公开(公告)号：WO2006073867A1

公开(公告)日：2006-07-13

申请号：PCT/US2005/046594

申请日：2005-12-22

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  JING, Naiyong ,  CAO, Chuntao ,  FUKUSHI, Tatsuo ,  TATGE, Timothy, J. ,  COGGIO, William, D. ,  WALKER, Christopher, B., Jr. ,  KLUN, Thomas, P. ,  SCHULTZ, William, J. ,  QIU, Zai-Ming

Inventor： JING, Naiyong ,  CAO, Chuntao ,  FUKUSHI, Tatsuo ,  TATGE, Timothy, J. ,  COGGIO, William, D. ,  WALKER, Christopher, B., Jr. ,  KLUN, Thomas, P. ,  SCHULTZ, William, J. ,  QIU, Zai-Ming

IPC: G02B1/10 ,  G02B1/11

CPC classification number: G02B1/111 ,  Y10T428/24942 ,  Y10T428/3154 ,  Y10T428/31663

Abstract: An economic, optically transmissive, stain and ink repellent, durable low refractive index fluoropolymer composition for use in an antireflection film or coupled to an optical display. In one aspect of the invention, the composition is formed from the reaction product of a fluoropolymer or reactive fluoropolymer, an amino silane ester coupling agent or ester equivalent, a multi-olefinic crosslinker, and optional surface modified inorganic particles or sol gel precursors.

Abstract translation: 用于抗反射膜或耦合到光学显示器的经济，光学透射，防污和防油墨，耐用的低折射率含氟聚合物组合物。 在本发明的一个方面，组合物由含氟聚合物或反应性含氟聚合物，氨基硅烷酯偶联剂或酯当量的反应产物，多烯属交联剂和任选的表面改性的无机颗粒或溶胶凝胶前体形成。

公开(公告)号：WO2006073918A1

公开(公告)日：2006-07-13

申请号：PCT/US2005/046979

申请日：2005-12-21

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  JING, Naiyong ,  CAO, Chuntao ,  FUKUSHI, Tatsuo ,  TATGE, Timothy J. ,  WALKER, Christopher B., Jr. ,  KLUN, Thomas, P. ,  SCHULTZ, William J. ,  QIU, Zai-ming

Inventor： JING, Naiyong ,  CAO, Chuntao ,  FUKUSHI, Tatsuo ,  TATGE, Timothy J. ,  WALKER, Christopher B., Jr. ,  KLUN, Thomas, P. ,  SCHULTZ, William J. ,  QIU, Zai-ming

IPC: G02B1/04 ,  C08F220/22 ,  G02B1/10 ,  G02B1/11 ,  C08F283/12

CPC classification number: G02B1/111 ,  A63B37/0004 ,  Y10T428/269

Abstract: An economic, optically transmissive, stain and ink repellent, durable low refractive index fluoropolymer composition for use in an antireflection film or coupled to an optical display. In one aspect of the invention, the composition is formed from the reaction product of a fluoropolymer and a fluoroalkyl containing multi-olefinic crosslinker. In another aspect of the invention, the composition further includes surface modified inorganic nanoparticles.

Abstract translation: 用于抗反射膜或耦合到光学显示器的经济，光学透射，防污和防油墨，耐用的低折射率含氟聚合物组合物。 在本发明的一个方面，组合物是由含氟聚合物和含氟烷基的多烯烃交联剂的反应产物形成的。 在本发明的另一方面，组合物还包括表面改性的无机纳米颗粒。

公开(公告)号：WO2006073785A1

公开(公告)日：2006-07-13

申请号：PCT/US2005/046010

申请日：2005-12-19

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  JING, Naiyong ,  COGGIO, William D., ,  KLUN, Thomas P., ,  MOORE, George G. I., ,  WANG, Sharon ,  LIU, Lan H., ,  NOYOLA, Joan M., ,  SAVU, Patricia M., ,  CAO, Chuntao

Inventor： COGGIO, William D., ,  KLUN, Thomas P., ,  MOORE, George G. I., ,  WANG, Sharon ,  LIU, Lan H., ,  NOYOLA, Joan M., ,  SAVU, Patricia M., ,  CAO, Chuntao

IPC: G02B1/11 ,  G02B1/10

CPC classification number: C08F14/18 ,  C08F259/08 ,  C08F283/00 ,  C08L51/003 ,  C09D151/003 ,  G02B1/111 ,  Y10T428/24942 ,  Y10T428/259 ,  Y10T428/3154 ,  Y10T428/31544 ,  Y10T428/31935 ,  C08F2/00 ,  C08L2666/02

Abstract: A low refractive index composition that forms a low refractive index layer on an optical display is formed having a co-crosslinked interpenetrating polymer network of a fluoropolymer phase and an acrylate phase. The fluoropolymer phase is preferably formed from fluoropolymers based on THV or FKM and having either a degree of unsaturation and/or containing a reactive cure site monomer in its polymer backbone. The acrylate phase includes a multifunctional acrylate crosslinker, and more preferably includes a perfluoropolyether acrylate crosslinker. The formed low refractive index layer has improved interfacial adhesion to other layers or substrates contained in the optical display. Further, the mechanical strength and scratch resistance of the either of above low refractive index compositions can be further enhanced through the incorporation of surface functionalized inorganic particle into the formed layer.

Abstract translation: 形成在光学显示器上形成低折射率层的低折射率组合物，其具有含氟聚合物相和丙烯酸酯相的共交联互穿聚合物网络。 含氟聚合物相优选由基于THV或FKM的含氟聚合物形成，并且在其聚合物主链中具有不饱和度和/或含有反应性固化位点单体。 丙烯酸酯相包括多官能丙烯酸酯交联剂，更优选包括全氟聚醚丙烯酸酯交联剂。 所形成的低折射率层对包含在光学显示器中的其它层或基底具有改善的界面粘合性。 此外，通过将表面官能化的无机颗粒并入成形层，可以进一步提高上述低折射率组合物中的任一种的机械强度和耐划伤性。

公开(公告)号：WO2012112321A3

公开(公告)日：2012-11-08

申请号：PCT/US2012023911

申请日：2012-02-06

Applicant: 3M INNOVATIVE PROPERTIES CO ,  ABUELYAMAN AHMED S ,  ECKERT ADRIAN S ,  MITRA SUMITA B ,  DUNBAR TIMOTHY D ,  CRAIG BRADLEY D ,  CAO CHUNTAO

Inventor： ABUELYAMAN AHMED S ,  ECKERT ADRIAN S ,  MITRA SUMITA B ,  DUNBAR TIMOTHY D ,  CRAIG BRADLEY D ,  CAO CHUNTAO

IPC: A61K6/083 ,  A61K6/00 ,  A61K6/09

CPC classification number: A61K6/083 ,  A61K6/0005 ,  A61K6/0008 ,  A61K6/0061 ,  A61K6/0073 ,  A61K6/09 ,  C08L33/08 ,  C08L33/10

Abstract: Hardenable compositions are described comprising at least one multifunctional ethylenically unsaturated isocyanurate monomer and at least one multifunctional ethylenically unsaturated tricyclodecane monomer. In favored embodiments, the compositions further comprise filler and are suitable dental restorations.

Abstract translation: 描述了包含至少一种多官能烯键式不饱和异氰脲酸酯单体和至少一种多官能烯键式不饱和三环癸烷单体的可硬化组合物。 在有利的实施方案中，组合物还包含填充剂并且是合适的牙科修复体。

公开(公告)号：WO2012112350A3

公开(公告)日：2012-08-23

申请号：PCT/US2012/024222

申请日：2012-02-08

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  JOLY, Guy D. ,  KREPSKI, Larry R. ,  GADDAM, Babu N. ,  ABUELYAMAN, Ahmed S. ,  CRAIG, Bradley D. ,  DUNBAR, Timothy D. ,  CAO, Chuntao ,  OXMAN, Joel D. ,  FALSAFI, Afshin ,  MOSER, William H. ,  BUI, Hoa T.

Inventor： JOLY, Guy D. ,  KREPSKI, Larry R. ,  GADDAM, Babu N. ,  ABUELYAMAN, Ahmed S. ,  CRAIG, Bradley D. ,  DUNBAR, Timothy D. ,  CAO, Chuntao ,  OXMAN, Joel D. ,  FALSAFI, Afshin ,  MOSER, William H. ,  BUI, Hoa T.

IPC: A61K6/083

Abstract: Dental compositions are described comprising an addition-fragmentation agent comprising at least one ethylenically unsaturated terminal group and a backbone unit comprising an α, β- unsaturated carbonyl; at least one monomer comprising at least two ethylenically unsaturated group; and inorganic oxide filler. The addition-fragmentation agent is preferably free-radically cleavable. The addition-fragmentation agent preferably comprises at least two ethylenically unsaturated terminal groups, such as (meth)acTylate groups. In some embodiments, the addition- fragmentation agent has the formula: wherein R 1 , R 2 and R 3 are each independently Ζ m ,-Q-, a (hetero)alkyl group or a (hetero)aryl group with the proviso that at least one of R 1 , R 2 and R 3 is Z m -Q-; Q is a linking group have a valence of m +1; Z is an ethylenically unsaturated polymerizable group; m is 1 to 6; each X1 is independently -O- or -NR 4 -, where R 4 is H or C 1 -C 4 alkyl; and n is 0 or 1. Also described are dental articles prepared from a dental composition comprising an addition- fragmentation agent and methods of treating a tooth surface.

公开(公告)号：WO2012112350A2

公开(公告)日：2012-08-23

申请号：PCT/US2012024222

申请日：2012-02-08

Applicant: 3M INNOVATIVE PROPERTIES CO ,  JOLY GUY D ,  KREPSKI LARRY R ,  GADDAM BABU N ,  ABUELYAMAN AHMED S ,  CRAIG BRADLEY D ,  DUNBAR TIMOTHY D ,  CAO CHUNTAO ,  OXMAN JOEL D ,  FALSAFI AFSHIN ,  MOSER WILLIAM H ,  BUI HOA T

Inventor： JOLY GUY D ,  KREPSKI LARRY R ,  GADDAM BABU N ,  ABUELYAMAN AHMED S ,  CRAIG BRADLEY D ,  DUNBAR TIMOTHY D ,  CAO CHUNTAO ,  OXMAN JOEL D ,  FALSAFI AFSHIN ,  MOSER WILLIAM H ,  BUI HOA T

IPC: A61K6/083

CPC classification number: A61K6/083 ,  A61K6/0023 ,  A61K6/0029 ,  A61K6/005 ,  C08L33/10

Abstract: Dental compositions are described comprising an addition-fragmentation agent comprising at least one ethylenically unsaturated terminal group and a backbone unit comprising an a, ß- unsaturated carbonyl; at least one monomer comprising at least two ethylenically unsaturated group; and inorganic oxide filler. The addition-fragmentation agent is preferably free-radically cleavable. The addition-fragmentation agent preferably comprises at least two ethylenically unsaturated terminal groups, such as (meth)acrylate groups. In some embodiments, the addition-fragmentation agent has the formula (I) wherein R1, R2 and R3 are each independently Zm-Q-, a (hetero)alkyl group or a (hetero)aryl group with the proviso that at least one of R1, R2 and R3 is Zm-Q-; Q is a linking group have a valence of m +1; Z is an ethylenically unsaturated polymerizable group; m is 1 to 6; each X1 is independently -O- or -NR4-, where R4 is H or C1-C4 alkyl; and n is 0 or 1. Also described are dental articles prepared from a dental composition comprising an addition-fragmentation agent and methods of treating a tooth surface are described.

Abstract translation: 描述了牙科组合物，其包含包含至少一个烯键式不饱和端基的加成断裂剂和包含α，β-不饱和羰基的主链单元; 至少一种包含至少两个烯属不饱和基团的单体; 和无机氧化物填料。 加成裂解剂优选是可自由基切割的。 加成断裂剂优选包含至少两个烯键式不饱和端基，例如（甲基）丙烯酸酯基团。 在一些实施方案中，加成断裂剂具有式（I），其中R 1，R 2和R 3各自独立地为Z m-Q-，（杂）烷基或（杂）芳基，条件是至少一个 R1，R2和R3是Zm-Q-; Q是连接基团，其价态为m + 1; Z是烯属不饱和可聚合基团; m为1〜6; 每个X 1独立地是-O-或-NR 4 - ，其中R 4是H或C 1 -C 4烷基; 并且n为0或1.还描述了由包含加成碎裂剂的牙科组合物制备的牙科用品和治疗牙齿表面的方法。

公开(公告)号：WO2012112321A2

公开(公告)日：2012-08-23

申请号：PCT/US2012/023911

申请日：2012-02-06

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  ABUELYAMAN, Ahmed S. ,  ECKERT, Adrian S. ,  MITRA, Sumita B. ,  DUNBAR, Timothy D. ,  CRAIG, Bradley D. ,  CAO, Chuntao

Inventor： ABUELYAMAN, Ahmed S. ,  ECKERT, Adrian S. ,  MITRA, Sumita B. ,  DUNBAR, Timothy D. ,  CRAIG, Bradley D. ,  CAO, Chuntao

IPC: A61K6/083

CPC classification number: A61K6/083 ,  A61K6/0005 ,  A61K6/0008 ,  A61K6/0061 ,  A61K6/0073 ,  A61K6/09 ,  C08L33/08 ,  C08L33/10

Abstract: Hardenable compositions are described comprising at least one multifunctional ethylenically unsaturated isocyanurate monomer and at least one multifunctional ethylenically unsaturated tricyclodecane monomer. In favored embodiments, the compositions further comprise filler and are suitable dental restorations.

Abstract translation: 描述了包含至少一种多官能烯键式不饱和异氰脲酸酯单体和至少一种多官能烯键式不饱和三环癸烷单体的可硬化组合物。 在有利的实施方案中，组合物还包含填充剂并且是适合的牙齿修复体。

公开(公告)号：WO2007146686A3

公开(公告)日：2010-05-27

申请号：PCT/US2007070465

申请日：2007-06-06

Applicant: 3M INNOVATIVE PROPERTIES CO ,  WALKER CHRISTOPHER B JR ,  RADCLIFFE MARC D ,  KLUN THOMAS P ,  LIU LAN H ,  POKORNY RICHARD J ,  COGGIO WILLIAM D ,  CAO CHUNTAO ,  PELLERITE MARK J ,  KELLEY PAUL C ,  FLEMING ROBERT J

Inventor： WALKER CHRISTOPHER B JR ,  RADCLIFFE MARC D ,  KLUN THOMAS P ,  LIU LAN H ,  POKORNY RICHARD J ,  COGGIO WILLIAM D ,  CAO CHUNTAO ,  PELLERITE MARK J ,  KELLEY PAUL C ,  FLEMING ROBERT J

IPC: G02B1/11

CPC classification number: G02B1/111 ,  Y10T428/24942 ,  Y10T428/25 ,  Y10T428/254 ,  Y10T428/256 ,  Y10T428/265 ,  Y10T428/269 ,  Y10T428/3154 ,  Y10T428/31935

Abstract: Antireflective films are described having a surface layer (20) comprising the reaction product of a polymerizable low refractive index composition comprising at least one fluorinated free -radically polymerizable material and surface modified inorganic nanoparticles. A high refractive index layer (22) is coupled to the low refractive index layer. The high refractive index (22) layer comprises surface modified inorganic nanoparticles dispersed in a crosslinked organic material. The antireflective film is preferably durable, exhibiting a haze of less than 1.0% after 25 wipes with steel wool using a 3.2 cm mandrel and a mass of 1000 grams.

Abstract translation: 描述了具有表面层（20）的抗反射膜，该表面层（20）包括包含至少一种含氟可自由共聚材料和表面改性无机纳米颗粒的可聚合低折射率组合物的反应产物。 高折射率层（22）耦合到低折射率层。 高折射率（22）层包含分散在交联的有机材料中的表面改性的无机纳米颗粒。 抗反射膜优选耐用，在使用3.2cm心轴和质量为1000克的钢丝绒进行25次擦拭之后，其雾度小于1.0％。

公开(公告)号：WO2007146686A2

公开(公告)日：2007-12-21

申请号：PCT/US2007/070465

申请日：2007-06-06

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  WALKER, Christopher B. Jr. ,  RADCLIFFE, Marc D. ,  KLUN, Thomas P. ,  LIU, Lan H. ,  POKORNY, Richard J. ,  COGGIO, William D. ,  CAO, Chuntao ,  PELLERITE, Mark J. ,  KELLEY, Paul C. ,  FLEMING, Robert J.

Inventor： WALKER, Christopher B. Jr. ,  RADCLIFFE, Marc D. ,  KLUN, Thomas P. ,  LIU, Lan H. ,  POKORNY, Richard J. ,  COGGIO, William D. ,  CAO, Chuntao ,  PELLERITE, Mark J. ,  KELLEY, Paul C. ,  FLEMING, Robert J.

IPC: G02B1/11

CPC classification number: G02B1/111 ,  Y10T428/24942 ,  Y10T428/25 ,  Y10T428/254 ,  Y10T428/256 ,  Y10T428/265 ,  Y10T428/269 ,  Y10T428/3154 ,  Y10T428/31935

Abstract: Antireflective films are described having a surface layer comprising a the reaction product of a polymerizable low refractive index composition comprising at least one fluorinated free-radically polymerizable material and surface modified inorganic nanoparticles. A high refractive index layer is coupled to the low refractive index layer. In one emboidiment, the high refractive index layer comprises surface modified inorganic nanoparticles dispersed in a crosslinked organic material. The antireflective film is preferably durable, exhibiting a haze of less than 1.0% after 25 wipes with steel wool using a 3.2 cm mandrel and a mass of 1000 grams.

Abstract translation: 描述了具有表面层的抗反射膜，该表面层包含包含至少一种氟化可自由基聚合材料和表面改性无机纳米颗粒的可聚合低折射率组合物的反应产物。 高折射率层耦合到低折射率层。 在一个实施例中，高折射率层包含分散在交联的有机材料中的表面改性的无机纳米颗粒。 抗反射膜优选耐用，在使用3.2cm心轴和质量为1000克的钢丝绒进行25次擦拭之后，其雾度小于1.0％。

公开(公告)号：WO2006083425A3

公开(公告)日：2006-08-10

申请号：PCT/US2005/046593

申请日：2005-12-22

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  JING, Naiyong, ,  CAO, Chuntao ,  FUKUSHI, Tatsuo, ,  TATGE, Timothy, J., ,  COGGIO, William, D., ,  WALKER, Cristopher, B. Jr., ,  KLUN, Thomas, P., ,  SCHULTZ, William, J., ,  QIU, Zai-Ming

Inventor： JING, Naiyong, ,  CAO, Chuntao ,  FUKUSHI, Tatsuo, ,  TATGE, Timothy, J., ,  COGGIO, William, D., ,  WALKER, Cristopher, B. Jr., ,  KLUN, Thomas, P., ,  SCHULTZ, William, J., ,  QIU, Zai-Ming

IPC: C08F2/44 ,  C08F2/48 ,  C08F259/08 ,  C08F292/00 ,  C08K3/36 ,  C08K5/5425 ,  C08K9/06 ,  C08L51/10 ,  C09D7/12 ,  C09D151/10 ,  G02B1/11

Abstract: An economic, optically transmissive, stain and ink repellent, durable low refractive index fluoropolymer composition for use in an antireflection film or coupled to an optical display. In one aspect of the invention, the composition is formed from the reaction product of a fluoropolymer, a C=C double bond group containing silane ester agent, and an optional multi-olefinic crosslinker. In another aspect of the invention, the composition further includes surface modified inorganic nanoparticles. In another aspect, the multi-olefinic crosslinker is an alkoxysilyl-containing multi-olefinic crosslinker.