USE OF CYCLODEXTRINS IN CONTROLLED ARCHITECTURE POLYMER SYNTHESIS
    3.
    发明申请
    USE OF CYCLODEXTRINS IN CONTROLLED ARCHITECTURE POLYMER SYNTHESIS 审中-公开
    环孢素在控制结构聚合物合成中的应用

    公开(公告)号:WO2008156984A1

    公开(公告)日:2008-12-24

    申请号:PCT/US2008/065033

    申请日:2008-05-29

    IPC分类号: D21C5/02 B32B27/32

    摘要: The invention relates to the use of macromolecular organic compound carriers, such as cyclodextrins, in a controlled radical polymerization process in aqueous media. The process can be used with a nitroxide-mediated process, atom transfer radical polymerization or similar processes to form controlled architecture homopolymer and block polymers. The macromolecular organic compound carriers can also be used to form amphiphilic block polymers in aqueous media by several different controlled-radical polymerization processes. Further, the use of macromolecular organic compound carriers in an aqueous media controlled radical polymerization process presents a means for recycling of the macromolecular organic compound carrier and radical control agent.

    摘要翻译: 本发明涉及在水性介质中的受控自由基聚合方法中使用大分子有机化合物载体,例如环糊精。 该方法可以与氮氧化物介导的方法,原子转移自由基聚合或类似方法一起使用以形成可控的结构均聚物和嵌段聚合物。 大分子有机化合物载体也可用于通过几种不同的受控自由基聚合方法在水性介质中形成两亲嵌段聚合物。 此外,在含水介质控制的自由基聚合方法中使用大分子有机化合物载体提供了大分子有机化合物载体和自由基控制剂的再循环的手段。