公开(公告)号：WO2012027139A3

公开(公告)日：2012-05-10

申请号：PCT/US2011047641

申请日：2011-08-12

Applicant: EXXONMOBIL CHEM PATENTS INC ,  HOLTCAMP MATTHEW W ,  HAGADORN JOHN R ,  BEDOYA MATTHEW S

Inventor： HOLTCAMP MATTHEW W ,  HAGADORN JOHN R ,  BEDOYA MATTHEW S

IPC: C08F10/00 ,  C08F4/52 ,  C08F4/60 ,  C08F10/14 ,  C08F210/00

CPC classification number: C08F236/20 ,  C08C2019/09 ,  C08F4/65908 ,  C08F210/14 ,  C08F4/65927 ,  C08F2500/17

Abstract: This invention relates to a process to produce a poly(alpha-olefin)(alpha, internally unsaturated, nonconjugated olefin) comprising: contacting at least one renewable feedstream with at least one lower olefin in the presence of a metathesis catalyst, wherein a mixture of at least one C4 to C40 linear alpha-olefm and at least one alpha, internally unsaturated, nonconjugated olefin is produced; and contacting the mixture with a metallocene catalyst system, wherein a poly(alpha-olefm)(alpha, internally unsaturated, nonconjugated olefin) is produced.

Abstract translation: 本发明涉及一种生产聚（α-烯烃）（α，内部不饱和的非共轭烯烃）的方法，包括：在复分解催化剂存在下使至少一种可再生的原料流与至少一种低级烯烃接触，其中将 产生至少一种C 4至C 40直链α-烯烃和至少一种α内部不饱和非共轭烯烃; 并使该混合物与金属茂催化剂体系接触，其中制备聚（α-烯烃）（α，内部不饱和的非共轭烯烃）。

公开(公告)号：WO2011100022A3

公开(公告)日：2011-11-17

申请号：PCT/US2010059703

申请日：2010-12-09

Applicant: EXXONMOBIL CHEM PATENTS INC ,  HOLTCAMP MATTHEW W ,  FALER CATHERINE A ,  HUFF CAOL P ,  BEDOYA MATTHEW S ,  HAGADORN JOHN R

Inventor： HOLTCAMP MATTHEW W ,  FALER CATHERINE A ,  HUFF CAOL P ,  BEDOYA MATTHEW S ,  HAGADORN JOHN R

IPC: B01J31/22 ,  C07B37/00 ,  C07C6/06 ,  C07C11/02 ,  C07F15/00

CPC classification number: C07F15/0046 ,  B01J31/2208 ,  B01J31/2252 ,  B01J31/2273 ,  B01J31/2278 ,  B01J2231/543 ,  B01J2531/821 ,  B01J2540/22 ,  C07C6/04 ,  C07C67/03 ,  C07C67/333 ,  C07C2531/24 ,  C11C3/00 ,  Y02E50/13 ,  C07C11/02 ,  C07C69/52 ,  C07C69/533

Abstract: This invention relates to a catalyst compound for the metathesis of olefins represented by the formula (I): wherein M is a Group 8 metal; X and X1 are anionic ligands; L is a neutral two electron donor; L1 is N, O, P, or S, preferably N or O; R is a C1 to C30 hydrocarbyl or a C1 to C30 substituted hydrocarbyl; G* is selected from the group consisting of hydrogen, a C1 to C30 hydrocarbyl, and a C1 to C30 substituted hydrocarbyl; R1 is selected from the group consisting of hydrogen, a C1 to C30 hydrocarbyl, and a C1 to C30 substituted hydrocarbyl; and G is independently selected from the group consisting of hydrogen, halogen, C1 to C30 hydrocarbyls and C1 to C30 substituted hydrocarbyls. This invention also relates to process to make alphaolefms comprising contacting an olefin, such as ethylene, with a feed oil containing a triacylglyceride (typically a fatty acid ester (such as methyl oleate)) with the catalyst compound described above. The fatty acid ester may be a fatty acid methyl ester derived from biodiesel.

Abstract translation: 本发明涉及由式（I）表示的用于烯烃复分解的催化剂化合物：其中M是第8族金属; X和X1是阴离子配体; L是中性二电子给体; L1是N，O，P或S，优选N或O; R是C1至C30烃基或C1至C30取代的烃基; G *选自氢，C1至C30烃基和C1至C30取代的烃基; R1选自氢，C1至C30烃基和C1至C30取代的烃基; 并且G独立地选自氢，卤素，C 1至C 30烃基和C 1至C 30取代的烃基。 本发明还涉及制备α-烯烃的方法，包括使烯烃如乙烯与含有三酰基甘油酯（通常为脂肪酸酯（如油酸甲酯））的进料油与上述催化剂化合物接触。 脂肪酸酯可以是衍生自生物柴油的脂肪酸甲酯。

公开(公告)号：WO2011056881A3

公开(公告)日：2011-09-15

申请号：PCT/US2010055309

申请日：2010-11-03

Applicant: EXXONMOBIL CHEM PATENTS INC ,  HAGADORN JOHN R ,  HOLTCAMP MATTHEW W ,  BEDOYA MATTHEW S

Inventor： HAGADORN JOHN R ,  HOLTCAMP MATTHEW W ,  BEDOYA MATTHEW S

IPC: B01J31/22 ,  C07C1/213 ,  C07C11/00 ,  C07F15/00

CPC classification number: C07F15/0046 ,  B01J31/2226 ,  B01J31/2291 ,  B01J31/2295 ,  B01J2231/49 ,  B01J2231/543 ,  B01J2531/821 ,  C07C6/04 ,  C07C67/333 ,  C07C2531/22 ,  C11C3/14 ,  Y02E50/13 ,  C07C11/02 ,  C07C69/533

Abstract: This invention relates to a catalyst compound comprising a combination of a cyclic alkyl amino carbene ligand and a benzylidene both attached to a Group 8 metal, preferably ruthenium atom. This invention also relates to a process to make linear alpha-olefms comprising contacting a feed material and an optional alkene (such as ethylene) with the catalyst described above, wherein the feed material is a triacylglyceride, fatty acid, fatty acid alkyl ester, and/or fatty acid ester, typically derived from seed oil (e.g., biodiesel).

Abstract translation: 本发明涉及催化剂化合物，其包含环状烷基氨基卡宾配体和亚苄基的组合，所述亚烷基氨基卡宾配体和亚苄基均连接至第8族金属，优选钌原子。 本发明还涉及制备线性α-烯烃的方法，包括使进料和任选的烯烃（如乙烯）与上述催化剂接触，其中进料为三酰基甘油酯，脂肪酸，脂肪酸烷基酯和 /或脂肪酸酯，通常来源于种子油（例如生物柴油）。

公开(公告)号：WO2012134725A3

公开(公告)日：2013-01-31

申请号：PCT/US2012027704

申请日：2012-03-05

Applicant: EXXONMOBIL CHEM PATENTS INC ,  HAGADORN JOHN R ,  BRANT PATRICK

Inventor： HAGADORN JOHN R ,  BRANT PATRICK

IPC: C08F10/00 ,  C08F4/6592 ,  C08F297/08 ,  C08L23/02 ,  C08L53/00

CPC classification number: C08F210/06 ,  C08F4/65908 ,  C08F4/65925 ,  C08F4/65927 ,  C08F290/062 ,  C08F297/08 ,  C08F299/00 ,  C08F210/16 ,  C08F2500/15 ,  C08F210/14

Abstract: The invention relates to a multiblock polyolefin, and methods to make a multiblock polyolefin, represented by the formula (X) or (XII): PO-C(R11)R12-CR13C(R14-C)-C(O)-((CR15R16) ZVC17R18)m-O)n-R19 (X) or PO-C(R11)R12-CR13C(R14-C)-C(O)-((CR15R16) ZVC17R18)mO)n-C(O)- C(R14C=(R13)-C(R12)(R11)-PO (XX) wherein R11, R12, R13, and R14 are each independently a substituted or unsubstituted C1 through C4 hydrocarbyl group or a hydrogen; R15, R16, R17, and R18 are each independently a substituted or unsubstituted C1 through C4 hydrocarbyl group or a hydrogen; R19 is a C1 to a C20 substituted or unsubstituted hydrocarbyl group or a hydrogen; z is = 1 to about 5; m is = 1 to about 5; PO is a polyolefin hydrocarbyl group comprising 10 to 4000 carbon atoms; and n is from 1 to about 10,000.

Abstract translation: 本发明涉及一种多嵌段聚烯烃，以及制备由式（X）或（XII）表示的多嵌段聚烯烃的方法：PO-C（R11）R12-CR13C（R14-C）-C（O） - （（ （R 15）C（O） - （CR 15 R 16）Z C 17 R 18）m O）n R 19（X）或PO-C（R 11）R 12 -C 13 C（R 14 -C （R 13）-C（R 12）（R 11）-PO（XX）其中R 11，R 12，R 13和R 14各自独立地为取代或未取代的C 1 -C 4烃基或氢; R 15，R 16，R 17和R 18为 各自独立地为取代或未取代的C1至C4烃基或氢; R19为C1至C20取代或未取代的烃基或氢; z为1至约5; m为1至约5; PO为 包含10至4000个碳原子的聚烯烃烃基; n为1至约10,000。

公开(公告)号：WO2012134717A2

公开(公告)日：2012-10-04

申请号：PCT/US2012/027682

申请日：2012-03-05

Applicant: EXXONMOBIL CHEMICAL PATENTS INC. ,  CROWTHER, Donna, J. ,  HOLTCAMP, Matthew, W. ,  HAGADORN, John, R. ,  RUFF, Charles, J. ,  RODRIGUEZ, George ,  BRANT, Patrick

Inventor： CROWTHER, Donna, J. ,  HOLTCAMP, Matthew, W. ,  HAGADORN, John, R. ,  RUFF, Charles, J. ,  RODRIGUEZ, George ,  BRANT, Patrick

IPC: C08F210/14 ,  C08F210/06 ,  C08L23/18 ,  C08F4/64 ,  C10M107/10

CPC classification number: C10M107/10 ,  C08F4/65908 ,  C08F4/65925 ,  C08F4/65927 ,  C08F210/06 ,  C08F210/14 ,  C08L2314/06 ,  C10M2205/0245 ,  C10M2205/0265 ,  C10M2205/0285 ,  C10N2220/021 ,  C10N2220/022 ,  C10N2220/028 ,  C10N2270/00 ,  C08F2500/17

Abstract: This invention relates to a vinyl terminated higher olefin copolymer having an Mn of 300 g/mol or more (measured by 1 H NMR) comprising: (i) from about 20 to about 99.9 mol% of at least one C 5 to C 40 higher olefin monomer; and (ii) from about 0.1 to about 80 mol% of propylene; wherein the higher olefin copolymer has at least 40% allyl chain ends. The copolymer may also have an isobutyl chain end to allyl chain end ratio of less than 0.7: 1 and/or an allyl chain end to vinylidene chain end ratio of greater than 2:1.

Abstract translation: 本发明涉及Mn为300g / mol或更高（通过1 H NMR测量）的乙烯基封端的高级烯烃共聚物，其包含：（i）约20 至约99.9摩尔％的至少一种C≡5至C≡40高级烯烃单体; 和（ii）约0.1至约80摩尔％的丙烯; 其中高级烯烃共聚物具有至少40％的烯丙基链端。 该共聚物还可具有小于0.7：1的异丁基链端与烯丙基链端部比例和/或大于2：1的烯丙基链端部与乙烯叉基链端部比率。

公开(公告)号：WO2011056874A3

公开(公告)日：2011-10-06

申请号：PCT/US2010055302

申请日：2010-11-03

Applicant: EXXONMOBIL CHEM PATENTS INC ,  HOLTCAMP MATTHEW W ,  BEDOYA MATTHEW S ,  FALER CATHERINE A ,  HUFF CAOL P ,  HAGADORN JOHN R

Inventor： HOLTCAMP MATTHEW W ,  BEDOYA MATTHEW S ,  FALER CATHERINE A ,  HUFF CAOL P ,  HAGADORN JOHN R

IPC: B01J31/12 ,  C07C1/213 ,  C07C11/00 ,  C07F15/00

CPC classification number: C07F15/0046 ,  B01J31/2208 ,  B01J31/2273 ,  B01J31/2278 ,  B01J2231/543 ,  B01J2531/0261 ,  B01J2531/821 ,  B01J2531/825 ,  C07C6/04 ,  C07C2531/22 ,  C07F15/002 ,  C07C11/02 ,  C07C11/08

Abstract: This invention relates to a metathesis catalyst compound comprising an asymmetrically substituted N-heterocyclic carbene (NHC) metathesis catalyst and a process to make linear alpha-olefms comprising contacting a feed material and an optional alkene (such as ethylene) with said catalyst, where the feed material is a triacylglyceride, fatty acid, fatty acid alkyl ester, and/or fatty acid ester, typically derived from biodiesel.

Abstract translation: 本发明涉及包含不对称取代的N-杂环卡宾（NHC）复分解催化剂的复分解催化剂化合物以及制备线性α-烯烃的方法，包括使进料和任选的烯烃（如乙烯）与所述催化剂接触，其中 进料是通常来自生物柴油的三酰甘油酯，脂肪酸，脂肪酸烷基酯和/或脂肪酸酯。

公开(公告)号：WO2011056881A2

公开(公告)日：2011-05-12

申请号：PCT/US2010/055309

申请日：2010-11-03

Applicant: EXXONMOBIL CHEMICAL PATENTS INC. ,  HAGADORN, John, R. ,  HOLTCAMP, Matthew, W. ,  BEDOYA, Matthew, S.

Inventor： HAGADORN, John, R. ,  HOLTCAMP, Matthew, W. ,  BEDOYA, Matthew, S.

IPC: B01J31/22 ,  C07C1/213 ,  C07C11/00 ,  C07F15/00

CPC classification number: C07F15/0046 ,  B01J31/2226 ,  B01J31/2291 ,  B01J31/2295 ,  B01J2231/49 ,  B01J2231/543 ,  B01J2531/821 ,  C07C6/04 ,  C07C67/333 ,  C07C2531/22 ,  C11C3/14 ,  Y02E50/13 ,  C07C11/02 ,  C07C69/533

Abstract: This invention relates to a catalyst compound comprising a combination of a cyclic alkyl amino carbene ligand and a benzylidene both attached to a Group 8 metal, preferably ruthenium atom. This invention also relates to a process to make linear alpha-olefms comprising contacting a feed material and an optional alkene (such as ethylene) with the catalyst described above, wherein the feed material is a triacylglyceride, fatty acid, fatty acid alkyl ester, and/or fatty acid ester, typically derived from seed oil (e.g., biodiesel).

Abstract translation: 本发明涉及包含环烷基氨基卡宾配体和亚苄基的组合的催化剂化合物，它们都附着在第8族金属，优选钌原子上。 本发明还涉及制备线性α-烯烃的方法，包括使进料和任选的烯烃（如乙烯）与上述催化剂接触，其中进料是甘油三酯，脂肪酸，脂肪酸烷基酯和 /或脂肪酸酯，通常衍生自种子油（例如，生物柴油）。

公开(公告)号：WO2012134721A2

公开(公告)日：2012-10-04

申请号：PCT/US2012/027690

申请日：2012-03-05

Applicant: EXXONMOBIL CHEMICAL PATENTS INC. ,  HOLTCAMP, Matthew, W. ,  RUFF, Charles, J. ,  CROWTHER, Donna, J. ,  HAGADORN, John, R. ,  BRANT, Patrick

Inventor： HOLTCAMP, Matthew, W. ,  RUFF, Charles, J. ,  CROWTHER, Donna, J. ,  HAGADORN, John, R. ,  BRANT, Patrick

IPC: C08F10/14 ,  C08F210/16 ,  C08F4/64 ,  C08F4/6592

CPC classification number: C08F10/14 ,  C08F4/65908 ,  C08F4/65912 ,  C08F210/14 ,  C08F4/65925 ,  C08F4/65927 ,  C08F2500/02

Abstract: This invention relates to higher olefin vinyl terminated polymers having an Mn of at least 200 g/mol (measured by lR NMR) including of one or more C4 to C4Q higher olefin derived units, where the higher olefin vinyl terminated polymer comprises substantially no propylene derived units; and wherein the higher olefin polymer has at least 5% allyl chain ends and processes for the production thereof. These vinyl terminated higher olefin polymers may optionally include ethylene derived units.

Abstract translation: 本发明涉及具有至少200g / mol（通过1 H NMR测量）的Mn的高级烯烃乙烯基封端的聚合物，其包括一种或多种C 4 -C 40高级烯烃衍生的单元，其中高级烯烃 乙烯基封端的聚合物基本不含丙烯衍生的单元 并且其中高级烯烃聚合物具有至少5％的烯丙基链端和用于其生产的方法。 这些乙烯基封端的高级烯烃聚合物可以任选地包括乙烯衍生的单元。

公开(公告)号：WO2012134718A3

公开(公告)日：2012-10-04

申请号：PCT/US2012/027683

申请日：2012-03-05

Applicant: EXXONMOBIL CHEMICAL PATENTS INC. ,  HAGADORN, John, R. ,  CROWTHER, Donna, J. ,  GANESH, Renuka, N. ,  BRANT, Patrick

Inventor： HAGADORN, John, R. ,  CROWTHER, Donna, J. ,  GANESH, Renuka, N. ,  BRANT, Patrick

IPC: C08F8/32 ,  C08F10/06 ,  C08F4/64 ,  C08L23/36

Abstract: This invention relates to a process to functionalize polyolefins comprising contacting a transition metal amide catalyst with an amine (preferably a secondary amine), and one or more vinyl terminated materials, preferably one or more vinyl terminated polyolefins. This invention further relates to the amine-functionalized polyolefins produced thereby.

公开(公告)号：WO2012134614A1

公开(公告)日：2012-10-04

申请号：PCT/US2012/022475

申请日：2012-01-25

Applicant: EXXONMOBIL CHEMICAL PATENTS INC. ,  HAGADORN, John, R. ,  GANESH, Renuka, N.

Inventor： HAGADORN, John, R. ,  GANESH, Renuka, N.

IPC: C07F7/28 ,  C07F7/00 ,  C07F5/00 ,  C07F9/00 ,  C08F4/16 ,  C08F10/06

CPC classification number: C07D213/38 ,  B01J31/1815 ,  B01J31/183 ,  B01J2531/48 ,  B01J2531/49 ,  C07D213/48 ,  C07D213/53 ,  C07F7/00 ,  C07F7/006 ,  C08F10/00 ,  C08F110/06 ,  C08F210/16 ,  C08F2500/03 ,  C08F2500/05 ,  C08F210/14 ,  C08F4/64144 ,  C08F4/64148 ,  C08F4/64151

Abstract: Pyridyldiamido transition metal complexes are disclosed for use in alkene polymerization to produce multimodal polyolefins.

Abstract translation: 公开了用于烯烃聚合以制备多峰聚烯烃的吡啶基二酰氨基过渡金属络合物。