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    PROCESS FOR MAKING A SOLID CATALYST COMPONENT FOR ETHYLENE POLYMERIZATION AND COPOLYMERIZATION
    1.
    发明申请
    PROCESS FOR MAKING A SOLID CATALYST COMPONENT FOR ETHYLENE POLYMERIZATION AND COPOLYMERIZATION 审中-公开
    用于制备乙烯聚合和共聚的固体催化剂组分的方法

    公开(公告)号：WO2017114813A1

    公开(公告)日：2017-07-06

    申请号：PCT/EP2016/082680

    申请日：2016-12-27

    Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

    Inventor： MOMAN, Akhlaq ,  BLACKMORE, Ian

    IPC: C08F10/02 ,  C08F4/651 ,  C08F4/655 ,  C08F4/658 ,  C08F210/16

    CPC classification number: C08F10/02 ,  C08F4/6565 ,  C08F4/6546 ,  C08F4/651 ,  C08F110/02 ,  C08F2500/04 ,  C08F210/16 ,  C08F210/14 ,  C08F4/025

    Abstract: The present invention relates to a process for preparing a solid catalyst component suitable for producing polyethylene and its copolymers, said process comprising the steps of: (a) contacting a dehydrated support having hydroxyl groups with a magnesium compound having the general formula MgR 1 R 2 ; (b) contacting the product obtained in step (a) with modifying compounds (A) and/or (B) and/or (C), wherein: (A) is an 4-amino-pent-3-en-2-one; (B) is a compound having the general formula R 11 f (R 12 O) g SiX h , (C) is a compound having the general formula (R 13 O) 4 M, and (c) contacting the product obtained in step (b) with a titanium halide compound having the general formula TiX 4 , wherein Ti is a titanium atom and X is a halide atom. The invention also relates to a solid catalyst component obtainable by said process. The invention further relates to a process for producing polyethylene and its copolymers in the presence of the solid catalyst component and a co-catalyst.

    Abstract translation: 本发明涉及制备适用于生产聚乙烯及其共聚物的固体催化剂组分的方法，所述方法包括以下步骤：（a）使具有羟基的脱水载体与镁化合物 具有通式MgR 1 1 R 2 2; （b）使步骤（a）中得到的产物与改性化合物（A）和/或（B）和/或（C）接触，其中：（A）为4-氨基 - 戊-3-烯-2-酮 一; （B）是具有通式R 11 R 12（R 12 O）g SiX

    CATALYST FOR POLYMERIZATION OF OLEFINS AND PROCESS THEREOF
    4.
    发明申请
    CATALYST FOR POLYMERIZATION OF OLEFINS AND PROCESS THEREOF 审中-公开
    用于烯烃聚合的催化剂及其工艺

    公开(公告)号：WO2014045258A3

    公开(公告)日：2014-10-30

    申请号：PCT/IB2013058791

    申请日：2013-09-24

    Applicant: INDIAN OIL CORP LTD

    Inventor： SINGH GURMEET ,  KUMAR NARESH ,  KAUR SUKHDEEP ,  KAPUR GURPREET SINGH ,  KANT SHASHI ,  BASU BISWAJIT ,  MALHOTRA RAVINDER KUMAR ,  NENSETH SVEIN ,  LINDROOS JARMO

    IPC: C08F4/654 ,  C08F110/06

    CPC classification number: C08F4/76 ,  C08F4/10 ,  C08F4/52 ,  C08F10/06 ,  C08F110/06 ,  C08F4/651 ,  C08F4/6546 ,  C08F210/06 ,  C08F210/16 ,  C08F2500/02 ,  C08F2500/03 ,  C08F2500/12 ,  C08F2500/18

    Abstract: The present invention provides a process for preparation of a solid titanium catalyst component for use as pro-catalyst for a Ziegler-Natta catalyst system. The solid titanium catalyst component comprises a combination of 15 to 20 wt% of a magnesium moiety, 1.0 to 6.0 wt% of a titanium moiety and 5.0 to 20 wt% of an internal donor, said solid titanium catalyst component has an average particle size in the range of 1 to 100 µm, characterized by a three point particle size distribution of D10 in the range of 1 to 10 µm; D50 in the range of to 25 µm and D90 in the range of 15 to 50 µm. The present invention also provides a 15 Ziegler-Natta catalyst system comprising the solid titanium catalyst component and the method of polymerizing and/or copolymerizing olefins by using the Ziegler-Natta catalyst system.

    Abstract translation: 本发明提供了用作齐格勒 - 纳塔催化剂体系的催化剂的固体钛催化剂组分的制备方法。 固体钛催化剂组分包含15至20重量％的镁部分，1.0至6.0重量％的钛部分和5.0至20重量％的内给体的组合，所述固体钛催化剂组分的平均粒度为 范围为1至100μm，其特征在于D10的三点粒度分布在1至10μm的范围内; D50在25μm的范围内，D90在15至50μm的范围内。 本发明还提供了包含固体钛催化剂组分的齐格勒 - 纳塔催化剂体系和通过使用齐格勒 - 纳塔催化剂体系聚合和/或共聚烯烃的方法。

    NON-PHTHALATE COMPOUNDS AS ELECTRON DONORS FOR POLYOLEFIN CATALYSTS
    5.
    发明申请
    NON-PHTHALATE COMPOUNDS AS ELECTRON DONORS FOR POLYOLEFIN CATALYSTS 审中-公开
    作为聚烯烃催化剂的电子助剂的非对苯二甲酸酯化合物

    公开(公告)号：WO2014160012A2

    公开(公告)日：2014-10-02

    申请号：PCT/US2014/025625

    申请日：2014-03-13

    Applicant: FORMOSA PLASTICS CORPORATION, USA ,  XU, Demin ,  ZHANG, Lei

    Inventor： XU, Demin ,  ZHANG, Lei

    IPC: C08F4/52

    CPC classification number: C08F4/52 ,  C08F4/6546 ,  C08F110/06 ,  C08F2500/12 ,  C08F2500/15 ,  C08F4/6548 ,  C08F4/651

    Abstract: Non-phthalate compounds having a structure represented by the general formula (I) and a method for using same are provided as electron donors in the Ziegler-Natta type catalyst system for the homopolymerization or copolymerization of alpha olefins. The non-phthalate compounds may be used in the preparation of the solid catalyst component, thus serving as "internal electron donors", or employed during or prior to polymerization as "external electron donors", and therefore they can be used to prepare phthalate-free polyolefins.

    Abstract translation: 在用于α-烯烃的均聚或共聚的齐格勒 - 纳塔型催化剂体系中，作为电子给体提供具有通式（I）表示的结构的非邻苯二甲酸酯化合物及其使用方法。 非邻苯二甲酸酯化合物可用于制备固体催化剂组分，因此用作“内电子供体”，或在聚合期间或之前用作“外电子供体”，因此它们可用于制备邻苯二甲酸酯 - 游离聚烯烃。

    HIGH PERFORMANCE ZIEGLER-NATTA CATALYST SYSTEMS, PROCESS FOR PRODUCING SUCH SUPPORTED CATALYSTS AND USE THEREOF
    8.
    发明申请
    HIGH PERFORMANCE ZIEGLER-NATTA CATALYST SYSTEMS, PROCESS FOR PRODUCING SUCH SUPPORTED CATALYSTS AND USE THEREOF 审中-公开
    高性能ZIEGLER-NATTA催化剂体系，生产这种支持催化剂的方法及其用途

    公开(公告)号：WO2014079971A1

    公开(公告)日：2014-05-30

    申请号：PCT/EP2013/074468

    申请日：2013-11-22

    Applicant: LUMMUS NOVOLEN TECHNOLOGY GMBH

    Inventor： DENKWITZ, Yvonne ,  SCHUSTER, Oliver ,  WINTER, Andreas

    IPC: C08F10/00 ,  C08F4/651 ,  C08F4/654

    CPC classification number: C08F110/06 ,  C08F4/64 ,  C08F10/00 ,  C08F4/651 ,  C08F4/6546

    Abstract: A method for making a solid catalyst component for use in a Ziegler-Natta catalyst includes combining in a hydrocarbon solvent a porous particulate support with a hydrocarbon soluble organomagnesium compound to form a suspension. The organomagnesium compound is halogenated followed by addition of an alcohol and the mixture is then reacted with a titanium compound followed by a reaction with at least one diether compound to form the solid catalyst component. Afterwards the reaction product is extracted with a mixture of a titanium compound and a hydrocarbon solvent. The solid catalyst component recovered is combined with an aluminum cocatalyst to form a Ziegler- Natta catalyst system for the polymerization of olefins. In particular, the catalyst system including a diether internal electron donor may have an activity and hydrogen response suitable for the production of propylene polymers having a molecular weight distribution (PI(GPC)) in the range from about 5.75 to about 9.

    Abstract translation: 制备用于齐格勒 - 纳塔催化剂的固体催化剂组分的方法包括在烃溶剂中将多孔颗粒载体与可溶于烃的有机镁化合物混合以形成悬浮液。 将有机镁化合物卤化，然后加入醇，然后将混合物与钛化合物反应，然后与至少一种二醚化合物反应形成固体催化剂组分。 之后，用钛化合物和烃溶剂的混合物萃取反应产物。 将回收的固体催化剂组分与铝助催化剂组合以形成用于烯烃聚合的齐格勒 - 纳塔催化剂体系。 特别地，包括二醚内电子给体的催化剂体系可具有适用于生产分子量分布（PI（GPC））在约5.75至约9范围内的丙烯聚合物的活性和氢气响应。

    FORMATION OF ZIEGLER-NATTA CATALYST USING NON-BLENDED COMPONENTS
    9.
    发明申请
    FORMATION OF ZIEGLER-NATTA CATALYST USING NON-BLENDED COMPONENTS 审中-公开
    使用非混合组分形成ZIEGLER-NATTA催化剂

    公开(公告)号：WO2011133313A1

    公开(公告)日：2011-10-27

    申请号：PCT/US2011/031072

    申请日：2011-04-04

    Applicant: FINA TECHNOLOGY, INC. ,  ZHANG, Lei ,  GAUTHIER, William

    Inventor： ZHANG, Lei ,  GAUTHIER, William

    IPC: C08F4/44

    CPC classification number: C08F10/00 ,  C08F110/02 ,  C08F4/6548 ,  C08F4/6557 ,  C08F2500/18 ,  C08F4/6546

    Abstract: Methods of forming a catalyst, catalysts, polymerization processes and polymers formed therefrom are described herein. The method of forming a catalyst generally includes contacting an alkyl magnesium compound with an alcohol to form a magnesium alkoxide compound; contacting the magnesium alkoxide compound with a first titanium alkoxide and a first agent to form a reaction product "A", wherein the titanium alkoxide and the first agent are nonblended individual components prior to contacting the magnesium alkoxide; and sequentially contacting the reaction product "A" with a second agent, followed by a third agent, and subsequently a first reducing agent to form a catalyst component.

    Abstract translation: 本文描述了形成催化剂，催化剂，聚合方法和由其形成的聚合物的方法。 形成催化剂的方法通常包括使烷基镁化合物与醇接触以形成烷氧基镁化合物; 使烷氧基镁化合物与第一钛醇盐和第一试剂接触以形成反应产物“A”，其中钛醇盐和第一试剂是在与烷氧基镁接触之前是非共混的单独组分; 并依次使反应产物“A”与第二试剂接触，然后与第三试剂接触，随后使第一还原剂接触以形成催化剂组分。

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