公开(公告)号：WO2004005360A3

公开(公告)日：2005-11-10

申请号：PCT/EP0307485

申请日：2003-07-09

Applicant: BASELL POLYOLEFINE GMBH ,  RESCONI LUIGI ,  FOCANTE FRANCESCA ,  CAMURATI ISABELLA ,  GUIDOTTI SIMONA

Inventor： RESCONI LUIGI ,  FOCANTE FRANCESCA ,  CAMURATI ISABELLA ,  GUIDOTTI SIMONA

IPC: C07F5/02 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F110/02 ,  C08F4/645

CPC classification number: C07F5/027 ,  C08F4/65912 ,  C08F4/65925 ,  C08F10/00 ,  C08F110/02 ,  C08F4/65908

Abstract: An organometallic compound obtainable by contacting: a compound having the following formula (I), wherein: R is a hydrocarbon radical; R , R and R , are hydrogen atoms, halogen atoms, or hydrocarbon radicals; with a Lewis acid of formula (II) MtR 3 (II) wherein Mt is a metal belonging to Group 13 of the Periodic Table of the Elements; R are selected from the group consisting of halogen atoms, halogenated C6-C20 aryl and halogenated C7-C20 alkylaryl groups.

Abstract translation: 通过使具有下式（I）的化合物接触而获得的有机金属化合物，其中：R a是烃基; R b，R o和R d分别是氢原子，卤素原子或烃基; 与式（II）的路易斯酸MtR 1（II）其中Mt是属于元素周期表第13族的金属; R 1选自卤素原子，卤代C 6 -C 20芳基和卤代C 7 -C 20烷基芳基。

公开(公告)号：WO2007116034A1

公开(公告)日：2007-10-18

申请号：PCT/EP2007/053422

申请日：2007-04-06

Applicant: BASELL POLYOLEFINE GMBH ,  RESCONI, Luigi ,  FOCANTE, Francesca ,  BALBONI, Davide ,  NIFANT'EV, Ilya E. ,  IVCHENKO, Pavel V. ,  BAGROV, Vladimir

Inventor： RESCONI, Luigi ,  FOCANTE, Francesca ,  BALBONI, Davide ,  NIFANT'EV, Ilya E. ,  IVCHENKO, Pavel V. ,  BAGROV, Vladimir

IPC: C07F17/00 ,  C07F7/08 ,  C08F10/00 ,  C08F4/64

CPC classification number: C07F17/00 ,  C07F7/0812 ,  C07F7/0818 ,  C08F4/65912 ,  C08F10/00 ,  C08F210/06 ,  Y10S526/943 ,  C08F4/65927 ,  C08F210/16 ,  C08F2500/15 ,  C08F2500/17 ,  C08F2500/03 ,  C08F2500/20 ,  C08F210/14 ,  C08F210/08

Abstract: A bridged metallocene compound of formula (I) wherein: M is a transition metal; X, is a hydrogen atom, a halogen atom, or a hydrocarbon group optionally containing heteroatoms; L is a divalent bridging group; R 1 is a linear C 1 -C 40 hydrocarbon radical optionally containing heteroatoms; T 1 and T 4 are a oxygen, sulfur atom or a C(R 18 ) 3 group; wherein R 18 , are hydrogen atoms or a C 1 -C 40 hydrocarbon radical; T 3 and T 4 are C 1 -C 40 hydrocarbon radicals; R 4 is a hydrogen atom or a C 1 -C 40 hydrocarbon radical; W is an aromatic 5 or 6 membered ring.

Abstract translation: 式（I）的桥连茂金属化合物，其中：M是过渡金属; X是氢原子，卤原子或任选含有杂原子的烃基; L是二价桥基; R 1是任选地含有杂原子的直链C 1 -C 40烃基; T 1和T 4是氧，硫原子或C（R 18）3 N 3基团; 其中R 18是氢原子或C 1 -C 40烃基; T 3和T 4是C 1 -C 40烃基; R 4是氢原子或C 1 -C 40烃基; W是芳族5或6元环。

公开(公告)号：WO2007065816A3

公开(公告)日：2007-08-23

申请号：PCT/EP2006069031

申请日：2006-11-29

Applicant: BASELL POLIOLEFINE SRL ,  LIGUORI DARIO ,  FOCANTE FRANCESCA ,  MORINI GIAMPIERO ,  RESCONI LUIGI ,  VITALE GIANNI

Inventor： LIGUORI DARIO ,  FOCANTE FRANCESCA ,  MORINI GIAMPIERO ,  RESCONI LUIGI ,  VITALE GIANNI

IPC: C08F10/00 ,  C08F4/651

CPC classification number: C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  C08F4/6543 ,  C08F4/651 ,  C08F4/6493 ,  C08F2500/12 ,  C08F2500/18 ,  C08F210/14

Abstract: A catalyst component for the polymerization of olefins CH 2 =CHR, wherein R is hydrogen or a hydrocarbon radical having 1-12 carbon atoms. In particular, the present invention relates to catalyst components comprising Mg, Ti, halogen and a compound selected from phosphorous derivatives, boron derivatives and aromatic heterocyclic nitrogen derivatives. Said catalyst components are particularly suitable for the preparation of homo and copolymers of ethylene with a-olefins.

Abstract translation: 用于烯烃CH 2 = CHR聚合的催化剂组分，其中R是氢或具有1-12个碳原子的烃基。 特别地，本发明涉及包含Mg，Ti，卤素和选自磷衍生物，硼衍生物和芳族杂环氮衍生物的化合物的催化剂组分。 所述催化剂组分特别适用于制备乙烯与α-烯烃的均聚物和共聚物。

公开(公告)号：WO2006134046A1

公开(公告)日：2006-12-21

申请号：PCT/EP2006/062964

申请日：2006-06-07

Applicant: BASELL POLYOLEFINE GMBH ,  RESCONI, Luigi ,  CIACCIA, Eleonora ,  FOCANTE, Francesca

Inventor： RESCONI, Luigi ,  CIACCIA, Eleonora ,  FOCANTE, Francesca

IPC: C08F210/06 ,  C08F4/6592

CPC classification number: C08F10/06 ,  C08F4/65912 ,  C08F4/65916 ,  C08F210/06 ,  C08F2/06 ,  C08F4/65927 ,  C08F210/16 ,  C08F2500/17

Abstract: A solution polymerization process comprising contacting under polymerization conditions propylene and at least ethylene or an alpha olefin of formula CH 2 =CHT wherein T is a C 2 -C 20 alkyl radical, in the presence of a catalyst system obtainable by contacting: b) at least a metallocene compound of formula (I) b) alumoxane or a compound capable of forming an alkyl metallocene cation; and optionally c) an organo aluminum compound; wherein the groups R 1 R 4 , L, M and W are described in the text.

Abstract translation: 一种溶液聚合方法，包括在聚合条件下接触丙烯和至少乙烯或式CH 2 CH 2的α烯烃，其中T是C 2 -C 20 在通过使b）至少一种式（I）的茂金属化合物b）铝氧烷或能够形成烷基金属茂阳离子的化合物可以得到的催化剂体系的存在下， 和任选地c）有机铝化合物; 其中基团R 1，R 4，L，M和W在文中描述。

公开(公告)号：WO2007122098A1

公开(公告)日：2007-11-01

申请号：PCT/EP2007/053429

申请日：2007-04-06

Applicant: BASELL POLYOLEFINE GMBH ,  FOCANTE, Francesca ,  RESCONI, Luigi

Inventor： FOCANTE, Francesca ,  RESCONI, Luigi

IPC: C08F210/16 ,  C08F4/6592

CPC classification number: C08F210/16 ,  C08F4/65912 ,  C08F4/65927 ,  C08F210/08 ,  C08F2500/17

Abstract: A polymerization process comprising contacting under polymerization conditions ethylene and at least one alpha olefin of fo rmu la CH2=CHA wherein A is a C 2 -C 20 alkyl radical to obtain a copolymer containing from 95% by mol to 50% by mol of ethylene derived units in the presence of a catalyst system obtainable by contacting: b) at least a metallocene compound of formu la (I) b) alumoxane or a compound capable of forming an alkyl metallocene cation; and optionally c) an organo aluminum compound; wherein the groups R 1 -R 4 , L, M and W are described in the text.

Abstract translation: 一种聚合方法，包括在聚合条件下使乙烯和至少一种其中A为C 2 -C 20烷基的α-烯烃，其中A为C 2 -C 20烷基， 共聚物在催化剂体系的存在下含有95摩尔％至50摩尔％的乙烯衍生单元，所述催化剂体系可以通过以下方式获得：b）至少一种式Ia（I）的茂金属化合物：铝氧烷或能够形成 烷基茂金属阳离子; 和任选地c）有机铝化合物; 其中基团R 1 -R 4，L，M和W在文中描述。

公开(公告)号：WO2007122097A1

公开(公告)日：2007-11-01

申请号：PCT/EP2007/053424

申请日：2007-04-06

Applicant: Basell Polyolefine GmbH ,  RESCONI, Luigi ,  FOCANTE, Francesca

Inventor： RESCONI, Luigi ,  FOCANTE, Francesca

IPC: C08F210/06 ,  C08F4/6592

CPC classification number: C08F210/16 ,  C08F4/65912 ,  C08F4/65927 ,  C08F210/06 ,  C08F2500/17

Abstract: A polymerization process comprising contacting under polymerization conditions ethylene and at least propylene to obtain a copolymer containing from 96% by mol to 71% by mol of ethylene derived units, in the presence of a catalyst system obtainable by contacting: b) at least a metallocene compound of formula (I), b) alumoxane or a compound capable of forming an alkyl metallocene cation; and optionally c) an organo aluminum compound; wherein the groups R 1 -R 4 , L, M and W are described in the text.

Abstract translation: 一种聚合方法，包括在聚合条件下使乙烯和至少丙烯接触，以获得含有衍生自乙烯的单元的96摩尔％至71摩尔％的乙烯衍生单元的共聚物，所述催化剂体系可以通过以下方式获得：b）至少一种茂金属 式（I）化合物，b）铝氧烷或能够形成烷基金属茂阳离子的化合物; 和任选地c）有机铝化合物; 其中基团R 1 -R 4，L，M和W在文中描述。

公开(公告)号：WO2006097500A1

公开(公告)日：2006-09-21

申请号：PCT/EP2006/060772

申请日：2006-03-15

Applicant: Basell Polyolefine GmbH ,  SACCO, Marco ,  NIFANT'EV, Ilya E. ,  IVCHENKO, Pavel V. ,  BAGROV, Vladimir ,  FOCANTE, Francesca

Inventor： SACCO, Marco ,  NIFANT'EV, Ilya E. ,  IVCHENKO, Pavel V. ,  BAGROV, Vladimir ,  FOCANTE, Francesca

IPC: C07F17/00 ,  C08F4/6592 ,  C08F210/06 ,  C08F2/00 ,  C07D317/70

CPC classification number: C07F7/0812 ,  C07D317/70 ,  C07F17/00 ,  C08F4/65912 ,  C08F210/06 ,  Y10S526/941 ,  Y10S526/943 ,  C08F2/001 ,  C08F4/65927 ,  C08F210/16 ,  C08F2500/17

Abstract: A bridged metallocene compound of formula (I) wherein: M is a transition metal; X, is a hydrogen atom, a halogen atom, or a hydrocarbon group optionally containing hetematoms; L is a divalent bridging group; R 1 is a linear C 1 C 40 hydrocarbon radical optionally containing hetexoatonis; T 1 , T 2 , T 3 and T 4 are an oxygen or sulfur atom or a C(R 18 ) 2 group with the proviso that at least one group between T 1 and T 2 is an oxyge or a sulfur atom; wherein R 18 , are hydrogen atoms or a C 1 -C 4O hydrocarbon radical; n is 1 , 2 or 3; R 4 is a hydrogen atom or a C 1 -C 40 hydro carbon radical; W is an aromatic 5 or 6 membered ring.

Abstract translation: 式（I）的桥连茂金属化合物，其中：M是过渡金属; X是氢原子，卤素原子或任选含有蒸气的烃基; L是二价桥基; R 1是任选地含有己二酸的线性C 1 -C 40烃基; T 1，T 2，T 3和T 4是氧或硫原子或C（R 条件是T 1和T 2之间的至少一个基团是氧原子或 硫原子; 其中R 18是氢原子或C 1 -C 4烃基; n为1,2或3; R 4是氢原子或C 1 -C 40烃基; W是芳族5或6元环。

公开(公告)号：WO2007107448A1

公开(公告)日：2007-09-27

申请号：PCT/EP2007/052056

申请日：2007-03-05

Applicant: BASELL POLYOLEFINE GMBH ,  RESCONI, Luigi ,  NIFANT'EV, Ilya E. ,  IVCHENKO, Pavel V. ,  BAGROV, Vladimir ,  FOCANTE, Francesca ,  MOSCARDI, Gilberto

Inventor： RESCONI, Luigi ,  NIFANT'EV, Ilya E. ,  IVCHENKO, Pavel V. ,  BAGROV, Vladimir ,  FOCANTE, Francesca ,  MOSCARDI, Gilberto

IPC: C07F17/00 ,  C07F7/08 ,  C08F10/00 ,  C08F4/62

CPC classification number: C07F17/00 ,  C07F7/0859 ,  C07F7/0861 ,  C08F4/65912 ,  C08F10/00 ,  C08F210/06 ,  C08F4/65927 ,  C08F210/16 ,  C08F2500/17

Abstract: A bridged metallocene compound of formula (I) wherein: M is an atom of a transition metal selected from those belonging to group 3, 4, or to the lanthanide or actinide groups in the Periodic Table of the Elements; X, equal to or different from each other, is a hydrogen atom, a halogen atom, a R, OR, OSO 2 CF 3 , OCOR, SR, NR 2 or PR 2 group; L is a divalent bridging group; R 1 and R 2 , equal to each other, are C 1 -C 40 h ydrocarbon radical; R3 is hydrogen o r a are C 1 -C 40 hydrocarbon radical and W is an aromatic 5 or 6 membered ring.

Abstract translation: 式（I）的桥接金属茂化合物，其中：M是选自族3,4中的过渡金属的原子，或元素周期表中的镧系元素或锕系元素基团; X，相同或不同的是氢原子，卤素原子，R，OR，OSO 2，CF 3，OCOR，SR，NR _{2 或PR <2> 组; L是二价桥基; R 1和R 2彼此相同，为C 1 -C 40烷基; R 3是氢，a是C 1 -C 40烃基，W是芳族5或6元环。}

公开(公告)号：WO2007065816A2

公开(公告)日：2007-06-14

申请号：PCT/EP2006/069031

申请日：2006-11-29

Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  LIGUORI, Dario ,  FOCANTE, Francesca ,  MORINI, Giampiero ,  RESCONI, Luigi ,  VITALE, Gianni

Inventor： LIGUORI, Dario ,  FOCANTE, Francesca ,  MORINI, Giampiero ,  RESCONI, Luigi ,  VITALE, Gianni

IPC: C08F10/00 ,  C08F4/651

CPC classification number: C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  C08F4/6543 ,  C08F4/651 ,  C08F4/6493 ,  C08F2500/12 ,  C08F2500/18 ,  C08F210/14

Abstract: A catalyst component for the polymerization of olefins CH 2 =CHR, wherein R is hydrogen or a hydrocarbon radical having 1-12 carbon atoms. In particular, the present invention relates to catalyst components comprising Mg, Ti, halogen and a compound selected from phosphorous derivatives, boron derivatives and aromatic heterocyclic nitrogen derivatives. Said catalyst components are particularly suitable for the preparation of homo and copolymers of ethylene with α-olefins.

Abstract translation: 用于烯烃CH 2 = CHR聚合的催化剂组分，其中R是氢或具有1-12个碳原子的烃基。 特别地，本发明涉及包含Mg，Ti，卤素和选自磷衍生物，硼衍生物和芳族杂环氮衍生物的化合物的催化剂组分。 所述催化剂组分特别适用于制备乙烯与α-烯烃的均聚物和共聚物。

公开(公告)号：WO2004005360A2

公开(公告)日：2004-01-15

申请号：PCT/EP2003/007485

申请日：2003-07-09

Applicant: BASELL POLYOLEFINE GMBH ,  RESCONI, Luigi ,  FOCANTE, Francesca ,  CAMURATI, Isabella ,  GUIDOTTI, Simona

Inventor： RESCONI, Luigi ,  FOCANTE, Francesca ,  CAMURATI, Isabella ,  GUIDOTTI, Simona

IPC: C08F10/00

CPC classification number: C07F5/027 ,  C08F4/65912 ,  C08F4/65925 ,  C08F10/00 ,  C08F110/02 ,  C08F4/65908

Abstract: An organometallic compound obtainable by contacting: a compound having the following formula (I), wherein: R a is a hydrocarbon radical; R b , R ° and R d , are hydrogen atoms, halogen atoms, or hydrocarbon radicals; with a Lewis acid of formula (II) MtR 1 3 (II) wherein Mt is a metal belonging to Group 13 of the Periodic Table of the Elements; R l are selected from the group consisting of halogen atoms, halogenated C 6- C 20 aryl and halogenated C 7 -C 20 alkylaryl groups.

Abstract translation: 通过使具有下式（I）的化合物接触而获得的有机金属化合物，其中：R a是烃基; R b，R o和R d分别是氢原子，卤素原子或烃基; 与式（II）的路易斯酸MtR 1（II）其中Mt是属于元素周期表第13族的金属; R 1选自卤素原子，卤代C 6 -C 20芳基和卤代C 7 -C 20烷基芳基。