METHOD FOR MANUFACTURING A MIXED CATALYST CONTAINING A METAL OXIDE NANOWIRE, AND ELECTRODE AND FUEL CELL INCLUDING A MIXED CATALYST MANUFACTURED BY THE METHOD
    33.
    发明申请
    METHOD FOR MANUFACTURING A MIXED CATALYST CONTAINING A METAL OXIDE NANOWIRE, AND ELECTRODE AND FUEL CELL INCLUDING A MIXED CATALYST MANUFACTURED BY THE METHOD 审中-公开
    制造含有金属氧化物纳米线的混合催化剂的方法以及包括通过该方法制造的混合催化剂的电极和燃料电池

    公开(公告)号:WO2011122757A2

    公开(公告)日:2011-10-06

    申请号:PCT/KR2010008923

    申请日:2010-12-14

    摘要: Provided is a method for manufacturing a mixed catalyst containing a metal oxide nanowire, and an electrode and a fuel cell which include a mixed catalyst manufactured by said method. The method for manufacturing the mixed catalyst comprises the steps of: forming a metal/polymer mixture nanowire by electrospinning a polymer solution containing a first metal precursor and a second metal precursor; forming a metal oxide nanowire by heat-treating the metal/polymer mixture nanowire; and mixing the metal oxide nanowire with active metal nanoparticles. Here, the metal of the second metal precursor is used as a dopant for the metal oxide nanowire. In the event an electrode catalyst layer of a fuel cell is formed using the manufactured mixed catalyst, the fuel cell has the advantages of significantly improved performance and reduced costs in generating electricity.

    摘要翻译: 本发明提供一种含有金属氧化物纳米线的混合催化剂的制造方法以及包含由该方法制造的混合催化剂的电极和燃料电池。 用于制造混合催化剂的方法包括以下步骤:通过静电纺丝包含第一金属前体和第二金属前体的聚合物溶液形成金属/聚合物混合物纳米线; 通过热处理金属/聚合物混合物纳米线形成金属氧化物纳米线; 并将金属氧化物纳米线与活性金属纳米颗粒混合。 这里,第二金属前体的金属用作金属氧化物纳米线的掺杂剂。 在使用制造的混合催化剂形成燃料电池的电极催化剂层的情况下,燃料电池具有显着改进的性能和降低发电成本的优点。

    METHOD FOR PREPARING A MULTI-METAL CATALYST HAVING AN OPTIMIZED SITE PROXIMITY
    36.
    发明申请
    METHOD FOR PREPARING A MULTI-METAL CATALYST HAVING AN OPTIMIZED SITE PROXIMITY 审中-公开
    制备具有优化现场接近度的多金属催化剂的方法

    公开(公告)号:WO2011012776A2

    公开(公告)日:2011-02-03

    申请号:PCT/FR2010000443

    申请日:2010-06-15

    摘要: The invention relates to a method for preparing a catalyst including at least one metal M of the platinum group, tin, a phosphorus promoter, a halide compound, a porous substrate, and at least one promoter X1 selected from the group comprising gallium, indium, thallium, arsenic, antimony and bismuth. The X1 promoter(s) and the phosphorus are added during one or more sub-steps a1) or a2), the sub-step a1) corresponding to the synthesis of the precursor of the dominant oxide and the sub-step a2) corresponding to the shaping of the substrate. The tin is added during one at least of the sub-steps a1) and a2). The product is dried and calcinated before depositing at least one metal M of the platinum group. The assembly is then dried under a neutral gas flow or an oxygen-containing gas flow and further calcinated. The invention also relates to the use of the catalyst obtained by said method in catalytic-reforming or aromatic production reactions.

    摘要翻译: 本发明涉及一种制备催化剂的方法,所述催化剂包括至少一种铂族金属M,锡,磷促进剂,卤化物,多孔底物和至少一种选自镓,铟, 铊,砷,锑和铋。 在一个或多个子步骤a1)或a2)期间添加X1启动子和磷,对应于主要氧化物的前体的合成的子步骤a1)和对应于 基材的成型。 在一个至少子步骤a1)和a2)中添加锡。 在沉积至少一种铂族金属M之前,将产物干燥并煅烧。 然后将组件在中性气流或含氧气体流下干燥并进一步煅烧。 本发明还涉及通过所述方法获得的催化剂在催化重整或芳族生产反应中的用途。