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    RIGID NON-CYCLOPENTADIENYL GROUP 4 TRANSITION METAL AND RARE EARTH METAL CATALYSTS FOR OLEFIN POLYMERIZATION
    1.
    发明申请
    RIGID NON-CYCLOPENTADIENYL GROUP 4 TRANSITION METAL AND RARE EARTH METAL CATALYSTS FOR OLEFIN POLYMERIZATION 审中-公开

    公开(公告)号：WO2018232503A1

    公开(公告)日：2018-12-27

    申请号：PCT/CA2018/050742

    申请日：2018-06-19

    Applicant: MCMASTER UNIVERSITY

    Inventor： EMSLIE, David ,  WILLIAMS, Kelly ,  VASANTHAKUMAR, Arthithiyan

    IPC: C08F4/76 ,  C08F4/52

    CPC classification number: C08F110/02 ,  C08F2/06 ,  C08F4/65908 ,  C08F4/64141 ,  C08F4/64148 ,  C08F4/64186 ,  C08F4/64113 ,  C08F4/6411 ,  C08F4/64117 ,  C08F4/64182 ,  C08F4/545 ,  C08F2500/02

    Abstract: The present application provides a catalyst component for alkene polymerization. The catalyst component contains: (a) a group 4 transition metal or rare earth metal, (b) a rigid non-cyclopentadienyl ligand with a tricyclic backbone composed of three ortho -fused 6-membered rings in a linear arrangement (as is the case in xanthene), with or without additional fused rings; the tricyclic backbone contains at least one donor atom within the central ring (as is the case for xanthene, oxanthrene, or acridan); furthermore, donor atoms/groups or aryl rings are attached directly (i.e. via the donor atom in the case of donor groups) to both of the bondable carbon atoms adjacent to at least one of the donor atoms within the central ring (e.g. xanthene with two donor groups, or two aryl rings, or one donor group and one aryl ring adjacent to oxygen), and (c) two or more activatable ligands, such as chloro, alkyl, aryl, allyl or hydride ligands, attached to the central metal if the complex is neutral or anionic, or one or more activatable ligand if the complex is monocationic or dicationic. The rigid non-cyclopentadienyl ligand has a charge of 0, 1– or 2– (considering all donor atoms of the ligand to have an octet of valence electrons). The catalyst component is optionally combined with an activator, typically for the purpose of generating a highly active monocationic or dicationic polymerization catalyst, and the catalyst and/or catalyst components may be in solution, precipitated from solution, or optionally carried on a support.

    LIGANDS FOR CATALYSTS
    4.
    发明申请
    LIGANDS FOR CATALYSTS 审中-公开
    催化剂配体

    公开(公告)号：WO2014149361A1

    公开(公告)日：2014-09-25

    申请号：PCT/US2014/017671

    申请日：2014-02-21

    Applicant: UNIVATION TECHNOLOGIES, LLC

    Inventor： GIESBRECHT, Garth, R.

    IPC: C08F10/00 ,  C08F4/6592 ,  C07F7/00

    CPC classification number: C08F10/02 ,  C08F4/64148 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65922 ,  C08F10/00 ,  C08F210/02 ,  C08F210/16 ,  C08F210/14 ,  C08F2500/03

    Abstract: Catalyst systems and methods for making and using the same. A catalyst system can include a non-metallocene catalyst having the structure: wherein M is a group 4 element, each of R 13 -R 20 are independently a hydrogen or a methyl group, wherein at least one of R 13 -R 20 is a methyl group, Ar is an aryl group or a substituted aryl group, Ar' is an aryl group or a substituted aryl group, and each X is, independently, a hydride group, an amide, a benzyl group, a methyl group, a chloro group, a fluoro group, or a hydrocarbyl group.

    Abstract translation: 催化剂体系及其制造和使用方法。 催化剂体系可以包括具有以下结构的非金属茂催化剂：其中M是第4族元素，R 13 -R 20各自独立地是氢或甲基，其中R 13 -R 20中的至少一个是甲基，Ar 是芳基或取代的芳基，Ar'是芳基或取代的芳基，并且各X独立地是氢化物基，酰胺，苄基，甲基，氯基，氟 基团或烃基。

    PROCESS FOR PREPARING CATALYSTS AND CATALYSTS MADE THEREBY
    7.
    发明申请
    PROCESS FOR PREPARING CATALYSTS AND CATALYSTS MADE THEREBY 审中-公开
    制备催化剂和催化剂的方法

    公开(公告)号：WO2013172950A1

    公开(公告)日：2013-11-21

    申请号：PCT/US2013/031170

    申请日：2013-03-14

    Applicant: UNION CARBIDE CHEMICALS AND PLASTICS TECHNOLOGY LLC ,  JORGENSEN, Robert, J.

    Inventor： JORGENSEN, Robert, J.

    IPC: B01J37/14 ,  B01J23/26 ,  B01J31/22 ,  B01J35/02 ,  B01J35/10 ,  B01J37/00 ,  C08F10/02

    CPC classification number: C08F4/69 ,  B01J23/26 ,  B01J31/2295 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1042 ,  B01J37/0045 ,  B01J37/0201 ,  B01J37/04 ,  B01J37/12 ,  C08F4/63912 ,  C08F4/63925 ,  C08F4/659 ,  C08F10/02 ,  C08F10/00 ,  C08F4/64148 ,  C08F4/65925 ,  C08F4/63904 ,  C08F4/025

    Abstract: A process for preparing a catalyst comprising (A) selecting a catalyst support selected from the group consisting of gels of silica, silica alumina, alumina, aluminum phosphate, aluminaphospate, and combinations of two or more thereof; (B) mixing the catalyst support with one or more chromium containing compound, wherein the chromium containing compound is selected from the group consisting of chromium containing compounds which are oxidizable to a Cr +6 state and chromium containing compounds wherein the chromium is in a Cr +6 state; (C) mixing the catalyst support with one or more transition metal catalyst component; (D) calcining the catalyst support; and (E) optionally for the chromium containing compound which is oxidizable to a Cr +6 state, converting the chromium in the chromium containing compound to Cr +6 ; and (F) spray drying the catalyst support to form catalyst particles; wherein steps (B) - (F) may occur separately in any order or wherein any one or more of steps (B) - (F) may be combined together; and wherein the catalyst support gels are characterized by a surface area greater than 50 m 2 /gram and a pore volume greater than 0.5 cc/gram at the time of mixing the catalyst support gels with the chromium containing compound is provided.

    Abstract translation: 一种制备催化剂的方法，包括（A）选择选自二氧化硅凝胶，二氧化硅氧化铝，氧化铝，磷酸铝，铝铝酸盐的催化剂载体，以及其两种或多种的组合; （B）将催化剂载体与一种或多种含铬化合物混合，其中含铬化合物选自可氧化成Cr + 6态的含铬化合物和含铬化合物，其中铬为Cr +6状态 （C）将催化剂载体与一种或多种过渡金属催化剂组分混合; （D）煅烧催化剂载体; 和（E）任选用于可氧化成Cr + 6状态的含铬化合物，将含铬化合物中的铬转化为Cr + 6; 和（F）喷雾干燥催化剂载体以形成催化剂颗粒; 其中步骤（B） - （F）可以以任何顺序分开发生，或其中步骤（B） - （F）中的任何一个或多个可以组合在一起; 并且其中催化剂载体凝胶的特征在于表面积大于50m 2 / g，并且在催化剂载体凝胶与含铬化合物混合时，孔体积大于0.5cc / g。

    METHODS FOR PRODUCING POLYOLEFINS WITH CATALYST SYSTEMS
    8.
    发明申请
    METHODS FOR PRODUCING POLYOLEFINS WITH CATALYST SYSTEMS 审中-公开
    用催化剂体系生产聚烯烃的方法

    公开(公告)号：WO2013070602A1

    公开(公告)日：2013-05-16

    申请号：PCT/US2012/063704

    申请日：2012-11-06

    Applicant: UNIVATION TECHNOLOGIES, LLC

    Inventor： SUN, Lixin ,  RIX, Francis, C. ,  KAO, Sun-Chueh ,  KHOKHANI, Paul, A. ,  CAO, Phuong, A.

    IPC: C08F210/16 ,  C08F10/02 ,  C08F4/659 ,  C08F4/64

    CPC classification number: C08F210/16 ,  C08F4/65904 ,  C08F4/6592 ,  C08F4/65925 ,  C08F4/65927 ,  C08F10/00 ,  C08F2500/05 ,  C08F4/659 ,  C08F10/02 ,  C08F4/64148 ,  C08F210/14 ,  C08F2500/12

    Abstract: Described herein are methods comprising contacting one or more olefins with a catalyst system in a polymerization reactor at conditions sufficient to produce a polyolefin, wherein the catalyst system comprises a first metallocene catalyst compound comprising a first transition metal atom, two cyclopentadienyl ligands bound to the first transition metal atom, and two leaving groups bound to the first transition metal atom, wherein at least one leaving group is selected from the group consisting of a halo-phenoxy and a halo-alkoxy; wherein the first metallocene catalyst compound has a catalyst productivity that is at least 20% greater than a comparative metallocene catalyst compound used to produce the same polyolefin, wherein the comparative metallocene catalyst compound is the same as the first metallocene catalyst compound except neither leaving group is a halo-phenoxy or a halo-alkoxy.

    Abstract translation: 本文描述的方法包括使一种或多种烯烃与聚合反应器中的催化剂体系在足以产生聚烯烃的条件下接触，其中催化剂体系包含第一茂金属催化剂化合物，其包含第一过渡金属原子，两个环戊二烯基配位体与第一 过渡金属原子和与第一过渡金属原子结合的两个离去基团，其中至少一个离去基团选自卤代 - 苯氧基和卤代 - 烷氧基; 其中所述第一茂金属催化剂化合物的催化剂生产率比用于制备相同聚烯烃的对比茂金属催化剂化合物大至少20％，其中所述比较茂金属催化剂化合物与除离开基团之外的第一茂金属催化剂化合物相同 卤代 - 苯氧基或卤代 - 烷氧基。

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