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公开(公告)号:WO2023088861A1
公开(公告)日:2023-05-25
申请号:PCT/EP2022/081882
申请日:2022-11-15
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: BRITA, Diego , GUIDOTTI, Simona , LIGUORI, Dario , MENICHELLI, Francesco , NAGY, Sandor , HALLINAN, Noel C.
IPC: B01J23/30 , C07C4/22 , C10G1/10 , C08J11/16 , C08F8/50 , C08J11/12 , B01J23/888 , B01J27/188 , B01J27/19
Abstract: A method of depolymerizing plastic waste using a supported heteropolyacids catalyst is described herein. The method provides with high efficiency a high quality liquid depolymerization product usable as cracker feedstock.
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公开(公告)号:WO2022152464A1
公开(公告)日:2022-07-21
申请号:PCT/EP2021/084064
申请日:2021-12-02
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: MASSARI, Paola , FELISATI, Andrea , CAVALIERI, Claudio , GALVAN, Monica , GRAZZI, Michele
Abstract: A polymer composition comprising: A) from 70 wt% to 95 wt% of a propylene composition comprising: A1) from 15 wt% to 35 wt% of a propylene 1-butene copolymer A2) from 65 wt% to 85 wt% of a propylene ethylene 1-butene terpolymer B) from 5.0 wt% to 30.0 wt% of a copolymer of 1-butene and ethylene containing from 3.0 wt% to 4.2 wt% of ethylene derived units the sum of the amounts of A) and B) being 100 wt%.
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公开(公告)号:WO2022122596A2
公开(公告)日:2022-06-16
申请号:PCT/EP2021/084260
申请日:2021-12-03
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: NAGY, Sandor , WHITE, Daniel F. , SMITH, Christopher D. , RAMAGE, David L. , BRITA, Diego , HALLINAN, Noel C.
IPC: B01J27/16 , B01J27/18 , B01J29/08 , B01J29/40 , B01J29/70 , B01J27/232 , C08J11/16 , B01J21/16 , B01J21/04 , C10G11/05 , C10G47/12 , C10G47/16 , B01J2229/42 , B01J27/1802 , B01J29/084 , B01J29/085 , B01J29/088 , B01J29/405 , B01J29/7007 , B01J29/7057 , C08J2323/02 , C08J2323/06 , C08J2323/12 , C10G1/086
Abstract: Catalytic compositions for depolymerizing polyolefin-based waste material into useful petrochemical products and methods of use are described. The compositions are a composite of at least one zeolite catalyst with one or more co-catalyst(s) that is a solid inorganic material. These composite catalysts, along with heat, are used to both increase the depolymerization reaction rate of the feed streams and suppress poisoning effects of non-polyolefin polymers that may be present. This results in a shorter residence time in the depolymerization unit and more efficient process.
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公开(公告)号:WO2022002601A1
公开(公告)日:2022-01-06
申请号:PCT/EP2021/066329
申请日:2021-06-17
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: CAVALIERI, Claudio , GALVAN, Monica
IPC: C08L23/12 , C08L2203/18 , C08L2205/03 , C08L2207/20
Abstract: A polypropylene composition comprising (percentage by weight unless otherwise specified): (a) 65 to 85%, of a crystalline propylene polymer having an amount of isotactic pentads (mmmm), measured by 13C-MNR on the fraction insoluble in xylene at 25° C, higher than 97.0 molar% and a polydispersity index ranging from 3 to 15; (b) 5 to 25% of an elastomeric copolymer of ethylene and propylene, the copolymer having an amount of recurring units deriving from ethylene ranging from 30 to 70%, and being partially soluble in xylene at ambient temperature; the polymer fraction soluble in xylene at ambient temperature having an intrinsic viscosity value ranging from 2 to 8 dl/g; and (c) 5 to 25% of recycled polyethylene (r-PE) having a melt flow rate (190°C/2.16 Kg) from 0.1 to 10 g/10', the whole composition having a value of melt flow rate (ISO 1133 230°C/2.16 kg) ranging from 0.1 to 3.0 g/10 min; the percentages of (a), (b) and (c) being referred to the sum of (a), (b) and (c).
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公开(公告)号:WO2021213960A1
公开(公告)日:2021-10-28
申请号:PCT/EP2021/060035
申请日:2021-04-19
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: GALVAN, Monica , CAVALIERI, Claudio , BIONDINI, Gisella , BAUDIER, Vincent
Abstract: Asphalt product comprising Z1) from 90 wt% to 98 wt% of mineral aggregate; Z2) From 2 wt% to 10 wt% of a bitumen composition comprising: T1) from 99 wt% to 75 wt% of bitumen, and T2) from 1 wt% to 25 wt% of polymer composition comprising the following components, A) 5-35% by weight of a propylene homopolymer; B) 20-50% by weight; of an ethylene homopolymer; and C) 30-60% by weight of a terpolymer of ethylene, propylene and 1-butene derived units.
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公开(公告)号:WO2021165045A1
公开(公告)日:2021-08-26
申请号:PCT/EP2021/052610
申请日:2021-02-04
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: CAVALIERI, Claudio , BURGIN, Emanuele , GALVAN, Monica , BÖHM, Thomas
IPC: C08L23/04
Abstract: A polypropylene compositions comprising: T1) 35-65wt%, of a recycled polypropylene mixture containing at least 80 wt% of polypropylene items and having a purity of at least 90 wt%. T2) 20-50 wt% of a an ethylene propylene copolymer T3) 5-20 wt% of a propylene, ethylene copolymer composition comprising: a) from 12 wt% to 52 wt% of a propylene homopolymer or a propylene/ethylene copolymer; b) from 48 wt% to 88 wt% of a propylene ethylene copolymer having a content of ethylene derived units ranging from 15 wt% to 42 wt%; wherein the propylene composition has a melt flow rate (ISO 1133 230°C/2.16 kg) ranging from 0.5 to 20 g/10 min.
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公开(公告)号:WO2021099123A1
公开(公告)日:2021-05-27
申请号:PCT/EP2020/081034
申请日:2020-11-05
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: BRITA, Diego , COLLINA, Gianni , EVANGELISTI, Daniele , GADDI, Benedetta , GESSI, Piero , MORINI, Giampiero , SOFFRITTI, Silvia , VINCENZI, Paolo
Abstract: A process for preparing a catalyst component comprising Mg, Ti, and at least an electron donor compound (ID) said process comprising two or more steps of reaction in which in a first step (a) carried out at a temperature ranging from 0 to 150°C, a Mg based compound is reacted with a Ti compound, having at least a Ti-Cl bond, in an amount such that the Ti/Mg molar ratio is greater than 3 so as to generate an intermediate solid catalyst component containing Mg and Ti and, in a following step (b), the intermediate solid catalyst component (a) is contacted, in a gaseous dispersing medium, with a gaseous stream containing the electron donor compound (ID) thereby obtaining a final solid catalyst component having an ID/Ti molar ratio ranging from 0.5:1 to 20:1.
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公开(公告)号:WO2021037851A1
公开(公告)日:2021-03-04
申请号:PCT/EP2020/073754
申请日:2020-08-25
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: NAGY, Sandor , SMITH, Christopher D. , YANG, Xueyong , WHITE, Daniel F. , DAVIS, Sheri E. , MIHAN, Shahram , FRAAIJE, Volker
Abstract: A method of depolymerizing plastics using a fluorinated alumina catalyst is described herein. The method reduces the energy required for the depolymerization process while achieving improved depolymerization results.
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公开(公告)号:WO2021001232A1
公开(公告)日:2021-01-07
申请号:PCT/EP2020/067640
申请日:2020-06-24
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: MIGNOGNA, Alessandro , LIGUORI, Dario , MORINI, Giampiero
IPC: C08F4/651 , C08F110/06 , C08F4/654
Abstract: A solid catalyst component for the polymerization of olefins comprising Mg, Ti and a an electron donor of formula (I) where the R 1 and R 5 groups, equal to or different from each other, are selected from C 1 -C 15 hydrocarbon groups, R 2 group is selected from C 2 -C 10 hydrocarbon groups, R 3 to R 4 groups, independently, are selected from hydrogen or C 1 -C 20 hydrocarbon groups, optionally fused together to form one or more cycles, with the proviso that at least one of R 3 to R 4 groups is a C 1 -C 20 alkyl group. The catalyst system based on the solid catalyst component is endowed with high activity and stereospecificity.
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公开(公告)号:WO2020249387A1
公开(公告)日:2020-12-17
申请号:PCT/EP2020/064489
申请日:2020-05-26
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: DE PALO, Roberto , LEMAIRE, Renaud , MARTI PORQUERES, Jaume
IPC: D01F6/30 , C08F210/06 , D01F8/06
Abstract: A skin-core fiber wherein the skin comprises a propylene ethylene copolymer having: : i) xylene soluble fraction from 14 wt% to 27 wt% ii) intrinsic viscosity of the fraction soluble in xylene at 25°C from 1.0 to 2.4 dl/g; iii) melt flow rate, MFR, from 1.0 g/10 min to 50.0 g/10 min; iv) an ethylene content from 5.0 wt% to 12.0 wt% v) the ethylene content on the fraction insoluble in xylene from 2.5 wt% to 6.0 wt%; vi) the ethylene content on the fraction soluble in xylene ranging from 15.2. wt% to 30.2 wt% vii) the C 13 NMR sequences PEP on the fraction insoluble in xylene from 3.5mol% to 5.5mol% and the sequences PEP on the fraction soluble in xylene from 11.0 mol% to 14.2 mol%; the core of the fiber comprises a polyethylene having a density between 0.940 g/cm 3 to 0.975 g/cm 3 .
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