Abstract:
A method for manufacturing a honeycomb structure comprises providing an aqueous ceramic solution, providing a batch cross-link agent, mixing the agent with the solution, extruding the aqueous ceramic solution containing the cross-link agent into a honeycomb structure, and drying the honeycomb structure via a single drying step thereby forming a hardened, substantially water resistant, honeycomb structure. The method may further comprise addition of a ceramic surfactant to the aqueous ceramic solution, as well as plugging channels within the honeycomb structure with a plugging material comprising an aqueous ceramic solution that includes batch cross-link agents and ceramic surfactants therein. Also disclosed is a green body honeycomb article having a green honeycomb matrix containing a first ceramic batch compound of inorganic constituents, a first batch cross-link agent, and an aqueous vehicle wherein the matrix includes interconnected walls forming open-ended channels and a plugging material located in at least one of the open-ended channels.
Abstract:
Disclosed are ceramic articles, which in one aspect are composed predominately of a cordierite having a composition close to that of Mg 2 Al 4 Si 5 O 18 . The ceramic articles possess a microstructure characterized by a unique combination of relatively high porosity and relatively narrow pore size distribution, both as measured by mercury porosimetry, that render the ceramic structure useful for ceramic filter applications requiring high thermal durability and high filtration efficiency coupled with low pressure drop along the length of the filter. Such ceramic bodies are particularly well suited for filtration applications, such as diesel exhaust filters or DPFs. Also disclosed are methods for the manufacture of the ceramic articles described herein.
Abstract:
The present invention relates generally to mercaptofunctional high μβ EO chromophores and EO polymers, and particularly to mercaptofunctional high μβ EO chromophores and EO polymers useful for making electro-optical devices and systems. Mercaptofunctional high μβ EO chromophores are covalently bonded to poly(imido sulfide) polymers producing high Tg, low optical loss, covalently bonded, high μβ EO chromophore containing polymers. Methods of synthesizing these EO materials using mild polymerization conditions are also described.
Abstract:
A porous ceramic honeycomb filter manufactured from an oxide-based ceramic material having a pore size distribution with d1 7.0 microns. Preferably, the oxide-based material is cordierite or aluminum titanate. Alternatively, the filter contains a cordierite-containing ceramic body with a narrow pore size distribution with db 1.00, wherein db = (d90 - d10) / d50. Also disclosed is a batch mixture, method and honeycomb green body made from mixture of inorganic source materials selected from the group of magnesia sources, alumina sources, and silica sources, and a pore former having a narrow particle size distribution with dps 0.90, wherein dps = {(dp90-dp10)/dp50}. The pore former is preferably selected from a group consisting of canna starch, sago palm starch, green mung bean starch, and single-mode potato starch.
Abstract:
Porous ceramic catalyst supports or filters to be provided with catalyst coatings via oxide washcoating processes are pre-coated with polymer barrier layers to prevent washcoat nanoparticle intrusion into the microcracked and/or microporous surfaces of the ceramics, the barrier coatings being formed of hydrocarbon polymers that are soluble or dispersible in polar media, capable of forming neutral or hydrophilic surfaces on porous ceramic supports, and completely vaporizable at moderate washcoat stabilization or catalyst activation temperatures.
Abstract:
Methods of forming low molecular weight oligomers of aniline-based compounds are provided as well as methods of forming varied molecular weight oligomers and polymers that are aniline-based which are end-functionalized and capable of being reacted with other monomeric species to form a variety of copolymers. The oligomers, end-functionalized oligomers and copolymers exhibit corrosion-resistant properties and provide corrosion-resistant compounds for use on various substrates.