PREPARATION OF PRECIPITATED ZN PP CATALYSTS WITH INTERNAL PORE STRUCTURE USING NANOPARTICLES
    2.
    发明申请
    PREPARATION OF PRECIPITATED ZN PP CATALYSTS WITH INTERNAL PORE STRUCTURE USING NANOPARTICLES 审中-公开
    使用纳米颗粒制备具有内部结构的ZN PP催化剂

    公开(公告)号:WO2010127997A3

    公开(公告)日:2010-12-29

    申请号:PCT/EP2010055885

    申请日:2010-04-30

    Abstract: Process for the preparation of a catalyst being in the form of solid particles comprising the steps of °preparing a solution of a complex of a metal which is selected from one of the groups 1 to 3 of the periodic table (IUPAC) and an electron donor by reacting a compound of said metal with said electron donorin an organic liquid reaction medium; °adding to said solution solid material obtaining a suspension, said solid material -does not comprise catalytically active sites, -has a specific surface area below 500 m2/g, and -has a mean particle size below 200 nm; °combining said suspension at a temperature of at least 50°C with at least one transition metal compound resulting in a precipitation of said catalyst being in the form of a solid particle, wherein said transition metal compound is selected from one of the groups 4 to 10 of the periodic table (IUPAC) or a compound of actinide or lanthanide; and °optionally separating said catalyst; said catalyst being in the form of solid particles, which -have a specific surface area of less than 20 m2/g, and -contain said solid material.

    Abstract translation: 制备固体颗粒形式的催化剂的方法包括以下步骤:制备选自元素周期表(IUPAC)中1组至3族之一的金属络合物和电子给体 通过使所述金属的化合物与所述电子给体的反应有机液体反应介质; 加入到所述溶液固体材料中得到悬浮液,所述固体材料不包含催化活性位点 - 具有低于500m 2 / g的比表面积,并且具有低于200nm的平均粒度; °将所述悬浮液在至少50℃的温度下与至少一种过渡金属化合物结合,导致所述催化剂以固体颗粒的形式沉淀,其中所述过渡金属化合物选自组4至 10的周期表(IUPAC)或锕系元素或镧系元素的化合物; 和任选地分离所述催化剂; 所述催化剂为具有小于20m 2 / g的比表面积的固体颗粒的形式,并且包含所述固体材料。

    RANDOM PROPYLENE COPOLYMER WITH HIGH COMONOMER CONTENT
    3.
    发明申请
    RANDOM PROPYLENE COPOLYMER WITH HIGH COMONOMER CONTENT 审中-公开
    具有高音质内容的随机丙烯共聚物

    公开(公告)号:WO2009068577A1

    公开(公告)日:2009-06-04

    申请号:PCT/EP2008/066265

    申请日:2008-11-26

    CPC classification number: C08F210/06 C08F2/001 C08F210/16 C08F2500/12

    Abstract: The present invention relates to a propylene random copolymer, comprising comonomers selected from the group consisting of ethylene, C 4 to C 20 alpha-olefins, and any combination thereof, wherein the propylene random copolymer (a) has a comonomer content of at least 3.5 wt.-%, based on the weight of the propylene random copolymer, (b) has a randomness of at least 30 %, and (c) is prepared in the presence of a catalyst system comprising solid catalyst particles, wherein the solid catalyst particles (cl) have a specific surface area of less than 20 m 2 /g, (c2) comprise a transition metal compound which is selected from one of the groups 4 to 10 of the periodic table or a compound of actinide or lanthanide, (c3) comprise a metal compound which is selected from one of the groups 1 to 3 of the periodic table, and (c4) comprise inclusions not having catalytically active sites.

    Abstract translation: 本发明涉及丙烯无规共聚物,其包含选自乙烯,C 4至C 20α-烯烃以及它们的任何组合的共聚单体,其中丙烯无规共聚物(a)的共聚单体含量为至少3.5wt。 - %,基于丙烯无规共聚物的重量,(b)具有至少30%的随机性,和(c)在包含固体催化剂颗粒的催化剂体系的存在下制备,其中固体催化剂颗粒 )具有小于20m 2 / g的比表面积,(c2)包含选自元素周期表第4至10族之一的过渡金属化合物或锕系元素或镧系元素的化合物,(c3)包含 金属化合物,其选自周期表第1至3族之一,(c4)包含不具有催化活性位点的夹杂物。

    PROCESS FOR THE MANUFACTURE OF HETEROPHASIC PROPYLENE COPOLYMER
    7.
    发明申请
    PROCESS FOR THE MANUFACTURE OF HETEROPHASIC PROPYLENE COPOLYMER 审中-公开
    异构丙烯共聚物的制备方法

    公开(公告)号:WO2009068581A1

    公开(公告)日:2009-06-04

    申请号:PCT/EP2008/066269

    申请日:2008-11-26

    Abstract: The invention is directed to a process for the manufacture of heterophasic propylene copolymer compositions comprising the steps of forming a propylene polymer matrix in at least one slurry reactor and optionally in at least one gas phase reactor and subsequently forming in at least one gas phase reactor an elastomeric copolymer by copolymerizing propylene with ethylene and/or with another α-olefm in the presence of said matrix, wherein the polymerization is carried out in the presence of a catalyst system comprising a catalyst in form of solid particles, said particles (a) have a surface area of less than 20 m 2 /g (b) comprise a transition metal compound of groups 4 to 10 of the periodic table or a compound of actinide or lanthanide, (c) comprise a metal compound of groups 1 to 3 of the periodic table, and (d) comprise inclusions not comprising catalytically active sites.

    Abstract translation: 本发明涉及制造多相丙烯共聚物组合物的方法,包括以下步骤:在至少一个淤浆反应器中和任选地在至少一个气相反应器中形成丙烯聚合物基质,随后在至少一个气相反应器中形成 弹性体共聚物,其通过在所述基质存在下将丙烯与乙烯和/或与另一个α-烯烃共聚合,其中所述聚合在包含固体颗粒形式的催化剂的催化剂体系存在下进行,所述颗粒(a)具有 表面积小于20m2 / g(b)包含元素周期表第4至10族的过渡金属化合物或锕系元素或镧系元素的化合物,(c)包含周期表中第1至3族的金属化合物 表和(d)包含不包含催化活性位点的夹杂物。

    PREPARATION OF PRECIPITATED ZN PP CATALYSTS WITH INTERNAL PORE STRUCTURE USING NANOPARTICLES
    10.
    发明申请
    PREPARATION OF PRECIPITATED ZN PP CATALYSTS WITH INTERNAL PORE STRUCTURE USING NANOPARTICLES 审中-公开
    用纳米颗粒制备内部孔结构的沉淀ZN PP催化剂

    公开(公告)号:WO2010127997A2

    公开(公告)日:2010-11-11

    申请号:PCT/EP2010/055885

    申请日:2010-04-30

    Abstract: Process for the preparation of a catalyst being in the form of solid particles comprising the steps of •preparing a solution of a complex of a metal which is selected from one of the groups 1 to 3 of the periodic table (IUPAC) and an electron donor by reacting a compound of said metal with said electron donorin an organic liquid reaction medium; •adding to said solution solid material obtaining a suspension, said solid material -does not comprise catalytically active sites, -has a specific surface area below 500 m 2 /g, and -has a mean particle size below 200 nm; •combining said suspension at a temperature of at least 50°C with at least one transition metal compound resulting in a precipitation of said catalyst being in the form of a solid particle, wherein said transition metal compound is selected from one of the groups 4 to 10 of the periodic table (IUPAC) or a compound of actinide or lanthanide; and •optionally separating said catalyst; said catalyst being in the form of solid particles, which -have a specific surface area of less than 20 m 2 /g, and -contain said solid material.

    Abstract translation: 用于制备固体颗粒形式的催化剂的方法包括以下步骤:·制备选自周期表第1至3族之一的金属络合物的溶液 通过使所述金属的化合物与所述电子供体在有机液体反应介质中反应来制备表(IUPAC)和电子供体; ·向所述溶液中添加固体材料以获得悬浮液,所述固体材料不包含催化活性位点, - 具有低于500m 2 / g的比表面积和 - 具有低于500m 2 / g的平均粒度 200纳米; ·将所述悬浮液在至少50℃的温度下与至少一种过渡金属化合物结合,导致所述催化剂沉淀为固体颗粒形式,其中所述过渡金属化合物选自组4至组4 周期表(IUPAC)的10或act系元素或镧系元素的化合物; 和·任选分离所述催化剂; 所述催化剂为固体颗粒形式,其具有小于20m 2 / g的比表面积,并且包含所述固体材料。

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