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公开(公告)号：WO2019134870A1
公开(公告)日：2019-07-11
申请号：PCT/EP2018/086824
申请日：2018-12-21
CPC分类号： C07C2/84 , C07C5/48 , C10G9/36 , C10G50/00 , C10G57/02 , C10G2400/20 , C10G2400/22 , C07C9/06 , C07C11/04
摘要： Die Erfindung betrifft ein Verfahren zur Gewinnung eines oder mehrerer Olefine, bei dem ein Methan und Sauerstoff enthaltendes Einsatzgemisch (1) einer oder mehreren katalytischen Zonen (11) eines oder mehrerer Reaktoren (10) zugeführt werden, wobei die eine oder die mehreren katalytischen Zonen (11) einen Katalysator zur oxidativen Kopplung von Methan aufweisen, wobei der einen oder den mehreren katalytischen Zonen (11) ein Gasgemisch entnommen wird und zumindest teilweise in eine oder mehrere nichtkatalytische Zonen (12) des einen oder der mehreren Reaktoren (10) überführt wird, wobei in die eine oder die mehrere nichtkatalytischen Zonen (12) ein oder mehrere Paraffine eingespeist werden, und wobei das eine oder die mehreren in die eine oder in die mehreren nichtkatalytischen Zonen (12) eingespeisten Paraffine in der einen oder in den mehreren nichtkatalytischen Zonen (12) teilweise durch eine Dampfspaltreaktion zu einem oder mehreren Olefinen umgesetzt werden. Es ist vorgesehen, dass das eine oder die mehreren Paraffine an einer oder an mehreren von mehreren unterschiedlichen Einspeisepositionen (13a, 13b, 13c), die während der Durchführung des Verfahrens in Abhängigkeit von einer vorgegebenen Konversion des einen oder der mehreren Paraffine ausgewählt wird oder werden, in die eine oder die mehreren nichtkatalytischen Zonen (12) eingespeist werden. Eine entsprechende Anlage (100) ist ebenfalls Gegenstand der Erfindung.
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公开(公告)号：WO2019104778A1
公开(公告)日：2019-06-06
申请号：PCT/CN2017/117561
申请日：2017-12-20
申请人： 中国科学院大连化学物理研究所
CPC分类号： B01J29/06 , B01J29/70 , B01J29/83 , B01J29/84 , B01J29/85 , C07C1/20 , C07C11/04 , C07C11/06
摘要： 一种催化剂，其含有分子筛，分子筛结构中具有至少一维8元环小孔通道，该8元环通道方向可扩散物质的直径不小于2.0Å，分子筛结构中可容纳物质直径不超过6Å。该催化剂用于甲醇和/或二甲醚制丙烯反应，包括将甲醇和/或二甲醚与甲醇制丙烯催化剂接触，得到丙烯。
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公开(公告)号：WO2019102305A1
公开(公告)日：2019-05-31
申请号：PCT/IB2018/058931
申请日：2018-11-13
摘要： Methods and systems for improving energy conversion from the heat available in a hydrocarbon feedstream during the production of olefins. In a particular non-limiting embodiment, a method can include increasing the temperature of a hydrocarbon feedstream and a hydrogen gas feedstream via a first heat exchanger; combining and feeding the feedstreams into a reactor to produce a reactor effluent including one or more olefins; expanding the reactor effluent in a reactor effluent expander to decrease the pressure and/or temperature of the reactor effluent; transferring the reactor effluent to the heat exchanger to increase the temperature of the feedstreams and/or decrease the temperature of the reactor effluent; and compressing the reactor effluent in a compressor, where the expansion of the reactor effluent drives the compressor.
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公开(公告)号：WO2019092668A1
公开(公告)日：2019-05-16
申请号：PCT/IB2018/058876
申请日：2018-11-12
摘要： Methods and systems for improving energy conversion from the heat available in a hydrocarbon feedstream during the production of olefins. In a particular non-limiting embodiment, the method can include increasing the temperature of a hydrocarbon feedstream and a hydrogen gas feedstream via a first heat exchanger; combining the feedstreams and expanding the combined feedstream in an expander to decrease the pressure and/or temperature of the combined feedstream; increasing the temperature of the combined feedstream via a second heat exchanger; feeding the combined feedstream into a reactor to produce a reactor effluent; decreasing the temperature of the reactor effluent; and compressing the reactor effluent in a compressor, where the expansion of the combined feedstream drives the compressor.
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公开(公告)号：WO2019083846A1
公开(公告)日：2019-05-02
申请号：PCT/US2018/056727
申请日：2018-10-19
发明人： LEYSHON, David W.
CPC分类号： C07C1/22 , B01J21/16 , B01J29/85 , C07C1/20 , C07C1/24 , C07C4/06 , C07C2521/08 , C07C2521/16 , C07C2527/173 , C07C2529/40 , C07C2529/82 , C10G3/49 , C10G11/05 , C10G2400/20 , C07C11/04 , C07C11/06 , C07C11/08
摘要： Methods of producing at least one of ethylene and propylene. The methods may include contacting a mixture of C4+ compounds with a catalyst to convert at least a portion of the C4+ compounds to at least one of ethylene and propylene. The catalyst can include a phosphorus treated zeolite, and the mixture of C4+ compounds can include at least one of t-butyl alcohol and methyl t-butyl ether.
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公开(公告)号：WO2019060153A1
公开(公告)日：2019-03-28
申请号：PCT/US2018/050185
申请日：2018-09-10
申请人： UOP LLC
发明人： MONTALBANO, Joseph , LECHNICK, W. Jay , ZHU, Xin X
CPC分类号： B01D53/225 , B01D53/002 , B01D53/047 , B01D53/1406 , B01D53/864 , B01D2257/304 , B01D2257/308 , B01D2257/504 , B01D2257/7022 , B01D2257/80 , C01B3/50 , C01B3/52 , C01B2203/0233 , C01B2203/043 , C01B2203/046 , C01B2203/048 , C01B2203/0827 , C07C4/02 , C07C5/08 , C07C5/09 , C07C5/327 , C07C7/005 , C07C7/04 , C07C7/09 , C07C7/11 , C07C7/12 , C07C7/144 , C07C7/148 , C07C7/167 , C07C9/04 , C07C2523/755 , Y02C10/10 , Y02P20/152 , Y02P20/51 , C07C9/06 , C07C11/04 , C07C9/08 , C07C11/06
摘要： A process for recovering a steam cracking feed from FCC absorber off-gas comprising ethylene, ethane and heavier hydrocarbons and light gases involves removing hydrogen, nitrogen, sulfur species, carbon monoxide/dioxide, methane and other impurities from the off-gas. An absorption zone is upstream of an acetylene selective hydrotreating reactor to remove sufficient hydrogen sulfide that can poison the selective hydrotreating catalyst but leave sufficient sulfur in the feed stream to prevent temperature runaway.
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公开(公告)号：WO2018208679A1
公开(公告)日：2018-11-15
申请号：PCT/US2018/031408
申请日：2018-05-07
发明人： RUMORE, Nicole , ASLAM, Naveed
IPC分类号： F25J3/06
CPC分类号： C07C7/09 , B01D5/0003 , B01D5/0036 , C10G70/043 , F25J3/062 , F25J3/064 , F25J3/066 , F25J3/0695 , F25J2210/12 , F25J2210/42 , F25J2220/02 , F25J2245/42 , F25J2270/60 , F25J2270/904 , F25J2270/908 , F25J2280/10 , F25J2280/20 , C07C11/04 , C07C11/06
摘要： Methods and systems for recovering alkenes (e.g. ethylene, propylene) and nitrogen from process gas streams, including multi-step condensing of the process gas stream, are provided herein.
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8.发明申请
公开(公告)号：WO2018202828A1
公开(公告)日：2018-11-08
申请号：PCT/EP2018/061454
申请日：2018-05-04
申请人： BOREALIS AG
IPC分类号： C07C1/12 , C07C2/84 , C07C4/06 , C07C5/327 , C07C5/333 , C07C9/04 , C07C9/06 , C07C11/04 , C07C11/06
CPC分类号： C07C1/12 , C07C2/84 , C07C4/06 , C07C5/327 , C07C5/3332 , C07C5/3335 , C07C5/3337 , C07C7/04 , C07C7/09 , C07C2523/02 , C07C2523/14 , C07C2523/16 , C07C2523/26 , C07C2523/42 , C07C2523/62 , C07C2523/74 , C07C2523/755 , C07C9/04 , C07C11/04 , C07C9/06 , C07C11/06 , C07C9/08
摘要： The present invention relates to a process for oxidative coupling of methane (OCM, 100) comprising the steps of feeding methane (104) and at least one oxidizing agent (103), preferably oxygen, into at least one OCM reactor (101) comprising at least one OCM catalyst, wherein C 2+ alkene is generated from methane by the OCM catalyst; wherein at least part of the methane (104) is provided by at least one methanation unit (111), in which hydrogen and carbon dioxide are reacted to methane, wherein at least part of the hydrogen fed to the methanation unit (111) is provided from a hydrogen stream (211) generated in a propane dehydrogenation process (200), and/or wherein ethane (105) is fed into the at least one OCM reactor (101) comprising further at least one cracking unit, wherein C 2+ alkene is generated from ethane in the cracking unit, wherein at least part of the ethane (105) is provided from ethane (213) generated in a propane dehydrogenation process (200). The invention also relates to a process system for such a process.
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公开(公告)号：WO2018170263A1
公开(公告)日：2018-09-20
申请号：PCT/US2018/022633
申请日：2018-03-15
申请人： SABIC GLOBAL TECHNOLOGIES, B.V. , MAMEDOV, Aghaddin , NAIR, Balamurali , GAUTAM, Pankaj S. , PANNALA, Sreekanth , SANKARANARAYANAN, Krishnan
发明人： MAMEDOV, Aghaddin , NAIR, Balamurali , GAUTAM, Pankaj S. , PANNALA, Sreekanth , SANKARANARAYANAN, Krishnan
CPC分类号： C07C2/82 , C07C2/78 , C07C5/09 , C07C5/42 , C07C5/52 , C07C29/1518 , Y02P20/52 , Y02P30/42 , C07C11/24 , C07C11/04 , C07C31/04
摘要： A process for producing ethylene comprising introducing fuel and oxidant gas to combustion zone to produce combustion product; introducing first reactants (hydrocarbons, combustion product) to first reaction zone to produce pyrolysis product (unconverted hydrocarbons, C 2 H 2 , CO, H 2 , CO 2 , optionally C 2 H 4 ), wherein combustion product heats hydrocarbons to first temperature effective for pyrolysis; cooling pyrolysis product in quench zone to produce cooled pyrolysis product having second temperature lower than first temperature; introducing second reactants (C 2 H 6 , cooled pyrolysis product) to second reaction zone excluding catalyst to produce second product (C 2 H 4 , CO, H 2 , C 2 H 2 , CO 2 , unconverted hydrocarbons), wherein C 2 H 6 dehydrogenates to C 2 H 4 , wherein CO 2 hydrogenates to CO, wherein C 2 H 4 amount in second product is greater than in pyrolysis product, wherein second product is characterized by third temperature lower than second temperature; separating second product into C 2 H 4 &C 2 H 2 stream (C 2 H 4 , C 2 H 2 , CO, H 2 , unconverted hydrocarbons) and CO 2 stream; and recycling CO 2 stream to second reaction zone.
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公开(公告)号：WO2018114747A1
公开(公告)日：2018-06-28
申请号：PCT/EP2017/083218
申请日：2017-12-18
IPC分类号： C07C5/48 , C07C11/04 , C07C51/215 , C07C53/08 , C07C51/25 , C07C67/055 , C07C69/15 , C07C67/52
CPC分类号： C07C5/48 , C07C51/215 , C07C51/25 , C07C67/055 , C07C67/52 , Y02P20/125 , C07C11/04 , C07C53/08 , C07C69/15
摘要： The invention relates to an integrated process for the production of ethylene and vinyl acetate (VAM), comprising contacting in a first reaction zone a gas stream comprising ethane and optionally ethylene with an oxygen- containing gas stream in the presence of a dehydrogenation catalyst under oxidative dehydrogenation conditions to produce a first product stream comprising ethane, ethylene, acetic acid and water, and optionally other compounds, separating said first product stream in a first separation zone into a second stream comprising acetic acid and optionally water and a third stream comprising ethane, ethylene and optionally water, optionally concentrating the second stream comprising acetic acid, optionally dewatering said third stream in a dewatering zone to produce a dewatered fourth stream comprising ethane and ethylene, contacting in a second reaction zone said third stream or said dewatered fourth stream comprising ethane and ethylene with a stream comprising concentrated acetic acid and with an oxygen-containing gas stream in the presence of a VAM catalyst, to produce a fifth product stream comprising vinyl acetate, water, ethane, ethylene, and optionally other compounds, and recovering vinyl acetate and ethylene from said fifth product stream, wherein all or at least a portion of the second stream comprising acetic acid is used to recover vinyl acetate from the fifth product stream. The invention further relates to a reaction system for carrying out the process.
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