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    TRIMETAL-ARENE CLUSTERS WITH ANTICANCER ACTIVITY
    3.
    发明申请
    TRIMETAL-ARENE CLUSTERS WITH ANTICANCER ACTIVITY 审中-公开
    具有抗癌活性的三聚甲醛聚合物

    公开(公告)号：WO2009013724A3

    公开(公告)日：2009-03-19

    申请号：PCT/IB2008052998

    申请日：2008-07-25

    Applicant: ECOLE POLYTECH ,  THERRIEN BRUNO ,  SUESS-FINK GEORG ,  DYSON PAUL JOSEPH ,  ANG WEE HAN

    Inventor： THERRIEN BRUNO ,  SUESS-FINK GEORG ,  DYSON PAUL JOSEPH ,  ANG WEE HAN

    IPC: C07F17/02 ,  A61K31/28

    CPC classification number: C07F17/02

    Abstract: The present invention relates to new medicaments, pharmaceutical compositions and methods of treatment of cancer. Disclosed are trimetallic clusters for use as a medicament, in particular in the treatment of cancer including metastasis. Preferably, the compounds are provided in the form of pharmaceutically acceptable salts. Preferred compound include trinuclear ruthenium- arene clusters as exemplified by the compounds 1a and 1b shown in Figure 1.

    Abstract translation: 本发明涉及新的药物，药物组合物和治疗癌症的方法。 公开了用作药物的三金属团簇，特别是用于治疗包括转移的癌症。 优选地，化合物以药学上可接受的盐的形式提供。 优选的化合物包括三核钌 - 芳烃簇，例如图1中所示的化合物1a和1b。

    IONIC LIQUIDS BASED ON IMIDAZOLIUM SALTS INCORPORATING A NITRILE FUNCTIONALITY
    6.
    发明申请
    IONIC LIQUIDS BASED ON IMIDAZOLIUM SALTS INCORPORATING A NITRILE FUNCTIONALITY 审中-公开
    基于具有独特功能的咪唑盐的离子液体

    公开(公告)号：WO2005019185A1

    公开(公告)日：2005-03-03

    申请号：PCT/EP2004/009499

    申请日：2004-08-25

    Applicant: ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE (EPFL) ,  DYSON, Paul ,  ZHAO, Dongbin ,  FEI, Zhaofu

    Inventor： DYSON, Paul ,  ZHAO, Dongbin ,  FEI, Zhaofu

    IPC: C07D233/61

    CPC classification number: C07F5/022 ,  B01J31/0218 ,  B01J31/0284 ,  B01J31/0285 ,  B01J31/1805 ,  B01J31/30 ,  B01J31/4038 ,  B01J2231/4211 ,  B01J2231/645 ,  B01J2531/821 ,  B01J2531/824 ,  B01J2531/828 ,  C07D233/54 ,  C07D233/56 ,  Y02P20/584

    Abstract: Novel chemical compounds of the general formula K + A - , in which K + is a 5- or 6- membered heterocyclic ring having 1-3 hetereo atoms, which can be independently N, S, or 0; with the proviso that at least one of the hetereo atoms must be a quaternized nitrogen atom having a -R'CN substituent, wherein R' is alkyl (C 1 to C 12 ); the heterocyclic ring having up to 4 or 5 substituents independently chosen from the moieties: (i) H; (ii) halogen or (iii) alkyl (C 1 to C 12 ) , which is unsubstituted or partially or fully substituted by further groups, preferably F, Cl, N(C n F( 2n+1-x )H x ) 2 , O(C n F (2n+1-x) H x ), S0 2 (C n F( 2n+1-x) H x ) 2 or C n F (2n+1-x )H x where 1 n F (2n+1-x.) H x .) 2 , O(C n F (2n+1-x) H x ), S0 2 (C n F (2n+1-x )H x ) 2 or C n F( 2n+1-x )H x where 1 - is any anion that provides a salt with a low melting point, below about 100 °C; A - can be halide, BF 4 - , PF 6 - , N0 3 - , CH 3 CO 2 - , CF 3 SO 3 - , (CF 3 SO 2 ) 2 N - , (CF 3 SO 2 ) 3 C - CF 3 CO 2 - or N(CN) 2 - or [BF 3 RCN] - . These compounds can be used as industrial solvents, especially as ligands for efficient catalyst recycling.

    Abstract translation: 其中K +是具有1-3个hetereo原子的5-或6-元杂环，其可以独立地为N，S或0;通式为K + 条件是至少一个恒音原子必须是具有-R'CN取代基的季铵化氮原子，其中R'是烷基（C1至C12）; 所述杂环具有至多4个或5个独立地选自以下部分的取代基：（i）H; （CnF（2n + 1-x）Hx）2，O（CnF（2n + 1-x）Hx）2），（ii）卤素或（iii）未取代或部分或完全被其它基团 2n + 1-x）Hx），S02（CnF（2n + 1-x）Hx）2或CnF（2n + 1-x）Hx，其中1 。 这些化合物可用作工业溶剂，特别是作为有效催化剂再循环的配体。

    HYDROGEN PRODUCTION FROM FORMIC ACID
    8.
    发明申请
    HYDROGEN PRODUCTION FROM FORMIC ACID 审中-公开
    氢生产从形式酸

    公开(公告)号：WO2008047312A1

    公开(公告)日：2008-04-24

    申请号：PCT/IB2007/054222

    申请日：2007-10-17

    Applicant: ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE (EPFL) ,  LAURENCZY, Gabor ,  FELLAY, Céline ,  DYSON, Paul

    Inventor： LAURENCZY, Gabor ,  FELLAY, Céline ,  DYSON, Paul

    IPC: C01B3/22 ,  C01B31/20 ,  B01J31/18

    CPC classification number: C01B3/22 ,  B01J31/0215 ,  B01J31/0225 ,  B01J31/24 ,  B01J2531/821 ,  C01B32/50 ,  Y02P20/128

    Abstract: The present invention relates to a method of producing hydrogen gas and carbon dioxide in a catalytic reaction from formic acid, said reaction being conducted in an aqueous solution over a wide temperature range and already at room temperature (25°C). The reaction is advantageous because it can be tuned to take place at very high rates, up to about 90 litre H2 / minute / litre reactor volume. The gas produced is free of carbon monoxide. The method of the present invention is particularly suitable for providing hydrogen for a motor, fuel cell or chemical synthesis.

    Abstract translation: 本发明涉及在甲酸催化反应中生产氢气和二氧化碳的方法，所述反应在宽的温度范围内并在室温（25℃）下在水溶液中进行。 该反应是有利的，因为它可以调节以非常高的速率进行，高达约90升H 2 /分升/升反应器体积。 产生的气体不含一氧化碳。 本发明的方法特别适用于为电动机，燃料电池或化学合成提供氢。

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