CR 6 ; R 6 H, NO 2 , halogen or haloalkyl; n 0, 1, 2, 3, or 4, with the proviso that, when R 1 is hydrogen, n is not zero, processes for the preparation of compounds of formula (I), compositions containing them and their use for the control of insect and acarid pests and for the protection of plants from those pests as well as their use for treating, controlling, preventing and protecting warm-blooded animals and humans against infestation and infection by arachnids and arthropod endo-and ectoparasites.

    Abstract translation: 式(I)化合物,其中变量和指数具有以下含义:R 1 H,卤素,烷基,卤代烷基,烯基,卤代烯基,烷硫基,烷氧基烷基,烷硫基烷基或任选取代的苯基; R 2 H,卤素,烷基,卤代烷基,烯基,卤代烯基或任选取代的苯基; A H,OH,CN,NO 2,卤素,SCN,烷氧基,卤代烷氧基,烯氧基,烷硫基,卤代烷硫基,烷基亚磺酰基,烷基磺酰基,氨基硫代羰基,羟基羰基,烷氧基羰基或氨基羰基。 BH,OH,NH 2,CN,NO 2,卤素,任选取代的烷基,任选取代的烷氧基,任选取代的烯基,烯氧基,烷硫基,卤代烷硫基,烷氧基硫代羰基硫代,烷氧基羰基烷氧基,烷氧基羰基烷硫基,烷基亚磺酰基,烷基磺酰基,氨基硫代羰基,NR 3 R 4 ,N = CHOR 5或N = CHNR 5; R 3,R 4,烷基,烷氧基羰基烷基,[(烷氧基羰基)(烯基)]烷基,烷氧基羰基烯基,烷基羰基,环烷基羰基,烷基氨基羰基,二氨基羰基,烷氧基羰基,烷氧基氨基磺酰基或二(烷氧基)氨基磺酰基; R 5烷基,卤代烷基或苯基烷基; Q H,NO 2,卤素,卤代烷基,烷基氨基,二烷基氨基,烷氧基,卤代烷氧基或烯氧基; X H,卤素,卤代烷基,烷氧基或卤代烷氧基; Y H,卤素,卤代烷基,烷氧基或卤代烷氧基; Z H,卤素,卤代烷基,烷氧基或卤代烷氧基; M N或CR <6>; R 6,H 2,NO 2,卤素或卤代烷基; n为0,1,2,3或4,条件是当R 1为氢时,n不为0,制备式(I)化合物的方法,含有它们的组合物及其用于 控制昆虫和螨类害虫以及保护植物免受这些害虫的侵害,以及用于治疗,控制,预防和保护温血动物和人类免受蜘蛛和节肢动物内寄生虫和外寄生虫侵袭和感染的用途。

    SUBSTITUTED 4-BENZOYL-PYRAZOLES
    13.
    发明申请
    SUBSTITUTED 4-BENZOYL-PYRAZOLES 审中-公开
    取代的4- Benzoylpyrazoles

    公开(公告)号:WO1998029392A1

    公开(公告)日:1998-07-09

    申请号:PCT/EP1997007210

    申请日:1997-12-19

    CPC classification number: A01N43/56 C07D231/24

    Abstract: The invention concerns 4-benzoyl-pyrazoles of formula (I), in which the variables have the following meanings: R , R stand for hydrogen, nitro, halogen, cyano, rhodano, alkyl, halogen alkyl, alkoxyalkyl, alkenyl, alkinyl, -OR , -OCOR , -OSO2R , -SH, -S(O)nR , -SO2OR , -SO2NR R , -NR SO2R or -NR COR ; R stands for hydrogen, cyano, alkyl, halogen alkyl, -OR , -SR or -NR R ; R stands for hydrogen, optionally substituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkinyl, -COR , -CO2R , -COSR or -CONR R ; X stands for oxygen or NR ; n equals 0, 1 or 2; R stands for hydrogen, alkyl, halogen alkyl, alkoxyalkyl, alkenyl or alkinyl; R stands for alkyl or halogen alkyl; R stands for alkyl, halogen alkyl, alkoxyalkyl, alkenyl or alkinyl; R stands for hydrogen or alkyl; R stands for alkyl, alkenyl, alkinyl, phenyl or benzyl; R stands for alkyl, halogen alkyl, alkenyl or alkinyl; Q stands for optionally substituted pyrazol linked in position 4. Also disclosed are the salts of these compounds useful in agriculture; processes and intermediate products for preparing the compounds of formula (I), agents containing the same and the use of these derivatives or agents containing the same for controlling undesirable plants.

    Abstract translation: 本发明涉及式(I),其中各变量具有以下含义的4-苯甲酰基吡唑,R <1>,R <2>为氢,硝基,卤素,氰基,氰硫基,烷基,卤代烷基,烷氧基烷基,烯基,炔 ,-OR <5>,-OCOR <6>,-OSO 2 R <6>,-SH,-S(O)NR <7>,-SO 2 OR <5>,-SO 2 <5> - [R <8>,-NR <8> SO 2 <6>或NR <8> COR <6>; [R <3>是氢,氰基,烷基,卤代烷基,-OR <7>,-SR <7>,或-NR <7> - [R <10>; [R <4>为氢,任选取代的烷基,环烷基,烯基,环烯基,炔基,-COR <9>,-CO 2 R <9>,-COSR <9>或-CONR <8> - [R <9>; X是氧或NR <8>; n为0,1或2; [R <5>是氢,烷基,卤代烷基,烷氧基烷基,链烯基或炔基; [R <6>是烷基或卤代烷基; [R <7>是烷基,卤代烷基,烷氧基烷基,烯基或炔基; [R <8>是氢或烷基; [R <9>是烷基,烯基,炔基,苯基或苄基; [R <10>为烷基,卤代烷基,链烯基或炔基; Q为任选取代的吡唑中的4位被链接; 及其可农用盐; 的方法和中间体用于制备式(I)的化合物; 含有这些组合物; 和使用这些衍生物或组合物的包含它们的防治不希望的植物。

    SUBSTITUTED 2-BENZOYL-CYCLOHEXAN-1,3-DIONES WITH HERBICIDAL EFFECT
    14.
    发明申请
    SUBSTITUTED 2-BENZOYL-CYCLOHEXAN-1,3-DIONES WITH HERBICIDAL EFFECT 审中-公开
    取代的2-苯甲酰基环己烷-1,3-二酮与除草活性

    公开(公告)号:WO1998029384A1

    公开(公告)日:1998-07-09

    申请号:PCT/EP1997007214

    申请日:1997-12-19

    Abstract: The invention concerns 2-benzoyl-cyclohexan-1,3-diones of formula (I), in which R , R stand for hydrogen, nitro, halogen, cyano, rhodano, alkyl, halogen alkyl, alkoxyalkyl, alkenyl, alkinyl, -OR , -OCOR , -OSO2R , -SH, -S(O)nR , -SO2OR , -SO2NR R , -NR SO2R or -NR COR ; R stands for hydrogen, cyano, alkyl, halogen alkyl, -OR , -SR or -NR R ; R stands for hydrogen, optionally substituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkinyl, -COR , -CO2R , -COSR or -CONR R ; X stands for oxygen or NR ; n equals 0, 1 or 2; R stands for hydrogen, alkyl, halogen alkyl, alkoxyalkyl, alkenyl or alkinyl; R stands for alkyl or halogen alkyl; R stands for alkyl, halogen alkyl, alkoxyalkyl, alkenyl or alkinyl; R stands for hydrogen or alkyl; R stands for alkyl, alkenyl, alkinyl, phenyl or benzyl; R stands for alkyl, halogen alkyl, alkenyl or alkinyl; Q stands for an optionally substituted cyclohexan-1,3-dione ring linked in position 2. Also disclosed are the salts of these compounds useful in agriculture; processes and intermediate products for preparing the compounds of formula (I), agents containing the same and the use of these derivatives or agents containing the same for controlling undesirable plants.

    Abstract translation: 本发明涉及式(I)的2-苯甲酰基环己烷-1,3-二酮,其中R <1>,R <2>为氢,硝基,卤素,氰基,氰硫基,烷基,卤代烷基,烷氧基烷基,烯基,炔基, -OR <5>,-OCOR <6>,-OSO 2 R <6>,-SH,-S(O)NR <7>,-SO 2 OR <5>,-SO 2 <5> - [R <8>,-NR < 8> SO 2 <6>或NR <8> COR <6>; [R <3>是氢,氰基,烷基,卤代烷基,-OR <7>,-SR <7>,或-NR <7> - [R <10>; [R <4>为氢,任选取代的烷基,环烷基,烯基,环烯基,炔基,-COR <9>,-CO 2 R <9>,-COSR <9>或-CONR <8> - [R <9>; X是氧或NR <8>; n为0,1或2; [R <5>是氢,烷基,卤代烷基,烷氧基烷基,链烯基或炔基; [R <6>是烷基或卤代烷基; [R <7>是烷基,卤代烷基,烷氧基烷基,烯基或炔基; [R <8>是氢或烷基; [R <9>是烷基,烯基,炔基,苯基或苄基; [R <10>为烷基,卤代烷基,链烯基或炔基; Q在2位上任选取代的联环己烷-1,3-二酮环; 及其可农用盐; 的方法和中间体用于制备式(I)的化合物; 含有这些组合物; 和使用这些衍生物或组合物的包含它们的防治不希望的植物。

    HERBICIDAL HETEROCYCLICALLY SUBSTITUTED BENZOYLISOTHIAZOLES
    15.
    发明申请
    HERBICIDAL HETEROCYCLICALLY SUBSTITUTED BENZOYLISOTHIAZOLES 审中-公开
    除草剂的杂环取代的benzoylisothiazoles

    公开(公告)号:WO1997038996A1

    公开(公告)日:1997-10-23

    申请号:PCT/EP1997001855

    申请日:1997-04-14

    CPC classification number: C07D275/02 A01N43/80 C07D417/10

    Abstract: 4-benzoylisothiazoles have the general formula (1), in which the substituents have the following meanings: X stands for oxygen or sulphur; R stands for hydrogen, alkyl, alkenyl, alkinyl, optionally substituted alkoxycarbonyl, aryl, heterocyclyl or hetaryl; R stands for hydrogen, alkyl, alkenyl, alkinyl, cycloalkyl or cycloalkenyl, whereas these radicals can bear one or several halogen, alkyl, alkenyl or alkinyl groups, or R stands for aryl, hetaryl or heterocyclyl; R stands for a radical of general formula (2), in which Z and the R , R , R and R substituents have the meanings given in claim 1. Also disclosed are the salts commonly used in agriculture of the 4-benzoylisothiazoles of general formula (1), a process for preparing the same and their use as herbicides.

    Abstract translation: 4- benzoylisothiazoles通式(1),其中取代基具有以下含义:X是氧或硫; [R <1>是氢,烷基,烯基,炔基; 未取代的或取代的。 烷; 未取代的或取代的。 的芳基,未取代的或取代的。 杂环基或未取代的或取代的。 杂芳基; [R <2>是氢,烷基,烯基,炔基,环烷基或环烯基,其中这些基团可带有以下基团的一个或多个:卤素,烷基,烯基或炔基; 芳基,杂芳基,或杂环基; [R <3>基为通式(2),其中Z和取代基R <4>,R <5> - [R <6>和R <7>具有权利要求1所示的含义,和农业上常用盐 4- benzoylisothiazoles通式(1)中,它们的制备方法和它们作为除草剂的用途。

    HERBICIDAL BENZOYLISOTHIAZOLES
    16.
    发明申请
    HERBICIDAL BENZOYLISOTHIAZOLES 审中-公开
    除草剂benzoylisothiazoles

    公开(公告)号:WO1997038987A1

    公开(公告)日:1997-10-23

    申请号:PCT/EP1997001854

    申请日:1997-04-14

    CPC classification number: C07D275/03

    Abstract: 4-benzoylisothiazoles have general formula (1), in which the substituents have the following meanings: X stands for oxygen or sulphur; R stands for hydrogen, alkyl, alkenyl, alkinyl, or for optionally substituted alkoxycarbonyl, aryl, heterocyclyl or hetaryl; R stands for hydrogen, alkyl, alkenyl, alkinyl, cycloalkyl or cycloalkenyl, whereas these radicals may bear one or several halogen, alkyl, alkenyl or alkinyl groups, or R stands for aryl, hetaryl or heterocyclyl; and R stands for alkyl, cycloalkyl or a radical of general formula (2), in which the substituents have the meanings indicated in claim 1. Also disclosed are the salts commonly used in agriculture of the 4-benzoylisothiazoles of general formula (1), a process for preparing the same and their use as herbicides.

    Abstract translation: 4- benzoylisothiazoles通式(1),其中取代基具有以下含义:X是氧或硫; [R <1>是氢,烷基,烯基,炔基; 未取代的或取代的。 烷; 未取代的或取代的。 的芳基,未取代的或取代的。 杂环基或未取代的或取代的。 杂芳基; [R <2>是氢,烷基,烯基,炔基,环烷基或环烯基,其中这些基团可带有以下基团的一个或多个:卤素,烷基,烯基或炔基; 芳基,杂芳基,或杂环基; [R <3>是烷基或环烷基,基团,通式(2),其中取代基具有的含义权利要求1中给出,并且的农用常用盐4- benzoylisothiazoles通式(1)中,它们的制备和处理它们的 使用除草剂。

    SACCHARINE DERIVATIVES
    17.
    发明申请
    SACCHARINE DERIVATIVES 审中-公开
    具有除草作用的糖精衍生物

    公开(公告)号:WO1996005198A1

    公开(公告)日:1996-02-22

    申请号:PCT/EP1995002975

    申请日:1995-07-27

    CPC classification number: C07D275/06 A01N43/80 C07D417/06

    Abstract: The invention concerns saccharine derivatives of formula (I) in which the substituents are defined as follows: L, M hydrogen, C1-C4 alkyl, C1-C4 alkoxy, C1-C4 alkylthio, chlorine, cyano, methylsulphonyl, nitro or trifluoromethyl; Z hydrogen, C1-C4 alkyl, C3-C8 cycloalkyl, C3-C6 alkenyl, C3-C5 alkinyl, C1-C4 acyl, benzyl or phenyl, wherein any of the phenyl rings may be substituted by halogen or C1-C4 alkyl; Q a T-J group, T being a carbonyl (CO) group or the -CHY group, J being an isoxazole ring of formula (II) bonded at the 4-position and in which R is hydrogen or C1-C4 alkyl, R is C1-C4 alkyl, cyclopropyl, 1-methylcyclopropyl or 1-methylthiocyclopropyl, Y is an OH-group, a hydroxy group acylated with C2-C4 acyl, or a chlorine atom. The invention also concerns salts of such compounds usually used in agriculture.

    Abstract translation: 糖精的式(I)的衍生物,其中取代基具有以下含义:L,M是氢,C1-C4烷基,C1-C4烷氧基,C1-C4烷硫基,氯,氰基,甲基磺酰基,硝基或三氟甲基; Z是氢,C1-C4烷基,C3-C8环烷基,C3-C6烯基,C3-C5炔基,C1-C4酰基,苄基或苯基,其中在每种情况下,苯环被卤素或C1-C4烷基任选地被取代 组; Q是一个基团TJ,其中T是一个羰基或CO基团-CHY,其中J表示在式I的4-位异恶唑(II),其中R <1>是氢或C1-C4烷基链接 且R <2>代表C1-C4烷基,环丙基,1-甲基环丙基或1- Methylthiocyclopropyl; Y是OH基团,任选地被C 2 -C 4酰基羟基或氯原子酰化; 化合物(I)的和农业上常用盐。

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